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Carbon acyclic carbonate

The chemical produced in the greatest amount through CO2 utilization is urea. According to the international fertilization association, 157 million tons of urea were produced in 2010. Other chemicals produced through CO2 utilization are cyclic carbonates, acyclic carbonates, polyalkylene carbonates, Asahi Kasei polycarbonates, carbamic acid esters, oxazolidinones, polyurethanes, carboxylic acids and esters, lactones, formic acid, and methanol. The amounts of various organic chemicals produced through carbon dioxide utilization throughout the world are shown in Table 9.3 [88]. [Pg.194]

The Wiener index was originally defined only for acyclic graphs and was initially called the path number [6]. "The path number, W, is defined as the sum of the distances between any two carbon atoms in the molecule in terms of carbon-carbon bonds". Hosoya extended the Wiener index and defined it as the half-sum of the off diagonal elements of a distance matrix D in the hydrogen-depleted molecular graph of Eq, (15), where dij is an element of the distance matrix D and gives the shortest path between atoms i and j. [Pg.410]

Division II. Acyclic compounds Isocyclic stem nuclei). The carbon... [Pg.1115]

Recent syntheses of steroids apply efficient strategies in which open-chain or monocyclic educts with appropiate side-chains are stereoselectively cyclized in one step to a tri- or tetracyclic steroid precursor. These procedures mimic the biochemical synthesis scheme where acyclic, achiral squalene is first oxidized to a 2,3-epoxide containing one chiral carbon atom and then enzymatically cyclized to lanostetol with no less than seven asymmetric centres (W.S. Johnson, 1%8, 1976 E.E. van Tamden, 1968). [Pg.279]

Unsaturated branched acyclic hydrocarbons are named as derivatives of the chain that contains the maximum number of double and/or triple bonds. When a choice exists, priority goes in sequence to (1) the chain with the greatest number of carbon atoms and (2) the chain containing the maximum number of double bonds. [Pg.4]

Aldehydes. When the group —C(=0)H, usually written —CHO, is attached to carbon at one (or both) end(s) of a linear acyclic chain the name is formed by adding the suffix -al (or -dial) to the name of the hydrocarbon containing the same number of carbon atoms. Examples are butanal for CHjCHjCHjCHO and propanedial for, OHCCH CHO. [Pg.26]

When the aldehyde group is directly attached to a carbon atom of a ring system, the suffix -carbaldehyde is added to the name of the ring system, e.g., 2-naphthalenecarbaldehyde. When the aldehyde group is separated from the ring by a chain of carbon atoms, the compound is named (1) as a derivative of the acyclic system or (2) by conjunctive nomenclature, for example, (1) (2-naphthyl)propionaldehyde or (2) 2-naphthalenepropionaldehyde. [Pg.26]

Many trivial names exist for acids these are listed in Table 1.11. Generally, radicals are formed by replacing -ic acid by -oyL When a trivial name is given to an acyclic monoacid or diacid, the numeral 1 is always given as locant to the carbon atom of a carboxyl group in the acid or to the carbon atom with a free valence in the radical RCO—. [Pg.30]

When the asymmetric carbon atoms in a chiral compound are part of a ring, the isomerism is more complex than in acyclic compounds. A cyclic compound which has two different asymmetric carbons with different sets of substituent groups attached has a total of 2 = 4 optical isomers an enantiometric pair of cis isomers and an enantiometric pair of trans isomers. However, when the two asymmetric centers have the same set of substituent groups attached, the cis isomer is a meso compound and only the trans isomer is chiral. (See Fig. 1.15.)... [Pg.47]

Onium ions of small and large heterocyclics are usually produced by electrophilic attack on a heteroatom. In three- and four-membered rings nucleophilic attack on an adjacent carbon follows immediately, in most cases, and ring opening stabilizes the molecule. In large rings the onium ion behaves as would its acyclic analog, except where aromaticity or transannular reactions come into play (each with its electronic and steric pre-conditions). A wide diversity of reactions is observed. [Pg.18]

Electron deficient carbon-carbon double bonds are resistant to attack by the electrophilic reagents of Section 5.05.4.2.2(t), and are usually converted to oxiranes by nucleophilic oxidants. The most widely used of these is the hydroperoxide ion (Scheme 79). Since epoxidation by hydroperoxide ion proceeds through an intermediate ct-carbonyl anion, the reaction of acyclic alkenes is not necessarily stereospecific (Scheme 80) (unlike the case of epoxidation with electrophilic agents (Section 5.05.4.2.2(f)) the stereochemical aspects of this and other epoxidations are reviewed at length in (B-73MI50500)). [Pg.117]

Diazoalkanes add to the carbon-carbon double bonds of 2,3-diphenylthiirene 1-oxide and 1,1-dioxide. The adducts lose SO or SO2 to give pyrazoles and related compounds (Scheme 103) (80CB1632). Mesoionic oxazolones (75CLH53), 4-methyl-5-phenyl-l,2-dithiolene-3-thione (80JOU395) and pyrylium betaines (72JOC3838) react similarly via intermediate adducts (Scheme 104). Enamines (Scheme 96) and ynamines add to the double bond of 2,3-diarylthiirene 1,1-dioxides to give acyclic and cyclic sulfones by a thermal. [Pg.167]

