Chlorine, reaction with hydrogen nitric oxide

Noncombustible gas bums with fuels, hydrocarbons, or when heated with hydrogen. Nitric oxide reacts violently with carbon disulfide vapors, producing green luminous flame with fluorine, it produces a pale yellow flame. It explodes when mixed with ozone, chlorine monoxide, or a nitrogen trihalide. Reactions with many pyrophoric metals produce incandescence. Reaction with amorphous boron produces brilliant flashes. 

Ordinarily arsenic does not react with water, hydrogen, caustic soda or hydrochloric acid. However, in presence of an oxidant it reacts with concentrated HCl. In concentrated HCl solution it reacts with hydrogen sulfide to form a precipitate of yellow arsenic sulfide, AS2S3. It forms orthoarsenic acid, H3ASO4 on reaction with concentrated nitric acid and chlorinated water. 

At low concentrations of chlorine, dimeric nitrosoalkanes free from chlorine are produced when alkanes are treated also with nitric oxide. Under these circumstances, molecular chlorine is first converted into atomic chlorine which attacks the alkane to form alkyl radicals and hydrogen chloride. The alkyl radicals, in turn, form nitrosoalkanes with nitric oxide. This reaction is most effectively carried out when the ultraviolet radiation is between 380 and 420 mp. [43, 56],... 

Bodenstein has, however, shown that the combination of nitric oxide and oxygen 2N0 + 02 = 2N02 is a homogeneous change which is kinetically of the third order, and the same appears to apply to the combination of nitric oxide with chlorine and with bromine f and to the reaction between nitric oxide and hydrogen. J 2NO + C12 = 2NOC1 2NO + Br2 = 2NOBr 2NO + H2 = N20+H20... 

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