Bonds INDEX

The modern quantum-mechanical approach to bonding indicates... 

The stereochemistry is usually expressed in structure diagrams by wedged and hashed bonds. A wedge indicates that the substituent is in ont of a reference plane and a hashed bond indicates that the substituent is pointing away om the viewer (behind the reference plane). This projection is applied both to tetrahe-... 

For each of the following molecules that contain polar covalent bonds indicate the positive and negative ends of the dipole using the symbol -<- Refer to Table 1 2 as needed... 

Bond dissociation energies refer to bond indicated in structural formula for each substance... 

Eclipsed conformation (Section 3 1) Conformation in which bonds on adjacent atoms are aligned with one another For example the C—H bonds indicated in the structure shown are eclipsed... 

The multiplicities of signals due to Jqh coupling (splitting occurs due to CH coupling across one bond) indicates the bonding mode of the C atoms, whether quaternary (R4C, singlet S), tertiary doublet D), secondary (R2CH2, triplet T) or primary (RCHj, quartet Q). 

Azulene does have an appreciable dipole moment (0.8 The essentially single-bond nature of the shared bond indicates, however, that the conjugation is principally around the periphery of the molecule. Several MO calculations have been applied to azulene. At the MNDO and STO-3G levels, structures with considerable bond alternation are found as the minimum-energy structures. Calculations which include electron correlation effects give a delocalized n system as the minimum-energy structure. ... 

The major difference in reactivity between CF3OF and FCIO3 lies in the capacity of the former to react with olefins without the benefit of an electron releasing group and even with electron deficient olefins such as a,y5-un-saturated ketones. Reactions with nonactivated double bonds indicate the presence of an oc-fluoro cationic intermediate [e.g., (64)] as exemplified by the reaction with the -3-ketone (63), which yields the fluorophenol (65). 

Bond indices /3 and /3 can be assigned to each edge of the hydrogen suppressed graph at the two vertices, / and... 

Finally, the atomic and bond indices can be combined to give indices for the whole unit. The zeroth-order connectivity indices and Oy for the entire molecule can be calculated as a summation over the vertices of the hydrogen suppressed graph, that is ... 

Use the 6-E/5- convention to show the direction of expected polarity for each of the bonds indicated. 

Norbornane has a conformationally locked boat cyclohexane ring (Section 4.5) in which carbons 1 and 4 are joined by an additional CH group. Note how, in drawing this structure, a break in the rear bond indicates that the vertical bond crosses in front of it. Making a molecular mode) is particularly helpful when trying to see the three-dimensionality of norbornane. 

We see again that there is but one principle which causes a chemical bond between two atoms all chemical bonds form because electrons are placed simultaneously near two positive nuclei. The term covalent bond indicates that the most stable distribution of the electrons (as far as energy is concerned) is symmetrical between the two atoms. When the bonding electrons are somewhat closer to one of the atoms than the other, the bond is said to have ionic character. The term ionic bond indicates the electrons are displaced so much toward one atom that it is a good approximation to represent the bonded... 

Lithium dibutylcuprate reacted with ( )-l, 3-butadienyl p-tosyl sulfone affording (Z)-2-octenyl p-tosyl sulfone. In the reaction of allyl ( )- and (Z)-l, 3-dibutadienyl sulfones with lithium dibutylcuprate or lithium (Z)-di(l-butenyl) cuprate, the major compound obtained was of (Z)-geometry around the 2,3-double bond, indicating that (Z)-selectivity is not so high in this reaction (56-79%)408-... 

AT-heterocyclic carbenes show a pure donor nature. Comparing them to other monodentate ligands such as phosphines and amines on several metal-carbonyl complexes showed the significantly increased donor capacity relative to phosphines, even to trialkylphosphines, while the 7r-acceptor capability of the NHCs is in the order of those of nitriles and pyridine [29]. This was used to synthesize the metathesis catalysts discussed in the next section. Experimental evidence comes from the fact that it has been shown for several metals that an exchange of phosphines versus NHCs proceeds rapidly and without the need of an excess quantity of the NHC. X-ray structures of the NHC complexes show exceptionally long metal-carbon bonds indicating a different type of bond compared to the Schrock-type carbene double bond. As a result, the reactivity of these NHC complexes is also unique. They are relatively resistant towards an attack by nucleophiles and electrophiles at the divalent carbon atom. 

Fig. 7. Molecular model of cyclododecane in the (gag)4 conformation of the crystalline state according to Dunitz and Shearer (Ref. 12>). The numbers at the bonds indicate the rotational angles...

The properties of some sulfide minerals can be discussed in a reasonably satisfactory way by assigning one or another of the structures of Table I to the sulfur atoms. For some minerals the ligancy of the sulfur atom is equal to its covalence, and for others it is greater, the bonds then having fractional bond numbers. It is often necessary to assign a hybrid structure to the sulfur atoms. I shall assume that the covalent bonds indicated in Table I always have the normal amount of covalent character, as given by the... 

Triphenylphosphonium ylide reacts with the silylene complex 93 which has a highly electrophilic silicon center, to give the corresponding cationic adduct 94 [115]. The lengthening of the PC bond indicates a loss of the double bond character of the ylide and corresponds to the formation of a tetrahedral silicon center with four covalent bonds (Scheme 28). 

In naming olefins, the prefix number indicates the lower numbered carbon atom involved in the double bond, numbering from one end of the molecule. Two or more double bonds in one molecule are possible with the number of double bonds indicated by di- for two double bonds, tri- for three, tetra for four, etc. before the -ene ending (e.g., butadiene). Buta- means four carbons and diene indicates the presence of two double bonds. 

Yields in the above reactions can often be improved by the addition of 1 mole of triphenylphosphine directly to the trifluoroacetic acid solution of the reactants immediately before final work-up. It would appear that the triphenylphosphine functions as a scavenger for TTFA released in the metal-metal exchange reaction, thus protecting the final phenol from further electrophilic thallation and/or oxidation. Validation of the metal-metal exchange mechanism was obtained indirectly by isolation and characterization of an ArTlX2/LTTFA complex directly from the reaction mixture. NMR analysis revealed that this complex still possessed an intact aryl-thallium bond, indicating that it was probably the precursor to the transmetallation products, an aryllead tristrifluoroacetate and TTFA. 

Answer We begiu by drawiug the Newmau projectiou that we would see wheu we look down the bond indicated. This Newman projection will have a methyl group... 

DOPED PA MODELS. We selected two criteria to characterize the structure of the mono- and di-cations. The wavefunctions of the cations at their respective optimized geometries were used to determine Mayer s bond indices which reflect the strength of the interatomic bonds. The differences in the cations and also the neutral molecule emerge very clearly from Table III. 

Table III. Interatomic CC distances (in angstroms) and Bond Indices for C22H24, C2iH23, C22H24 2. Cl labels the center carbon atom, Cl 1 the terminal carbon atom...

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