C-parameter

C PARAMETERS SHOULD MATCH NUMBER OF ELEMENTS, NODE.S, ETC. USED IN A PROBLEM... 

Note The speed of the motor ean be varied by vai-ying the frequeney alone but this docs not provide satisfactory performance, A variation in frequeney causes an inverse variation in the flux, for the same system voltage. The strength of magnetic field, p, develops, the torque and moves the rotor, but at lower speeds. / would be reduced, which would raise 0 , and lead the magnetic circuit to saturation. For higher s )ccds, / would be r.nised, but that would reduee which would adversely diminish the torque. Hence frequency variation alone is not recommended practice for speed control. The recommended practiee is to keep V/fas constant, to maintain the motor s vital operatin.c parameters, i.e. its torque and 0 ,. within acceptable limits. 

Fig. 31 Crystal structure of Rb sNb30Ft8. Projection on the plane (001). Numbers in brackets are the atom coordinates on the z-axis in percents of c parameter. Structure of NbOFj chains and NbFf polyhedron. Reproduced from [209], A. I. Agulyansky, V. E. Zavodnik, V. Y. Kuznetzov et al. Neorgan. Mater. 27 (1991) 380, Copyright 1991, with permission of Nauka (Russian Academy of Sciences) publishing.

The hiding of the pyroelectric coefficients seems to be correlated to the maximum c parameter, which in turn corresponds to the transition temperature. The shift along the Oz direction, Az, of the niobium atoms, which are located within the octahedrons, is responsible for the compound s polar properties. When c is at its maximum, this shift is enhanced and leads apparently to maximum spontaneous polarization P The value of Ps increases in the temperature range of 300 to 490K and then decreases at temperatures above 490°K. 

The numbers in parentheses correspond to 1 estimated standard deviation (esd), except those for the Cpf Cn ratio, which correspond to 3 esd. The values of n and m shown are the smallest integers for which the ratio (n + m)/n lies within the experimental error limits of the measured axial ratio < Fe-<=R — t + e. The c parameters in the bottom line refer to the supercells corresponding to the underlined (n + ro)/n values ... 

The reaction between hydrogen and oxygen leads to the formation of water. This reaction has extended explosive regimes with respect to the p,T,c-parameters. A mechanistic analysis of the elementary reactions is available and the explosion mechanisms are imderstood in detail. Accordingly, this reaction serves well as a model for other dangerous processes in the explosive regime such as many oxidations with pure oxygen. 

Figure 5.138. Program COMPSEG Dimensionless concentration of desired product YR versus dimensionless time THETA obtained by varying THETAMIX (0.03, 0.1,0.3, and 0.6, curves D, B, A and C). Parameter values used ETA=0.3, BETA=2000, DA=1.0.

The E and C parameters for Ga(III) have been revised from the original paper, as seen in Table I, and originally gave a predicted log Kx with azide of 3.84. 

The variation of the unit cell parameters versus temperature is reported in Figure 2. For the as-synthesized sample, at room temperature, the cell parameter are a=7.5675, b=l 8.1187, c=26.0605 A and the cell volume is 3573.2 A3. In the first step of heating (T <120 °C) only small variation of the cell parameters are shown. The volume variation is mostly due to the c parameter shortening, since it is the most subjected to temperature induced modifications. Between 120 and 360 °C a remains almost constant, c decreases of 0.1%, while b slightly increase-up to 215 °C- and subsequently regains its initial value. The combination of these variations leads an inflection in the volume contraction, slowing down its decrease. Above 390 °C the cell volume remains almost constant and only minor variations in the parameters are observed. The final values obtained after the refinement at 715 °C accounted a variation of -0.25, +0.07, -0.77 and -0.95% for a, b, c and V respectively. The minor variation of the cell parameters above 450 °C indicates that at this temperature the dehydration process is almost fulfilled. The TG curve in flowing air shows that the total mass variation of the as-synthesized phase is 15.8%. Dehydration process is almost fulfilled at about 500 °C above this temperature only... 

