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Calcium dichloride

CaCl2 calcium chloride, preferred to calcium dichloride... [Pg.521]

CaCl2 Calcium dichloride Calcium(II) chloride 9. La(I3)3 Lanthanum tris(triiodide) Lanthanum(III ) ftriiodide)... [Pg.110]

Calcium bis[tetrahydroborate(l-)] may be prepared from sodium tetra-hydroborate( 1 -) and calcium dichloride by cation exchange11 in a suitable solvent such as dimethylformamide,12 an amine13,14 or an alcohol.13,14 A particularly good preparation of very pure Ca[BH4]2 involves the reaction of calcium dihydride with the triethylamine-borane adduct.15,16 This method may also be used for the preparation of other tetrahydroborates of alkali and alkaline earth metals. The triethylamine-borane adduct17 may be synthesized in a variety of ways, e.g., from triethylamine, sodium tetrahydro-borate(l —), and trichloroborane 18 from a trialkoxyborane, aluminum metal, and hydrogen in the presence of triethylamine 19 or by hydrogenation under pressure of a mixture of triethylborane and triethylamine.20 The triethylamine-borane adduct is a colorless liquid (mp — 2°). It is stable to air and moisture at room temperature and it is easily purified by vacuum distillation (bp 95-96°/12 torr). [Pg.17]

Why is calcium dichloride not the correct systematic name for CaCl2 ... [Pg.46]

Dimethyl H-phosphonate reacts with calcium dichloride at 70 °C, with manganese acetate at 112 °C, and with calcium nitrate at 115 °C. Kinetic investigations [304] have shown that the reaction takes place as a bimolecular substitution of the second order. There is no difference in the reaction rate of the substitution of both alkyl groups. In general, it decreases with increase in the length of the carbon chain in the alkoxy group. [Pg.88]

Other Reductions. Ductile, pure zirconium has been made by a two-stage sodium reduction of zirconium tetrachloride (68) in which the tetrachloride and sodium are continuously fed into a stirred reactor to form zirconium dichloride [13762-26-0], heating with additional sodium yields zirconium metal. Leaching with water removes the sodium chloride from the zirconium. Bomb reduction of pure zirconium tetrafluoride with calcium also produces pure metal (69). [Pg.430]

Arsenic trifluoride (arsenic(III) fluoride), AsF, can be prepared by reaction of arsenic trioxide with a mixture of sulfuric acid and calcium fluoride or even better with fluorosulfonic acid. Chlorine reacts with ice-cold arsenic trifluoride to produce a hygroscopic soHd compound, arsenic dichloride trifluoride [14933-43-8] ASCI2F35 consisting of AsQ. and AsF ions (21). Arsenic trifluoride forms a stable adduct, 2AsF2 SSO, with sulfur trioxide and reacts with nitrosyl fluoride to give nitrosonium hexafluoroarsenate(V) [18535-07-4] [NO][AsFg]. [Pg.333]

Dichlorides and e2thers are the main by-products in this reaction. Treatment with base produces propylene oxide. Specialty epoxides, eg, butylene oxide, are also produced on an industrial scale by means of HOCl generated from calcium hypochlorite and acetic acid followed by dehydrohalogenation with base. [Pg.467]

Reaction of HOCl, formed from calcium hypochlorite and CO2, with highly substituted alkenes in CH2CI2 is a convenient route to aHyUc chlorides (111). Ketones are chlorinated to a-chloroketones by reaction with HOCl Acetone initially gives CH2COCH2CI (112). Methyl ethyl ketone gives 78% CH3CHCICOCH3, 15% CH3CH2COCH2CI, and 7% dichlorides (113). [Pg.468]

A. Bis i-methoxyphenyl)tellurium Dichloride. In a dry, 500-ml., three-necked, round-bottomed flask equipped with a thermometer and a reflux condenser fitted with a calcium chloride drying tube are placed 27.0 g. (0.1 mole) of tellurium tetrachloride (Note 1) and 64.8 g. (0.6 mole) of dry anisole (Note 2). The mixture is heated to 160 over a period... [Pg.18]

The checkers distilled the anisole from calcium sulfate before use. This reagent functions not only as a reactant, but also as solvent. In some similar preparations the intermediate trichloride is rather insoluble, as in the case of bis(3-methyl-4-methoxyphenyl)tellurium dichloride. The addition of co-solvents such as bis-(2-methoxyethyl) ether is beneficial. ... [Pg.19]

For recovery of tetrahydrofuran, the condensate from the cooling traps and the low-boiling material from the fractionations are combined, cooled in an ice bath, and treated carefully with 15-20 cc. of 40 per cent alkali. The upper layer is separated, dried with a little calcium chloride, and distilled. The recovered tetrahydrofuran, b.p. 64-67°, weighs 20-22 g. (17-19 per cent of the original material). The residue (12-14 g-) remaining after disdllation of the tetrahydrofuran distils at 43-45°/io mm. and is tetramethylene dichloride. [Pg.85]

