Cobalt references

Fig. 6.18 XANES spectra of cobalt reference compounds and of a CoPt/ Al203 Fischer-Tropsch catalyst in different stages of its working life. Samples labeled after FTS were taken from a pilot plant operated at commercially relevant conditions (220 °C, 20 bar, relatively high conversion of 50-70%). Although these catalysts were exposed to significant partial pressures of the byproduct water, the XANES indicate further reduction during usage. (Adapted from [55]).

In order to prepare the calibration curve take increasing quantities of cobalt reference solution containing between 0.005 and 0.15 mg of cobalt and subject the solutions to the process described under "Determination". In the linear range from 0.005 to 0.15 mg of cobalt a calibration factor may also be used for calculation. 

In analogy with the investigations for 400 keV the values for 100, 200 and 300 keV, Iridium-192 and Cobalt-60 were determined (Table I, [1,3]). For Co-60 the equivalent value for film could not be reached with lead foils. Sandwich sPuctures of steel foils and lead foils were necessary. For instance, with 0,5 mm steel and 1 mm lead one could only attain about 80 % of the film value referred to 1/(1+k). The necessary equivalent value is estimated to be 0,5 mm steel and 1,5-2,0 mm lead, but we are still short of determining the precise value. 

Often the aldehyde is hydrogenated to the corresponding alcohol. In general, addition of carbon monoxide to a substrate is referred to as carbonylation, but when the substrate is an olefin it is also known as hydroformylation. The eady work on the 0x0 synthesis was done with cobalt hydrocarbonyl complexes, but in 1976 a low pressure rhodium-cataly2ed process was commerciali2ed that gave greater selectivity to linear aldehydes and fewer coproducts. 

Although lead acetate [301-04-2] is the only metallic dye used ia the early 1990s, salts or silver, copper, nickel, cobalt, bismuth, and iron have been utilized ia the past. A patent (39) refers to the use of bismuth citrate ia a solution made alkaline with triisopropan ol amine. 

Hydantoin itself can be detected ia small concentrations ia the presence of other NH-containing compounds by paper chromatography followed by detection with a mercury acetate—diphenylcarba2one spray reagent. A variety of analytical reactions has been developed for 5,5-disubstituted hydantoias, due to their medicinal iaterest. These reactions are best exemplified by reference to the assays used for 5,5-diphenylhydantoiQ (73—78), most of which are based on their cycHc ureide stmcture. Identity tests iaclude the foUowiag (/) the Zwikker reaction, consisting of the formation of a colored complex on treatment with cobalt(II) salts ia the presence of an amine (2) formation of colored copper complexes and (3) precipitation on addition of silver(I) species, due to formation of iasoluble salts at N. ... 

Alloying elements either enlarge the austenite field or reduce it. The former include manganese, nickel, cobalt, copper, carbon, and nitrogen and are referred to as austenite stabilizers. 

Cobalt is the thirtieth most abundant element on earth and comprises approximately 0.0025% of the earth s cmst (3). It occurs in mineral form as arsenides, sulfides, and oxides trace amounts are also found in other minerals of nickel and iron as substitute ions (4). Cobalt minerals are commonly associated with ores of nickel, iron, silver, bismuth, copper, manganese, antimony, and 2iac. Table 1 Hsts the principal cobalt minerals and some corresponding properties. A complete listing of cobalt minerals is given ia Reference 4. 

Stacking faults thereby providing barriers to sHp. If carbides are allowed to precipitate to the point of becoming continuous along the grain boundaries, they often initiate fracture (see Fracture mechanics). A thorough discussion of the mechanical properties of cobalt alloys is given in References 29 and 30 (see also Refractories). 

More frequently either methyl ethyl ketone peroxide or cyclohexanone peroxide is used for room temperature curing in conjunction with a cobalt compound such as a naphthenate, octoate or other organic solvent-soluble soap. The peroxides (strictly speaking polymerisation initiators) are referred to as catalysts and the cobalt compound as an accelerator . Other curing systems have been devised but are seldom used. 

The Auger depth profile obtained from a plasma polymerized acetylene film that was reacted with the same model rubber compound referred to earlier for 65 min is shown in Fig. 39 [45]. The sulfur profile is especially interesting, demonstrating a peak very near the surface, another peak just below the surface, and a third peak near the interface between the primer film and the substrate. Interestingly, the peak at the surface seems to be related to a peak in the zinc concentration while the peak just below the surface seems to be related to a peak in the cobalt concentration. These observations probably indicate the formation of zinc and cobalt complexes that are responsible for the insertion of polysulfidic pendant groups into the model rubber compound and the plasma polymer. Since zinc is located on the surface while cobalt is somewhat below the surface, it is likely that the cobalt complexes were formed first and zinc complexes were mostly formed in the later stages of the reaction, after the cobalt had been consumed. 

Table 2.24 Breakdown potentials (mV) for 316 stainless steel, titanium and cobalt-chromium-molybdenum alloy in oxygen-free 0.17 m NaCl solution at 37°C using a silver/ silver chloride reference electrode.

The above considerations will be illustrated by the simultaneous determination of manganese and chromium in steel and other ferro-alloys. The absorption spectra of 0.001 M permanganate and dichromate ions in 1M sulphuric acid, determined with a spectrophotometer and against 1M sulphuric acid in the reference cell, are shown in Fig. 17.20. For permanganate, the absorption maximum is at 545 nm, and a small correction must be applied for dichromate absorption. Similarly the peak dichromate absorption is at 440 nm, at which permanganate only absorbs weakly. Absorbances for these two ions, individually and in mixtures, obey Beer s Law provided the concentration of sulphuric acid is at least 0.5M. Iron(III), nickel, cobalt, and vanadium absorb at 425 nm and 545 nm, and should be absent or corrections must be made. 

Other wear mechanisms are flank wear and crater wear which occur mostly with cemented-carbide tools. Flank wear refers to the depression that is formed below the cutting edge on the side of the tool caused by the abrasive wear of the cemented carbide. TiC is particularly effective in reducing it. Crater wear occurs in the form of small depressions on the rake face behind the point of contact of the tool with the workpiece. Diffusion of the cobalt binder into the cutting chip usually occurs with crater wear. TiN is effective in reducing both diffusion and crater wear.PI... 

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