Bonding adhesive, characterization

Moisture-related durability of wood-adhesive bonds is characterized in a standard delamination test according to SN EN 302-2 2004 [11]. 

The application of these principles to an actual adhesively bonded joint is anything but straightforward. One problem is the lack of pertinent information on the performance of adhesive joints. Most test data generated by adhesive producers are only useful for comparison purposes and are of limited use to the design engineer. Also, there is only limited information available on the performance of bonded joints exposed to service environments, while subjected to static or dynamic stresses. Adequate adhesive characterization and prediction of joint durability remain goals for the future. 

In most cases the strength of the adhesive bond is characterized acceptably by Wab values derived from the above presented theory. Often, especially in apolar systems, a close correlation exists between W b the macroscopic properties of the composite in particulate filled polymers, also shown, for example, by the dependence of composite strength on Wab presented in Fig. 9 for PP/CaC03 composites. However, the bond strengths determined with various mechanical tests are usually much lower than the values derived from... 

ISO 10354 1992 Adhesives - Characterization of durability of structural-adhesive-bonded assemblies - Wedge rupture test... 

Extensive use of the three-dimensional solubility parameters for predicting adhesion seems not to have been made, although its additional flexibility should make it successful over a wider range of conditions than the single-parameter approach. Some recent studies involving dental adhesion employed the method with success. Asmussen and Uno fl40 successfully correlated the shear bond strength of various dental adhesive resins, characterized in terms of their three-... 

Another illustrative example of the application of FTIR spectroscopy to problems of interest in adhesion science is provided by the work of Taylor and Boerio on plasma polymerized silica-like films as primers for structural adhesive bonding [15]. Mostly these films have been deposited in a microwave reactor using hexamethyldisiloxane (HMDSO) as monomer and oxygen as the carrier gas. Transmission FTIR spectra of HMDSO monomer were characterized by strong... 

The novel element in these models is the introduction of a third phase in the Hashin-Rosen model, which lies between the two main phases (inclusions and matrix) and contributes to the progressive unfolding of the properties of the inclusions to those of the matrix, without discontinuities. Then, these models incoporate all transition properties of a thin boundary-layer of the matrix near the inclusions. Thus, this pseudo-phase characterizes the effectiveness of the bonding between phases and defines a adhesion factor of the composite. 

Surface Morphology. The initial Integrity of an adhesively bonded system depends on the surface oxide porosity and microscopic roughness features resulting from etching or anodization pretreatments. (17) The SAA surface characterized in this study consists of a thick (9 ym), porous columnar layer which provides excellent corrosion resistance in both humid and aggressive (i.e., Cl ) media. I The thinner FPL oxide provides a suitable substrate surface for evaluating the candidate inhibitors. 

Adsorbed NTMP exhibits a pH-dependent surface coverage on anodized aluminum, which Includes a region characterized by a multilayer of hydrogen-bonded phosphonate molecules. These thick layers are weak and fall to provide good bond durability in a humid environment. NTMP monolayers are protective against hydration and are compatible with a nitrile-modified epoxy adhesive, but not with an epoxy-polyamide primer topcoat. 

The interaction of two substrates, the bond strength of adhesives are frequently measured by the peel test [76]. The results can often be related to the reversible work of adhesion. Due to its physical nature such a measurement is impossible to carry out for particulate filled polymers. Even interfacial shear strength widely applied for the characterization of matrix/fiber adhesion cannot be used in particulate filled polymers. Interfacial adhesion of the components is usually deduced indirectly from the mechanical properties of composites with the help of models describing composition dependence. Such models must also take into account interfacial interactions. 

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