Continental crust isotopic ratios

Let us first introduce some important definitions with the help of some simple mathematical concepts. Critical aspects of the evolution of a geological system, e.g., the mantle, the ocean, the Phanerozoic clastic sediments,..., can often be adequately described with a limited set of geochemical variables. These variables, which are typically concentrations, concentration ratios and isotope compositions, evolve in response to change in some parameters, such as the volume of continental crust or the release of carbon dioxide in the atmosphere. We assume that one such variable, which we label/ is a function of time and other geochemical parameters. The rate of change in / per unit time can be written... 

Taylor SR, McLennan SM (1985) The Continental Crust Its Composition and Evolution. Blackwell, Boston Tuit CB, Ravizza G (2003) The marine distribution of molybdenum. Geochim Cosmochim Acta 67 A4950 Tumlund JR, Keyes WR, Peiffer GL (1993) Isotope ratios of molybdenum determined by thermal ionization mass spectrometry for stable isotope studies of molybdenum metabolism in humans. Anal Chem 65 1717-1722... 

O, H, C, S, and N isotope compositions of mantle-derived rocks are substantially more variable than expected from the small fractionations at high temperatures. The most plausible process that may result in variable isotope ratios in the mantle is the input of subducted oceanic crust, and less frequent of continental crust, into some portions of the mantle. Because different parts of subducted slabs have different isotopic compositions, the released fluids may also differ in the O, H, C, and S isotope composition. In this context, the process of mantle metasomatism is of special significance. Metasomatic fluids rich in Fe +, Ti, K, TREE, P, and other large ion lithophile (LIE) elements tend to react with peridotite mantle and form secondary micas, amphiboles and other accessory minerals. The origin of metasomatic fluids is likely to be either (1) exsolved fluids from an ascending magma or (2) fluids or melts derived from subducted, hydrothermally altered crust and its overlying sediments. 

Since hthium and boron isotope fractionations mainly occur during low temperature processes, Li and B isotopes may provide a robust tracer of surface material that is recycled to the mantle (Elhott et al. 2004). Heterogeneous distribution of subducted oceanic and continental crust in the mantle will thus result in variations in Li and B isotope ratios. Furthermore, dehydration processes active in subducdon zones appear to be of crucial importance in the control of Li and B isotope composition of different parts of the mantle. For the upper mantle as a whole Jeffcoate et al. (2007) gave an estimated 8 Li-value of 3.5%o. 

The zircon reference material 91500 discussed before seems to be very suitable for calibrating in situ oxygen isotope analysis. For example, SIMS was employed to study the 8 0 value on the zircon single crystal 91500 . No systematic differences in SIMS 8 0 data were observed between individual fragments of zircon crystal. Peck et alP studied oxygen isotope ratios by ion microprobe analysis for evidence of oxygen isotope variation in continental crust and oceans in 3.3 to 4.4 X 10 year old zircons. In addition, the authors also analyzed rare earth elements (REEs). ... 

Peck W. H., Valley J. W., Wilde S. A., and Graham C. M. (2001) Oxygen isotope ratios and rare earth elements in 3.3. to 4.4 Ga zircons ion microprobe evidence for high continental crust and oceans in the Early Archean. Geochim Cosmochim. Acta 65, 4215-4229. 

Thallium. Tl has an ionic radius similar to Rb +. The crustal ratio Tl/Rb is quite constant at 0.005 (Hertogen et al., 1980). Since >60% of the Earth s mbidium is probably in the continental crust, and rubidium is reasonably well known from Rb/Sr isotope systematics, this ratio should supply a reasonable estimate for the PM. 

Chondritic relative abundances of strongly incompatible RLEs (lanthanum, niobium, tantalum, uranium, thorium) and their ratios to compatible RLEs in the Earth s mantle are more difficult to test. The smooth and complementary patterns of REEs in the continental crust and the residual depleted mantle are consistent with a bulk REE pattern that is flat, i.e., unfractionated when normalized to chondritic abundances. As mentioned earlier, the isotopic compositions of neodymium and hafnium are consistent with chondritic Sm/Nd and Lu/Hf ratios for bulk Earth. Most authors, however, assume that RLEs occur in chondritic relative abundances in the Earth s mantle. However, the uncertainties of RLE ratios in Cl-meteorites do exceed 10% in some cases (see Table 4) and the uncertainties of the corresponding ratios in the Earth are in same range (Jochum et ai, 1989 W eyer et ai, 2002). Minor differences (even in the percent range) in RLE ratios between the Earth and chondritic meteorites cannot be excluded, with the apparent exception of Sm/Nd and Lu/Hf ratios (Blicher-Toft and Albarede, 1997). 

Figure 3 Crust-mantle differentiation patterns for the decay systems Rb-Sr, Sm-Nd, Lu-Hf, and Re-Os. The diagram illustrates the depletion-enrichment relationships of the parent-daughter pairs, which lead to the isotopic differences between continental crust and the residual mantle. For example, the Sm/Nd ratio is increased, whereas the Rb/Sr ratio is decreased in the residual mantle. This leads to the isotopic correlation in mantle-derived rocks plotted in Figure 4(a). The construction is similar to that used in Figure 2, but D values have been adjusted slightly for greater clarity.

Figures 4-6 show the isotopic compositions of MORBs from spreading ridges in the three major ocean basins. Figures 4(b) and 5(a) also show isotope data for marine sediments, because these are derived from the upper continental crust and should roughly represent the isotopic composition of this crust. In general, the isotopic relationships between the continental and oceanic crust are just what is expected from the elemental parent-daughter relationships seen in Figure 3. The high Rb/Sr and low Sm/Nd and Lu/Hf ratios of continental materials relative to the residual mantle are reflected by high Sr/ Sr and low " Nd/ " Nd and Hf/ Hf ratios (not shown).

With the exception of Davies, who favored whole-mantle convection all along, the above authors concluded that it was only the upper mantle above the 660 km seismic discontinuity that was needed to balance the continental crust. The corollary conclusion was that the deeper mantle must be in an essentially primitive, nearly undepleted state, and consequently convection in the mantle had to occur in two layers with only little exchange between these layers. These conclusions were strongly reinforced by noble gas data, especially He/ He ratios and, more recently, neon isotope data. These indicated that hotspots such as Hawaii are derived from a deep-mantle source with a more primordial, high He/" He ratio, whereas MORBs are derived from a more degassed, upper-mantle reservoir with lower He/ He ratios. The noble-gas aspects are treated in Chapter 2.06. In the present context, two points must be mentioned. Essentially all quantitative evolution models dealing with the noble gas evidence concluded that, although plumes carry... 

A distinct class of models that describe the chemical evolution of the Earth are the so-called box models, in which assumptions are made about the geometry of distinct reservoirs and their interactions. For example, one can assign four distinct reservoirs in the upper mantle, lower mantle, continental crust, and atmosphere and develop differential equations that incorporate radiogenic ingrowth, chemical fractionation effects, and assumptions about mass transfer between the reservoirs. Successful models reproduce the observed isotopic ratios and/or... 

The fractionated igneous and sedimentary rocks in Figure 20 have Rb/Sr and Eu/Sr ratios that are much higher than those in current estimates for the upper continental crust. The latter can be constrained by the strontium isotope ratios of continental run-off (—0.712), and its model neodymium age (—1.8 Ga). According to this method, a minimum time-integrated upper crustal Rb/Sr ratio of 0.14 is indicated. 

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