Selective hydroxylation with osmium tetroxide (one equivalent in ether-pyridine at 0 ) converts (27) to a solid mixture of stereoisomeric diols (28a) which can be converted to the corresponding secondary monotoluene-sulfonate (28b) by treatment with /7-toluenesulfonyl chloride in methylene dichloride-pyridine and then by pinacol rearrangement in tetrahydrofuran-lithium perchlorate -calcium carbonate into the unconjugated cyclohepte-none (29) in 41-48 % over-all yield from (27). Mild acid-catalyzed hydrolysis of the ketal-ketone (29) removes the ketal more drastic conditions by heating at 100° in 2 hydrochloric acid for 24 hr gives the conjugated diketone (30). [Pg.364]

Primary Chlorides Dry sodium cyanide (30 g, 0.61 mole) is added to 150 ml of dimethyl sulfoxide in a flask fitted with a stirrer, reflux condenser, dropping funnel, and thermometer. The thick slurry is heated on a steam bath to 90° and the steam bath is then removed. The halide (0.5 mole of monochloride or 0.25 mole of dichloride) is slowly added to the stirred mixture, causing the temperature to increase immediately. The rate of addition should be adjusted so that the temperature of the reaction does not go above about 160°. After all the halide is added (about 10 minutes) the mixture is stirred for 10 minutes more, or until the temperature drops below 50°. In the preparation of mononitriles, the reaction mixture is then poured into water, and the product is extracted with chloroform or ether. The extract is washed several times with saturated sodium chloride solution then dried over calcium chloride, and the product is distilled. [Pg.140]

Boron trifluoride-acetic acid complex Harshaw Chemical Co., Allied Chemical Co. 1,5-Cyclooctadiene A, MCB Sulfur dichloride MCB Boron trifluoride etherate EK, MCB Mercuric acetate MCB Norbornene MCB Calcium carbide MCB Pinacol EK, MCB... [Pg.163]

These give rise to the same dangerous reactions as chromium halides. Iron dichloride and trichloride detonate in contact with sodium or potassium. There is also a violent combustion of an iron trichloride/calcium carbide mixture, which leads to the formation of melted iron. [Pg.205]

Zinc gives an explosive reaction with manganese dichloride, whereas with calcium chloride, which was in a galvanised iron container, the detonation is blamed on the overpressure created by the release of hydrogen, which is formed in these conditions. [Pg.209]

The electrolyte is made by in situ chlorination of vanadium to vanadium dichloride in a molten salt bath. Higher valent chlorides are difficult to retain in the bath and thus are not preferred. The molten bath, which is formed by sodium chloride or an equimolar mixture of potassium chloride-sodium chloride or of potassium chloride-lithium chloride or of sodium chloride-calcium chloride, is contained in a graphite crucible. The crucible also serves as an anode. Electrolysis is conducted at a temperature about 50 °C above the melting point of the salt bath, using an iron or a molybdenum cathode and a cathode current density of 25 to 75 A dnT2. The overall electrochemical deposition reaction involves the formation and the discharge of the divalent ionic species, V2+ ... [Pg.720]

The quality of the refined metal, and the current efficiency strongly depend on the soluble vanadium in the bath and the quality of the anode feed. As the amount of vanadium in the anode decreases, the current efficiency and the purity of the refined product also decrease. A laboratory preparation of the metal with a purity of better than 99.5%, containing low levels of nitrogen (30-50 ppm) and of oxygen (400-1000 ppm) has been possible. The purity obtainable with potassium chloride-lithium chloride-vanadium dichloride and with sodium chloride-calcium chloride-vanadium dichloride mixtures is better than that obtainable with other molten salt mixtures. The major impurities are iron and chromium. Aluminum also gets dissolved in the melt due to chemical and electrochemical reactions but its concentrations in the electrolyte and in the final product have been found to be quite low. The average current efficiency of the process is about 70%, with a metal recovery of 80 to 85%. [Pg.720]

Toluene, the major solvent, was stirred for three days with several portions of sulphuric acid, washed, dried, and stored over calcium hydride on a vacuum rack. The toluene was distilled out immediately prior to the reaction. The dichlorides were vacuum distilled at the time of the reaction into three fractions, and the middle fraction, about 60% of the total, used. The dichlorides were obtained from Petrach, stored in a nitrogen glove bag and handled by syringe. [Pg.102]


See other pages where Calcium dichloride is mentioned: [Pg.233]    [Pg.1637]    [Pg.38]    [Pg.510]    [Pg.103]    [Pg.46]    [Pg.118]    [Pg.1291]    [Pg.234]    [Pg.233]    [Pg.143]    [Pg.755]    [Pg.792]    [Pg.233]    [Pg.1637]    [Pg.38]    [Pg.510]    [Pg.103]    [Pg.46]    [Pg.118]    [Pg.1291]    [Pg.234]    [Pg.233]    [Pg.143]    [Pg.755]    [Pg.792]    [Pg.540]    [Pg.541]    [Pg.127]    [Pg.472]    [Pg.191]    [Pg.400]    [Pg.131]    [Pg.185]    [Pg.540]    [Pg.541]    [Pg.420]   
See also in sourсe #XX -- [ Pg.233 ]

See also in sourсe #XX -- [ Pg.88 ]

See also in sourсe #XX -- [ Pg.233 ]




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