Carbon nanotubes transmission electron microscopy

Single-walled carbon nanotube Transmission electron microscopy Thermogravimetric analysis Volume percent (%)... 

Carbon nanotubes. Scanning electron microscopy. Transmission electron microscopy. Thermo gravimetric analysis. Dynamic mechanical analysis. 

Regarding a historical perspective on carbon nanotubes, very small diameter (less than 10 nm) carbon filaments were observed in the 1970 s through synthesis of vapor grown carbon fibers prepared by the decomposition of benzene at 1100°C in the presence of Fe catalyst particles of 10 nm diameter [11, 12]. However, no detailed systematic studies of such very thin filaments were reported in these early years, and it was not until lijima s observation of carbon nanotubes by high resolution transmission electron microscopy (HRTEM) that the carbon nanotube field was seriously launched. A direct stimulus to the systematic study of carbon filaments of very small diameters came from the discovery of fullerenes by Kroto, Smalley, and coworkers [1], The realization that the terminations of the carbon nanotubes were fullerene-like caps or hemispheres explained why the smallest diameter carbon nanotube observed would be the same as the diameter of the Ceo molecule, though theoretical predictions suggest that nanotubes arc more stable than fullerenes of the same radius [13]. The lijima observation heralded the entry of many scientists into the field of carbon nanotubes, stimulated especially by the un-... 

The field of carbon nanotube research was launched in 1991 by the initial experimental observation of carbon nanotubes by transmission electron microscopy (TEM) [151], and the subsequent report of conditions for the synthesis of large quantities of nanotubes [152,153]. Though early work was done on... 

The earliest observations of carbon nanotubes with very small (nanometer) diameters [151, 158, 159] are shown in Fig. 14. Here we see results of high resolution transmission electron microscopy (TEM) measurements, providing evidence for m-long multi-layer carbon nanotubes, with cross-sections showing several concentric coaxial nanotubes and a hollow core. One nanotube has... 

Several structural characterisations of carbon nanotubes (CNTs) with the cylindrical graphite are reviewed from the viewpoint of transmission electron microscopy (TEM). Especially, electron energy loss spectroscopy (EELS) by using an energy-fdtered TEM is applied to reveal the dependence of fine structure of EELS on the diameter and the anisotropic features of CNTs. 

Many years have passed since the early days of AFM, when adhesion was seen as a hindrance, and it is now regarded as a useful parameter for identification of material as well as a key to understanding many important processes in biological function. In this area, the ability of AFM to map spatial variations of adhesion has not yet been fully exploited but in future could prove to be particularly useful. At present, the chemical nature and interaction area of the AFM probe are still rarely characterized to a desirable level. This may be improved dramatically by the use of nanotubes, carbon or otherwise, with functionalized end groups. However, reliance on other measurement techniques, such as transmission electron microscopy and field ion microscopy, will probably be essential in order to fully evaluate the tip-sample systems under investigation. 

Fig. 2.1 Transmission electron microscopy (TEM) images of pristine single-walled (a) and multi-walled carbon nanotubes (b)...

Application of transmission electron microscopy (TEM) techniques on heterogeneous catalysis covers a wide range of solid catalysts, including supported metal particles, transition metal oxides, zeolites and carbon nanotubes and nanofibers etc. 

Fig. 3 Structure of fullerenes Cso, C70, Cso and single-wall carbon nanotube. The figures were taken with permission of Prof. C. Dekker from the image gallery found at http //online.itp.ucsb.edu/online/qhalLc98/dekker/. Transmission electron microscopy image of multi-wall carbon nanotube (MWCNT) treated with iodinated and platinate DNA. The figure was taken from [24] with kind permission from Prof. P. Sadler...

Since it was initially reported [21], several methods have been presented in order to attach DNA onto CNTs, including adsorption. First, transmission electron microscopy showed that the DNA molecules tended to cover the surface of the nanotubes evenly, suggesting a strong interaction with the carbon surface [24]. 

Five years after the discovery of fullerenes, Iijima reported in 19911 a novel form of organized carbon which consists of hollow cylindrical structures, a few nanometers in diameter and some micrometers long. Although hollow carbon nanofibers had been prepared for several decades, their walls had never been resolved by High-Resolution Transmission Electron Microscopy (HRTEM). These HRTEM images allowed Iijima to conclude that the walls of the so-called multi-walled carbon nanotubes (MWCNTs) are made up of several concentric cylinders, each being formed by a graphene sheet rolled... 

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