To overcome such a problem, a silicon heater of negligible heat capacity was added to each detector to trim its sensitivity by a slight change of the (detector) temperature around the working temperature (see Section 16.6). Due to the steep dependence on T of the R and C parameters, changes in detector temperatures of the order of 1 mK are needed for the equalization of the detector response. 

Although the energies of the spectroscopic states of first row d2 ions were shown in Table 18.4, compilations exist for all gaseous metal ions. The standard reference is a series of volumes published by the National Institute of Standards and Technology (C. E. Moore, Atomic Energy Levels, National Bureau of Standards Circular 467, Vol. I, II, and III, 1949). Table 18.5 shows the energies for the spectroscopic states in dn ions in terms of the Racah B and C parameters. 

For the analogous bromide, SnN shortens to 249.6 pm, SnBr = 266.7 pm, Sn/C parameters remain similar, CSnBr angles are reduced and CSnN angles increased V... 

A sample of a strontium titanium sulfide Sr TiS3 was found to have a unit cell in which the repeat distance of the T1S3 chains, cTis, was found to be 0.30 nm and that of the Sr chains, cSr, was found to be 0.54 nm (Fig. 4.38). It is found that 5.5 Sr units fit with 10 TiS3 units. What is (a) the composition and (b) the approximate unit cell c parameter Another preparation has a composition Srj i2TiS3. (c) What is the new approximate unit cell c parameter ... 

The OPLS model is an example of pair potential where non-bonded interactions are represented through Coulomb and Lennard-Jones terms interacting between sites centred on nuclei (equation (51). Within this model, each atomic nucleus has an interaction site, except CH groups that are treated as united atoms centered on the carbon. It is important to note that no special functions were found to be needed to describe hydrogen bonding and there are no additional interaction sites for lone pairs. Another important point is that standard combining rules are used for the Lennard-Jones interactions such that An = (Ai As )1/2 and Cu = (C Cy)1/2. The A and C parameters may also be expressed in terms of Lennard-Jones o s and e s as A = 4ei Oi and C ... 

In general, W0 estimates are the most accurate, whereas the b estimates are the least accurate. For the c parameter, the poorest accuracy was observed at low c values. 

While this example of the Robinson annulation is clearly not enantioselec-tive, the same antibody converts the mero-ketone [120] into the Wieland-Miescher (WM) decalenedione product kcM = 0.086 min-1 and Km = 2.34 mM at 25°C, parameters that give an impressive ER of 3.6 x 106. Good evidence suggests that the mechanism of the reaction involves the formation of a ketimine with the e-amino group of a buried lysine residue in the antibody, as shown in Fig. 39. Most significantly, the reaction delivers the ( )-(+)-WM product in 96% ee (by polarimetry) and in 95% ee by nmr and hplc analysis for a 100 mg scale reaction. A recent report tells that this antibody is to be made commercially available at a cost of 100 for 10 mg. The realization of that objective would mark the start of a new era of application of abzymes to organic stereoselective synthesis. 

It should be kept in mind that this type of study, treated here in terms of single complexes, acquires greater importance when carried out on a series of homologous complexes. This allows one to evaluate how the electronic and/or structural variations of the ligand influence the reorganization processes of the solvent molecules. In fact, such a comparison has recently led to a reinterpretation of the A °c parameter also in terms of the structural reorganisations of the first coordination sphere.18,19 For example, if one compares the A-Sr°c values for... 

Table 4. The R Rfj=p-iatio and parameter C in Eq. (14) for various polymer architectures. The C-parameter gives information on the internal flexibility (C=0 inflexible particles, C= 0.2 flexible chain behavior) ...

Fig. 7.16 (a) Lattice parameters and (b) voltage vs x for two forms of Li TiSj. The c parameter for the layered (IT) form is the distance between the layers the a parameter in the cubic (spinel) form is the edge of the cubic unit cell. Data from Sinha and Murphy (1986), Dahn and McKinnon (1984), and Dahn and Haering (1981b). 

C. Parameters for Orthogonality Evaluation Between HPLC and CE Systems... 

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