Elastomers carboxyl-terminated butadiene-acrylonitrile

Several methods have been investigated to improve the fracture toughness of BMI resins, the most used technique being the incorporation of a second phase formed by the dispersion of rubber particles into the cross-linked matrix. Carboxyl-terminated butadiene-acrylonitrile elastomers (CTBN), which are very effective with epoxy resins, are also frequently added to BMI adhesives. The general formula of CTBN rubbers is ... 

CTBN type elastomers (carboxyl-terminated butadiene acrylonitrile) used to toughen this epoxy system. The Tg peak of the elastomer (-30°Q was shifted to higher temperatures suggesting that electron interaction resulted in crosslinking. The fact that the Tg peak disappeared at 10 rads suggests that crosslinking in the elastomer was extensive at high dose levels. 

It is obvious from these data that CTBN (the carboxyl terminated butadiene-acrylonitrile copolymer) is the most effective modifier, and therefore it was selected for further study. As the concentration of the elastomer was increased to levels up to 100 parts, the impact also increased. The data in Table II show that the room temperature impact of ERL-4221 increased from 40 inch-lbs to greater than 320 inch-lbs by adding 100 phr or 33 wt % of CTBN. At very low temperatures ( —160°F) the impact of the system modified with 60 parts, or 23 wt %, of CTBN was 120 inch-lbs. These impact improvements appear to be directly proportional to the concentration of the elastomer modifier. 

Bisphenol-F based, standard, undiluted, elastomer-modified resin (carboxyl-terminated butadiene acrylonitrile) Epon 58006 /Resolution 150,000-300,000 330-360... 

The rubber-toughening process has been one of the most successful methods for modifying polymer toughness. The incorporation of small amounts of rubber into polymer matrices has resulted in significantly improved fracture resistance (1). Particularly interesting improvements in the toughness of epoxies have been accomplished by the addition of carboxyl-terminated butadiene/acrylonitrile (CTBN) elastomers (2,3). 

The second ABCP-type materials of commerce are the rubber-toughened epoxy resinsUsually the epoxy resins are based on the diglycidyl ether of bisphenol A (DGEBA). Carboxyl-terminated butadiene-acrylonitrile (CTBN) rubber is the elastomer of preference. A typical composition is ... 

Acrylonitrile-butadiene copolymer, carboxyl-terminated. See Butadiene-acrylonitrile elastomer, carboxyl-terminated... 

Carboxylated butadiene-acrylonitrile copolymer. See Butadiene-acrylonitrile elastomer, carboxyl-terminated 1-(2-Carboxylatoethyl)-4,5-dihydro-3-(2-hydroxyethyl)-2-isoheptadecyl-1H-imidazolium. See Sodium isostearoamphopropionate Carboxylic acid C4. See n-Butyric acid Carboxylic acid C5. See 2-Methylbutyric acid n-Valeric acid... 

Tween 81. See Polysorbate 81 Tween 85 Tween 85LM. See Polysorbate 85 Twinkling Star. See Antimony trioxide Two-stage phenolic resin. See Novolac resin Two-stage resin. See Phenolic resin Ty-lon B11. See Sodium sulfite Tylac 037 Tylac 97-422 Tylac 692 Tylac 757 Tylac 820 Tylac 936 Tylac 979-RG Tylac 68009-00 Tylac 68010-00 Tylac 68012-00 Tylac 68013-00 Tylac 68014-00. See Styrene/butadiene polymer Tylac 68060-00. See Acrylonitrile copolymer Tylac 68073-00 Tylac 68074-00 Tylac 68075-00 Tylac 68076-00. See Butadiene-acrylonitrile elastomer, carboxyl-terminated Tylac 68150-00 Tylac 68151-00. See Butadiene/acrylonitrile copolymer Tylac 68152-00. See Styrene/butadiene polymer... 

Phenoxyethanol Polyazelaic polyanhydride Polytetramethylene ether glycol diamine Trilinoleic acid flexibilizer, epoxy coatings Bis (4-vinyl oxy butyl) hexanediyibiscarbamate flexibilizer, epoxy resin Butadiene-acrylonitrile elastomer, carboxyl-terminated Polyazelaic polyanhydride flexibilizer, inks... 

Effect of Molecular Configuration of Elastomer. The extent of the impact and strength improvements of ERL-4221 depends on the chemical structure and composition of the elastomer modifier. The data shown in Table I indicate that the carboxyl terminated 80-20 butadiene-acrylonitrile copolymer (CTBN) is the most effective toughening and reinforcing agent. The mercaptan terminated copolymer (MTBN) is considerably less effective as far as tensile strength and heat distortion temperature are concerned. The mercaptan groups are considerably less reactive with epoxides than carboxyls (4), and this difference in the rate of reaction may influence the extent of the epoxy-elastomer copolymerization and therefore the precipitation of the rubber as distinct particles. 

However, newer adhesives systems having moderate temperature resistance have been developed with improved toughness but without sacrificing other properties. When cured, these structural adhesives have discrete elastomeric particles embedded in the matrix. The most common toughened hybrids using this concept are acrylic and epoxy systems. The elastomer is generally a amine- or carboxyl-terminated acrylonitrile butadiene copolymer (ATBN and CTBN). 

Thus, with two equations and two unknowns, a unique solution to X and Y can be calculated. Carboxy-terminated copolymers of butadiene and acrylonitrile (CTBN) can be incorporated into the epoxy resin through a simple esterification reaction. One equivalent of carboxylic acid is esterified by one equivalent of epoxide. This reaction is again catalyzed by triphenylphosphine. Since, for our reactions, the limiting reagent in the esterification is the CTBN elastomer, the product is an elastomer capped with an epoxy resin. The epoxy terminated rubber is then capable of reacting in the usual manner with curing agents or in the previously discussed advancement reaction (Reaction Scheme 2). 

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