Chloride, monohydrate

C8H1607,Ca2+Cl-2,H20 Methyl D-glycero-a-D-guZo-heptopyranoside-calcium chloride monohydrate (GGHPCA)30... 

U.S. imports for consumption, 4 563t water treatment compound for aquaculture in U.S., 3 213t Calcium chloride dihydrate, physical properties of, 4 5571 Calcium chloride hexahydrate, physical properties of, 4 557t Calcium chloride monohydrate, physical properties of, 4 557t Calcium chloride production, use of aqueous hydrochloric acid in,... 

Concerning the initiation, we follow Russell [75a] in assuming that it is a second order reaction, the rate of which is independent of monomer concentration. Most probably it involves a complex of monomer with the stannic chloride monohydrate [75a]. In view of the well-known tendency of stannic chloride to form 6-co-ordinate rather than 5-coordinate structures, this idea does not seem too far-fetched. Since the monomer is in great excess over stannic chloride hydrate, the concentration of the complex, Pj-SnCl HjO, will be sensibly equal to that of the monohydrate, i.e. of either the stannic chloride or the water, whichever is the scarcer. Therefore, the rate of initiation Vi5 will be given by... 

Hydrate Isomerism.—As its name implies, this depends on the position of water in the molecule, just as in the case of the acido compounds. If two or more molecules of water are present in a molecule of ammine, the water may be present within the co-ordination complex or outside of it. For instance, the compound Cr en2.(H20)2.Br3 exists in isomeric forms. It may have all the water within the complex, in which case the formula will be [Cr en2(H20)2]Br3. In solution the whole of the bromine is precipitated by silver nitrate. On the other hand, the compound may have one molecule of water in the complex and the other outside, in which case the formula is [Cr en2(IT20)Br]Br2.H20, and only two-thirds of the bromine are precipitated by silver nitrate. Another example of this kind occurs in the cobalt series chloro-aquo-tetrammino-cobaltic chloride, [Co(NTI3)4Cl.H20]Cl2, is violet in colour, and is isomeric with dichloro-tetrammino-cobaltie chloride monohydrate, [Co(N1I3)4CI2]C1.H20, which is green. 

Tetrammino-cupric Chloride Monohydrate, [Cu(NI-l3)4]Cl2.H20. —When ammonia is passed into a hot saturated solution of cupric chloride a dark blue solution is formed, and, on cooling, dark blue crystals are deposited. The salt crystallises in blue quadratic prisms which lose water on drying, giving the anhydrous salt described above. If heated it loses ammonia, passing into the diammino-derivative, and finally, on further heating, decomposes completely. Water attacks the substance and converts it into cupric ammonium chloride, ammonium chloride, and basic cupric chloride. 

C. (+ )589-A-cis-DICHLOROBIS(l, 2-ETHANEDIAMINE)-CHRO MIUM(III) CHLORIDE MONOHYDRATE... 

Bis(2-amino-2-methyl-3-butanone oximato)-nickel(II) chloride monohydrate... 

Chloride monohydrate. Tetraphenyl borate. c Bromide pentahydrate. 

Cetylpyridinium chloride Monohydrate, C21H38C1N.H20 (Sigma-Aldrich Corp.)... 

Chlormethylthiophene (6.6 g) was added to a solution of 1-dimethylamino-2-phenoxyethane (8.2 g) in acetone (45 ml). On standing for 30 min an oil separeted. The resulting suspension was heated to reflux for a further 30 min and cooled. On standing, the separated oil partially crystallized. The supernatant liquors were decanted and the residue was recrystallized by dissolution in warm isopropanol and careful precipitation with ethyl acetate or ether to give colourless needles N,N-dimethyl-N-2-phenoxyethyl-N-2 -thenylammonium chloride monohydrate, M.P. 85-86°C. 

Cerium(lll) chloride monohydrate Cerium chloride (CeCl3), monohydrate (64332-99-6), 76, 228... 

Loehlin JH, Kvick A (1978) Tfetraethylammonium chloride monohydrate. Acta Cryst B 34 3488—3490... 

BAGXEM. 9-Methylhypoxanthinium chloride monohydrate (C6H7N40+, Cl-, H20). Belanger-Gariepy F, Beauchamp AL (1981) Cryst Struct Commun 10 1165... 

Lithium chloride (m). Dissolve 42-4 g anhydrous lithium chloride, LiCl, or 60-4 g lithium chloride monohydrate LiCl.H20 in water and dilute to 1 litre. 

Standard Lithium Solutions. Dissolve 4.3516g of lithium chloride monohydrate in sufficient O.IM hydrochloric acid to produce 100 ml. This solution contains 5 mg of Li in 1 ml. Serially dilute the solution widi sodium chloride-potassium chloride solution to produce solutions containing 5.0, 10.0, 15.0, 20.0, and 25.0 LLg of Li in 1 ml. 

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