In the main, the physical and chemical properties of saturated and partially unsaturated alicyclic compounds closely resemble those of the analogous acyclic compounds formally derived by cleavage of the carbon ring at a point remote from any functionality. Relatively small, but often significant, differences in properties arise from conformational effects, and from strain effects in small rings, and these differences can be striking in properties which are particularly sensitive to molecular shape. [Pg.2]

The stereochemistry of radical addition of hydrogen bromide to alkenes has been studied with both acyclic and cyclic alkenes. Anti addition is favored.This is contrary to what would be expected if the s[p- carbon of the radical were rapidly rotating or inverting with respect to the remainder of the molecule ... [Pg.709]

It has generally been assumed that phosphorous oxychloride-pyridine dehydrations, the elimination of sulfonates, and other base catalyzed eliminations (see below) proceed by an E2 mechanism (see e.g. ref. 214, 215, 216). Concerted base catalyzed eliminations in acyclic systems follow the Saytzelf orientation rule i.e., proceed toward the most substituted carbon), as do eliminations (see ref 214). However, the best geometrical arrangement of the four centers involved in 2 eliminations is anti-coplanar and in the cyclohexane system only the tran -diaxial situation provides this. [Pg.325]

Coupling reactions and related fluoroalkylations with polytTuoioalkyl halides are induced by vanous reagents, among them metals such as copper and zinc, or by an electrochemical cell. More recently, examples of carbon-carbon bond forma tion by coupling of unsaturated fluorides have been reported Both acyclic and cyclic fluoroolefins of the type (Rp)2C=CFRp undergo reducUve dimerization on treatment with phosphines [42] (equation 33) The reaction shown in equation 33 IS also accompbshed electrocheimcally but less cleanly [43]... [Pg.304]

The acid-catalyzed reaction of acetophenone with acyclic secondary amines results in the formation of the expected enamine and a rearrangement product. The latter product arises from the transfer of one of the amino N-alkyl groups to the cnamine s carbon to produce a ketimine (53a). [Pg.68]

The formation of acyclic sulfones is favored by increasing substitution at the a-carbon of the sulfonyl chloride and also of the enamine (97,100). [Pg.147]

The mechanism of the Cook-Heilbron reaction between a-aminonitriles and dithioformic ester 6 proceeds via an acyclic intermediate 7, as proven by its isolation in several cases. Nucleophilic attack of the amine function on the sulfur-bearing carbon leads to the elimination of hydrogen sulphide. Cyclization of the acyclic thiacetoamide results in a five membered ring which aromatises favourably to give 5-amino-2-benzylthiazole 8. [Pg.276]

Interconversion between two tautomeric structures can occur via discrete cationic or anionic intermediates (scheme 24, where T is an anion capable of reacting with a proton at a minimum of two distinct sites). Alternatively, interconversion can occur by simultaneous loss and gain of different protons (scheme 25, w here T has the same definition as in scheme 24). These mechanisms are well established for acyclic compounds, but they have been much less thoroughly investigated for heteroaromatic systems. The rate of interconversion of two tautomers is greatest when both of the alternative atoms to which the mobile proton can be attached arc hetero atoms, and isolation of the separate isomers is usually impossible in this case. If one of the alternative atoms involved in the tautomerization is carbon, the rate of interconversion is somewhat slower, but still fast. When both of the atoms in question are carbon, however, interconversion is... [Pg.317]

Polya s Theorem clearly showed the way to the general enumeration of all acyclic hydrocarbons, irrespective of how many double or triple bonds they might have but it was to be 35 years before this enumeration was carried out. In two papers [ReaR72,76] I obtained the solution to this general problem in both the structural isomer and stereoisomer cases, as generating functions in three variables. Of these variables, x marks the number of carbon atoms, y the number of double bonds, and z the number of triple bonds. The de- rivation of these generating functions was Polya theory all the way — a succession of applications of Polya s Theorem with occasional use of Otter s result. The derivation was really rather tedious, but the generating functions, once obtained, can be used to compute the... [Pg.108]

Another common ring system is the norbornane, or bicyclo[2.2.1.)heptane, structure. Like decalin, norbornane is a bicycloalkane, so called because two rings would have to be broken open to generate an acyclic structure. Its systematic name, bicyclo[2.2.1 heptane, reflects the fact that the molecule has seven carbons, is bicyclic, and has three "bridges" of 2, 2, and 1 carbon atoms connecting the two bridgehead carbons. [Pg.129]

Steroids are plant and animal lipids with a characteristic tetracyclic carbon skeleton. Like the eicosanoids, steroids occur widely in body tissues and have a large variety of physiological activities. Steroids are closely related to terpenoids and arise biosynthetically from the triterpene lanosterol. Lanosterol, in turn, arises from cationic cyclization of the acyclic hydrocarbon squalene. [Pg.1091]


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See also in sourсe #XX -- [ Pg.172 ]




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