Cell, shielded

Zinc is susceptible to attack from oiQ gen concentration cells. Shielded areas or areas depleted in oxygen concentration tend to corrode, forming voluminous, white, friable corrosion products. Once the zinc layer is breached, the underlying steel becomes susceptible to attack and is severely wasted locally (Figs. 5.12 and 5.13). 

A.J. Frank, Effect of a coadsorbent on the performance of dye-sensitized Ti02 solar cells Shielding versus band-edge movement, /. Phys. Chem. B 109 (2005) 23183-23189. 

Guo R, et al. A transient cell-shielding method for viable MSC delivery within hydrophobic scaffolds polymerized in situ. Biomaterials 2015 54 21-33. 

In the IIRE-2 the sampler is located adjacent to the cell shield, and it is necessary to remove the sample from the sampler and carry it to the analytical laboratory in a shielded carrier. The risk of contamination can be greatly reduced if the hot laboratory is built around the sampler so that samples may be analyzed without removal from the shield however, this would add to the cost of the facility. 

Improper operation or failure of protective interlocks on cell shielding ... 

Strain-gauge load cells are sensitive to temperature gradients induced by, for example, radiant heat from the sun or resulting from high temperature wash down. Load cells should be shielded from such effects or given time to stabilize before use. 

Another medical use of radioisotopes, such Co, is to irradiate certain tissues within the body. An intense source of Co in a heavily shielded facility provides a highly coUimated beam of y-rays that impinge on a tumor in order to kill its cells. 

The potassium hydroxide electrolyte used in alkaline batteries is a corrosive hazardous chemical. It is a poison and if ingested attacks the throat and stomach linings. Immediate medical attention is required. It slowly attacks skin if not rapidly washed away. Extreme care should be taken to avoid eye contact that can result in severe bums and blindness. Protective clothing and face shields or goggles should be worn when filling cells with water or electrolyte and performing other maintenance on vented batteries. 

Attack associated with nonuniformity of the aqueous environments at a surface is called concentration cell corrosion. Corrosion occurs when the environment near the metal surface differs from region to region. These differences create anodes and cathodes (regions differing in electrochemical potential). Local-action corrosion cells are established, and anodic areas lose metal by corrosion. Shielded areas are particularly susceptible to attack, as they often act as anodes (Fig. 2.1). Differences in concentration of dissolved ions such as hydrogen, oxygen, chloride, sulfate, etc. eventually develop between shielded and nearby regions. 

Deposits cause corrosion both directly and indirectly. If deposits contain corrosive substances, attack is direct interaction with the aggressive deposit causes wastage. Shielding of surfaces below deposits produces indirect attack corrosion occurs as a consequence of surface shielding provided by the deposit. Both direct and indirect attack may involve concentration cell corrosion, but indirect attack almost always involves this form of corrosion. 

Severe concentration cell corrosion involves segregation of aggressive anions beneath deposits. Concentrations of sulfate and chloride, in particular, are deleterious. Acid conditions may be established beneath deposits as aggressive anions segregate to these shielded regions. Mineral acids, such as hydrochloric and sulfuric, form by hydrolysis. The mechanism of acid formation is discussed in Chap. 2. 

Substituting one alloy for another may be the only viable solution to a specific corrosion problem. However, caution should be exercised this is especially true in a cooling water environment containing deposits. Concentration cell corrosion is insidious. Corrosion-resistant materials in oxidizing environments such as stainless steels can be severely pitted when surfaces are shielded by deposits. Each deposit is unique, and nature can be perverse. Thus, replacement materials ideally should be tested in the specific service environment before substitution is accepted. 

Slime is a network of secreted strands (extracellular polymers) intermixed with bacteria, water, gases, and extraneous matter. Slime layers occlude surfaces—the biological mat tends to form on and stick to surfaces. Surface shielding is further accelerated by the gathering of dirt, silt, sand, and other materials into the layer. Slime layers produce a stagnant zone next to surfaces that retards convective oxygen transport and increases diffusion distances. These properties naturally promote oxygen concentration cell formation. 

Different microstructural regions in a material which has an almost uniform composition can also lead to the formation of corrosion cells (e.g., in the vicinity of welds). Basically, corrosion cells can be successfully overcome by cathodic protection. However, in practice, care has to be taken to avoid electrical shielding by large current-consuming cathode surfaces by keeping the area as small as possible. In general, with mixed installations of different metals, it must be remembered that the protection potentials and the protection range depend on the materials (Section 2.4). This can restrict the use of cathodic protection or make special potential control necessary. 

A radioactive source was transferred from one container to another by remote operation in a shielded cell. A radiation detector, interlocked with the cell door, prevented anyone from opening the cell door when radiation could be detected inside it. To make sure the interlock was working, an operator tried to open the cell door, by remote control, during a transfer. He found he could open it. He then found that the closing mechanism would not work. Fortunately he had not opened the door very far. 

The deposit partially shields the steel surface, creating a differential aeration cell (Figure 4-435). 

Occluded Cell a corrosion cell of a geometry that prevents intermingling of the anodic reaction products (anolyte) with the bulk solution, resulting in a decrease in pH of the anolyte shielded areas or pits, crevices or cracks in the surface of the metal are examples. 

Special Self-shielded Irradiation Cells for Fast Neutron Activation of... 

The concrete block walls of the cell housing the generator tube and associated components are 1.7 meters thick. The facility also includes a Kaman Nuclear dual-axis rotator assembly for simultaneous transfer and irradiation of reference and unknown sample, and a dual Na iodide (Nal) scintillation detector system designed for simultaneous counting of activated samples. Automatic transfer of samples between load station to the rotator assembly in front of the target, and back to the count station, is accomplished pneumatically by means of two 1.2cm (i.d.) polyethylene tubes which loop down at both ends of the system and pass underneath the concrete shielding thru a pipe duct. Total one-way traverse distance for the samples is approx 9 meters. In performing quantitative analysis for a particular element by neutron activation, the usual approach is to compare the count rates of an unknown sample with that of a reference standard of known compn irradiated under identical conditions... 

All the various forms of concentration cell corrosion described are types of indirect attack induced by the effects of surface shielding, although not all concentration cell corrosion mechanisms involve the presence of oxygen. 

Antifoulants or metal surface cleaners to reduce the risk of pitting corrosion and other forms of concentration cell corrosion initiated at the metal surface by shielding effects from inorganic deposits. These could also be called deposit control agents. 

Haston, W.S., Shields, J.M., Wilkinson, P.C. (1982). Lymphocyte locomotion and attachment on two-dimensional surfaces and in three-dimensional matrices. J. Cell Biol. 92, 747—752. 

---