Condensers and tower pressure control

The bigger the radiator, the more heat is provided to a room. The bigger the radiator, the faster the steam condenses to water inside the radiator. A larger radiator has more heat-transfer surface area exposed to the condensing steam. Unfortunately, the radiator shown in Fig. 18.1 is suffering from a common malfunction. Water-hardness deposits have partly plugged the condensate drain line. Calcium carbonate is a typical water-hardness deposit. 

Anyone who has lived in an apartment house in Brooklyn will have had to occasionally bang on the radiator to increase heat flow. Banging on the radiator often breaks loose the carbonate deposits in the condensate drain line. The steam condensate, which has backed up in the radiator, now empties. This exposes more of the interior surface area of the radiator to the condensing steam. 

It rather seems that 40 percent of the surface area of the radiator in Fig. 18.1 is submerged under water. If the water is drained out, does this mean that the rate of steam condensation will increase by 

When steam condenses at atmospheric pressure, it gives off 1000 Btu/lb of condensing steam. This is called the latent heat of condensation of steam. 

When water cools off from 220 to 120°F, it gives off 100 Btu/lb of water. This heat represents the sensible-heat content of water between 220 and 120°F. 

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Fioure 16.1 Radiator in a Brooklyn apartment house, circa 1946. 

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Sometimes we see tower pressure control based on feeding a small amount of inert or natural gas into the reflux drum. This is bad. The natural gas dissolves in the overhead liquid product and typically flashes out of the product storage tanks. The correct way to control tower pressure in the absence of noncondensable vapors is to employ flooded condenser pressure control. If, for some external reason, a variable level in the reflux drum is required, then the correct design for tower pressure control is a hot-vapor bypass. 

With air-cooled condensers and water cooling towers it is possible to reduce the air flow hy automatic dampers, fan speed control, or switching off fans, where two or more drives are fitted. The control should work from pressure hut can he made to work from temperature (see Section 6.12). 

I well remember one pentane-hexane splitter in Toronto. The tower simply could not make a decent split, regardless of the feed or reflux rate selected. The tower-top pressure was swinging between 12 and 20 psig. The flooded condenser pressure control valve, shown in Fig. 3.1, was operating between 5 and 15 percent open, and hence it was responding in a nonlinear fashion (most control valves work properly only at 20 to 75 percent open). The problem may be explained as follows. 

In general, flooded condenser pressure control is the preferred method to control a tower s pressure. This is so because it is simpler and cheaper than hot-vapor bypass pressure control. Also, the potential problem of a leaking hot-vapor bypass control valve cannot occur. Many thousands of hot-vapor bypass designs have eventually been converted—at no cost—to flooded condenser pressure control. 

As a minimum, a distillation assembly consists of a tower, reboiler, condenser, and overhead accumulator. The bottom of the tower serves as accumulator for the bottoms product. The assembly must be controlled as a whole. Almost invariably, the pressure at either the top or bottom is maintained constant at the top at such a value that the necessary reflux can be condensed with the available coolant at the bottom in order to keep the boiling temperature low enough to prevent product degradation or low enough for the available HTM, and definitely well below the critical pressure of the bottom composition. There still remain a relatively large number of variables so that care must be taken to avoid overspecifying the number and kinds of controls. For instance, it is not possihle to control the flow rates of the feed and the top and bottom products under perturbed conditions without upsetting holdup in the system. 

Figure 3.14. The lower ends of fractionators, (a) Kettle reboiler. The heat source may be on TC of either of the two locations shown or on flow control, or on difference of pressure between key locations in the tower. Because of the built-in weir, no LC is needed. Less head room is needed than with the thermosiphon reboiler, (b) Thermosiphon reboiler. Compared with the kettle, the heat transfer coefficient is greater, the shorter residence time may prevent overheating of thermally sensitive materials, surface fouling will be less, and the smaller holdup of hot liquid is a safety precaution, (c) Forced circulation reboiler. High rate of heat transfer and a short residence time which is desirable with thermally sensitive materials are achieved, (d) Rate of supply of heat transfer medium is controlled by the difference in pressure between two key locations in the tower, (e) With the control valve in the condensate line, the rate of heat transfer is controlled by the amount of unflooded heat transfer surface present at any time, (f) Withdrawal on TC ensures that the product has the correct boiling point and presumably the correct composition. The LC on the steam supply ensures that the specified heat input is being maintained, (g) Cascade control The set point of the FC on the steam supply is adjusted by the TC to ensure constant temperature in the column, (h) Steam flow rate is controlled to ensure specified composition of the PF effluent. The composition may be measured directly or indirectly by measurement of some physical property such as vapor pressure, (i) The three-way valve in the hot oil heating supply prevents buildup of excessive pressure in case the flow to the reboiier is throttled substantially, (j) The three-way valve of case (i) is replaced by a two-way valve and a differential pressure controller. This method is more expensive but avoids use of the possibly troublesome three-way valve.

The bypassed vapor heats up the liquid there, thereby causing the pressure to rise. WTien the bypass is closed, the pressure falls. Sufficient heat transfer surface is provided to subcool the condensate, (f) Vapor bypass between the condenser and the accumulator, with the condenser near ground level for the ease of maintenance When the pressure in the tower falls, the bypass valve opens, and the subcooled liquid in the drum heats up and is forced by its vapor pressure back into the condenser. Because of the smaller surface now exposed to the vapor, the rate of condensation is decreased and consequently the tower pressure increases to the preset value. With normal subcooling, obtained with some excess surface, a difference of 10-15 ft in levels of drum and condenser is sufficient for good control, (g) Cascade control The same system as case (a), but with addition of a TC (or composition controller) that resets the reflux flow rate, (h) Reflux rate on a differential temperature controller. Ensures constant internal reflux rate even when the performance of the condenser fluctuates, (i) Reflux is provided by a separate partial condenser on TC. It may be mounted on top of the column as shown or inside the column or installed with its own accumulator and reflux pump in the usual way. The overhead product is handled by an alter condenser which can be operated with refrigerant if required to handle low boiling components. 

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