Boron-carbon-aluminum system

Table 1. Carbon superelectrophiles and their isoelectronic boron and aluminum systems. ...

Included in the term nonoxide ceramics are all non-electrically conducting materials in the boron-carbon-silicon-aluminum system. The industrially most important representatives, apart from carbon (see Section 5.7.4), are silicon carbide (SiC), silicon nitride (Si3N4), boron carbide (B4C), boron nitride (BN) and aluminum nitride (AIN). 

Aluminum, boron, carbon, iron, nitrogen, oxygen, phosphorus, sulfur and titanium are the common impurities in the SoG-Si feedstock. Arsenic and antimony are frequently used as doping agents. Transition metals (Co, Cu, Cr, Fe, Mn, Mo, Ni, V, W, and Zr), alkali and alkali-earth impurities (Li, Mg, and Na), as well as Bi, Ga, Ge, In, Pb, Sn, Te, and Zn may appear in the SoG-Si feedstock. A thermochemical database that covers these elements has recently been developed at SINTEF Materials and Chemistry, which has been designed for use within the composition space associated with the SoG-Si materials. All the binary and several critical ternary subsystems have been assessed and calculated results have been validated with the reliable experimental data in the literature. The database can be regarded as the state-of-art equilibrium relations in the Si-based multicomponent system. 

Electronic-Grade MMCs. Metal-matrix composites can be tailored to have optimal thermal and physical properties to meet requirements of electronic packaging systems, eg, cotes, substrates, carriers, and housings. A controUed thermal expansion space tmss, ie, one having a high precision dimensional tolerance in space environment, was developed from a carbon fiber (pitch-based)/Al composite. Continuous boron fiber-reinforced aluminum composites made by diffusion bonding have been used as heat sinks in chip carrier multilayer boards. 

As discussed above, thermobaric weapons contain monopropellants or secondary explosives and energetic particles. Boron, aluminum, silicon, titanium, magnesium, zirconium and carbon can be considered to be energetic particles. The main advantage of thermobaric systems is that they release large quantities of heat and pressure, often in amounts larger than for only secondary explosives. 

The reduction of various carbon-nitrogen ir-systems to saturated derivatives with metal hydrides, principally aluminum- and boron-based reagents, provides highly useful processes for the preparation of amines and related functionalities. 

Polymerization of carbon suboxide in heterogeneous systems, i.e. polymer precipitating from the reaction solution, by various initiators was examined qualitatively by Hegar (9). It was found that the best catalysts in cyclohexane solution (at 0°C., then room temperature) were triethylamine and pyridine. Boron trifluoride was somewhat less effective, while sulfuric acid was inefficient and slow. With aluminum chloride the catalyst particles were rapidly coated with polymer, and no significant amount of polymer could be obtained. 

Aluminum is an effective sintering aid for B4C and SiC ceramics if combined with elemental boron and carbon. Phase relations in the B-C-Al-Si system may hence indicate suitable procedures to initiate transient liquid phase or enhanced solid-state sintering. Furthermore, liquid A1 may be used to infiltrate porous B4C bodies acting as a reinforcing phase. 

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