Carbon black Particle surface chemical composition

In the rubber industry the distribution of particle size is considered to be important as it affects the mechanical properties and performance. Aggregate size also varies with particle size. Aggregates can have any shape or morphology. The fundamental property of the filler used in a filled elastomer is the particle size. This affects the reinforcement of elastomer most strongly. One of the sources of reinforcement between the carbon black surface and the rubber matrix is the van der Waals force attraction. Also, rubber chains are grafted onto the carbon black surface by covalent bonds. The interaction is caused by a reaction between the functional group at the carbon black particle surface and free radicals on polymer chains. Hence, filler-rubber interface is made up of complex physical-chemical interaction. The adhesion at the rubber-filler interface also affects the reinforcement of rubber. When the polymer composites are filled with spherical filler (aspect ratio of the particle is equal to unity), the modulus of the composite depends on the modulus, density, size, shape, volume ratio, and number of the incorporated particles. 

The physicochemical properties of carbon are highly dependent on its surface structure and chemical composition [66—68], The type and content of surface species, particle shape and size, pore-size distribution, BET surface area and pore-opening are of critical importance in the use of carbons as anode material. These properties have a major influence on (9IR, reversible capacity <2R, and the rate capability and safety of the battery. The surface chemical composition depends on the raw materials (carbon precursors), the production process, and the history of the carbon. Surface groups containing H, O, S, N, P, halogens, and other elements have been identified on carbon blacks [66, 67]. There is also ash on the surface of carbon and this typically contains Ca, Si, Fe, Al, and V. Ash and acidic oxides enhance the adsorption of the more polar compounds and electrolytes [66]. 

The composition and the chemical structure of the surfaces of carbon blacks, since they can fix substances by chemical adsorption, thus creating insulating layers between particles. This makes impossible the formation of electroconducting structures. To prevent this problem the surface of the carbon black particles is cleaned by heat treatments in vacuum or in an inert atmosphere at 2000°C. 

The link between exposure to air pollutants and adverse health effects is well established, but the causal biological mechanisms are not clear and this is especially the case for particulate matter health effects. Airborne particulate matter is extremely variable in chemical composition, size and morphology all parameters of possible health relevance. This and the different health endpoints affected by exposure to ambient PM make the situation very complex. It may well be that more than one particle characteristic is needed to effectively describe the harmful outcomes of exposure. Possible parameters under discussion are particle number concentration, which is dominated by particles below 100 nm in size the so-called ultrafines [33], particle surface area concentration, which is dominated by particles around 200-800 nm in diameter [34, 35], black carbon or black smoke [36], or the reactivity of particles with respect to redox reactions, or their potential to form radical oxidative species (ROS) [37]. These and some other alternative particulate indicators are currently discussed [38] and investigated in several large European and US studies such as ESCAPE and Transphorm2. 

Carbon black is the best UV screening compound and provides long-term protection. Carbon black not only screens out UV but also inhibits photooxidation through a complex series of autooxidative mechanisms. Not only is the particle size of carbon black important (the best performance is in the range of 15-25 nm), but also the chemical composition of its surface. It was proven experimentally that the best results were obtained when Channel Black was used. Channel Black is no longer manufactured by the channel process but by... 

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