Coated surface acoustic wave sensor

Chemical sensors for gas molecules may, in principle, monitor physisorp-tion, chemisorption, surface defects, grain boundaries or bulk defect reactions [40]. Several chemical sensors are available mass-sensitive sensors, conducting polymers and semiconductors. Mass-sensitive sensors include quartz resonators, piezoelectric sensors or surface acoustic wave sensors [41-43]. The basis is a quartz resonator coated with a sensing membrane which works as a chemical sensor. 

A coated surface-acoustic-wave (SAW) sensor capable of real-time, selective measurement of vinyl acetate vapor in the presence of several olefin and non-olefin cocontaminants is described. The coating film en loyed consists of the solid platinum-ethylene Ji-complex, trans-PtCl (ethylene)(pyridine). occluded in a polyisobutylene matrix. Exposure to vinyl acetate results in displacement of ethylene from the cott lex and formation of the vinyl acetate-substituted complex. Subsequent regeneration of the original reagent is possible by treatment with ethylene gas, in situ. A lower detection limit of 5 ppm of vinyl acetate is achieved for operation at 46 C. The industrial-hygiene applications of the sensor are discussed. 

The combination of molecularly imprinted polymers and europium signal transduction has proven applicable as a generic scheme to develop materials for the detection of hydrolyzed and non-hydrolyzed organophosphate containing cong>ounds such as pesticides and nerve agents. These polymers can be coated onto optical fibers and used as sensors for the detection of these species in aqueous environments. Similar functional polymers can also be used for enhancing the sensitivity and selectivity of other detection devices such as surface acoustic wave sensors. 

Lin H-B, Shih J-S (2003) Fullerene C -cryptand coated surface acoustic wave quartz crystal sensor for organic vapors. Sens Actuators B 92 243-254... 

Afzal A, Dickert FL (2011) Surface acoustic wave sensors for chemical applications. In Korotcenkov G (ed) Chemical sensors comprehensive sensor technologies, vol 4, Solid state devices. Momentum, New York, pp 447-484 Ameloot R, Stappers L, Fransaer J, Alaerts L, Sels BF, De Vos DE (2009) Patterned growth of metal-organic framework coatings by electrochemical synthesis. Chem Mater 21 2580-2582 Ballantine DS, Wohltjen H (1989) Surface acoustic wave devices for chemical analysis. Anal Chem 61 704-715 Ballantine DS Jr, White RM, Martin SJ, Ricco AJ, Zellers ET, Frye GC, Wohltjen H (1996) Acoustic wave sensors theory, design, and physico-chemical applications. In Levy M, Stem R (eds) Applications of modern acoustics. Academic, San Diego... 

Acoustic Wave Sensors. Another emerging physical transduction technique involves the use of acoustic waves to detect the accumulation of species in or on a chemically sensitive film. This technique originated with the use of quartz resonators excited into thickness-shear resonance to monitor vacuum deposition of metals (11). The device is operated in an oscillator configuration. Changes in resonant frequency are simply related to the areal mass density accumulated on the crystal face. These sensors, often referred to as quartz crystal microbalances (QCMs), have been coated with chemically sensitive films to produce gas and vapor detectors (12), and have been operated in solution as Hquid-phase microbalances (13). A dual QCM that has one smooth surface and one textured surface can be used to measure both the density and viscosity of many Hquids in real time (14). 

Microsensors have the potential for selective GC detectors and also as remote sensors when combined in arrays often referred to as electronic noses . Promising microsensors include surface acoustic wave (SAW) detectors normally coated with different semi-selective polymeric layers and microelectromechanical systems (MEMS) including microcantilever sensors. The hope is that, in the future, hundreds of such microcantilevers, coated with suitable coatings, may be able to achieve sufficient selectivity to provide a cost-effective platform for detecting explosives in the presence of potentially interfering compounds in real environments. This array of... 

Another state-of-the-art detection system contains a surface acoustic wave (SAW) device, which is based on a piezoelectric crystal whose resonant frequency is sensitive to tiny changes in its mass—it can sense a change of 10-1° g/cm2. In one use of this device as a detector it was coated with a thin film of zeolite, a silicate mineral. Zeolite has intricate passages of a very uniform size. Thus it can act as a molecular sieve, allowing only molecules of a certain size to pass through onto the detector, where their accumulation changes the mass and therefore alters the detector frequency. This sensor has been used to detect amounts of methyl alcohol (CH3OH) as low as 10 9 g. 

Compact chemical sensors can be broadly classified as being based on electronic or optical readout mechanisms [28]. The electronic sensor types would include resistive, capacitive, surface acoustic wave (SAW), electrochemical, and mass (e.g., quartz crystal microbalance (QCM) and microelectromechanical systems (MEMSs)). Chemical specificity of most sensors relies critically on the materials designed either as part of the sensor readout itself (e.g., semiconducting metal oxides, nanoparticle films, or polymers in resistive sensors) or on a chemically sensitive coating (e.g., polymers used in MEMS, QCM, and SAW sensors). This review will focus on the mechanism of sensing in conductivity based chemical sensors that contain a semiconducting thin film of a phthalocyanine or metal phthalocyanine sensing layer. 

Another important area where gold-thiol monolayers might find promising applications is gas- and biosensing. Simple sensors sensitive to certain types of compounds, based on such detection methods as surface plasmon resonance or surface acoustic wave, have been described454,455,531-533. This type of device is usually made of a gold plate coated with a functionalized monolayer. The terminal functional group of such a monolayer is responsible for selective interactions with the analyte, and adsorption of the latter is then detected by the appropriate method. 

Chemical sensors have been reported that are based on quartz micro balances or surface acoustic wave oscillators coated with the trimethylsilyl ethers of and 6 " and that are claimed to detect various solvent vapors in ppm amounts. ... 

An example of one of TSA/TSL s R D funded MEMS based project is the Sandia National Laboratories (SNL) MicroHound project. This is based on the SNL Micro Chem Lab on a Chip , illustrated in Figure 1. The original prototype system from SNL was developed for high vapour pressure, chemical weapons (CW) detection, which utilized a MEMS GC separator, with miniature surface acoustic wave (SAW s) based sensors. The system included an inlet, coated pre-concentrators, detectors, and pumps. To make this useful for trace explosives detection, the addition of an alternate front-end sample collection/macro-preconcentrator and MEMS based coated-preconcentrator is necessary, along with the option to utilize or exclude the MEMS GC separator followed by detection by either, or both, SAW s and miniaturized IMS detectors. 

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