Bimodal process

Fig. 8a-e Commercial bimodal processes a slurry-loop process, b gas phase—gas phase process, c double slurry loop process, d dual/triple slurry tank process and e dual/triple solution tank process... 

The bimodal profile observed at low catalyst concentration has been explained by a combination of two light generating reactive intermediates in equihbrium with a third dark reaction intermediate which serves as a way station or delay in the chemiexcitation processes. Possible candidates for the three intermediates include those shown as "pooled intermediates". At high catalyst concentration or in imidazole-buffered aqueous-based solvent, the series of intermediates rapidly attain equihbrium and behave kineticaHy as a single kinetic entity, ie, as pooled intermediates (71). Under these latter conditions, the time—intensity profile (Fig. 2) displays the single maximum as a biexponential rise and fall of the intensity which is readily modeled as a typical irreversible, consecutive, unimolecular process ... 

Biological wastewater treatment processes also affect solids characteristics and hence solids separation. Activated sludge solids have been found to have a distinct bimodal distribution with one mode in the supracolloidal to settleable range and another near the border between the colloidal and supracolloidal fractions. The concentrations and size limits in each range are affected by conditions in the... 

The significance of this novel attempt lies in the inclusion of both the additional particle co-ordinate and in a mechanism of particle disruption by primary particle attrition in the population balance. This formulation permits prediction of secondary particle characteristics, e.g. specific surface area expressed as surface area per unit volume or mass of crystal solid (i.e. m /m or m /kg). It can also account for the formation of bimodal particle size distributions, as are observed in many precipitation processes, for which special forms of size-dependent aggregation kernels have been proposed previously. 

K. C. H. Yi, and N. J. Maraschin, Bimodal HOPE Via Gas Phase Process, A New Frontier 1990, Union Carbide Chemicals Plastics Technology Corporation./ Mod. Plast. Int. January 1991, p. 12. 

The bimodal feature in the lower wavelength images is accounted for by the presence of the two processes for which evidence has been presented above. There is also a clear bimodality in the data from 266 nm dissociation. The energy distribution displays peaks at 2.7 and 3.6 eV. This distribution raises further questions since the process creating > 26) at lower... 

Resins with a bimodal molecular weight distribution, as illustrated in Fig. 5.3 b), are more readily processed than those with a most probable molecular weight distribution, but are more likely to be oriented in the solid state and have a somewhat reduced impact resistance. 

The major design concept of polymer monoliths for separation media is the realization of the hierarchical porous structure of mesopores (2-50 nm in diameter) and macropores (larger than 50 nm in diameter). The mesopores provide retentive sites and macropores flow-through channels for effective mobile-phase transport and solute transfer between the mobile phase and the stationary phase. Preparation methods of such monolithic polymers with bimodal pore sizes were disclosed in a US patent (Frechet and Svec, 1994). The two modes of pore-size distribution were characterized with the smaller sized pores ranging less than 200 nm and the larger sized pores greater than 600 nm. In the case of silica monoliths, the concept of hierarchy of pore structures is more clearly realized in the preparation by sol-gel processes followed by mesopore formation (Minakuchi et al., 1996). 

The first process in all cases is the production of the oxidiser in a suitable fine crystal size. A bimodal particle size distribution, obtained by mixing very fine with slightly coarser particles, often gives the best product. The fuel/binder is frequently prepared as a prepolymer so as to assist mixing and also to reduce the time of the later curing process. 

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