5-Benzoyl-4-methylthio

Pyrimidin-2( 1H) -one, 5-fluoro-1 -methyl-4-methylthio-alcoholysis, 3, 96 Pyrimidin-2(lH)-one, 5-hydroxy-benzoylation, 3, 89... 

Ap4A, diadenosine tetraphosphate BBG, Brilliant blue green BzATP, 2 - 3 -0-(4-benzoyl-benzoyl)-ATP cAMP, cyclic AMP CCPA, chlorocyclopentyl adenosine CPA, cyclopentyl adenosine CTP, cytosine triphosphate DPCPX, 8-cyclopentyl-1,3-dipnopylxanthine IP3, inosine triphosphate lpsl, diinosine penta phosphate a,p-meATP, a,p-methylene ATP p.y-meATP, p.y-meihylene ATP 2-MeSADP, 2-methylthio ADP 2-MeSAMP, 2-methylthio AMP 2-MeSATP, 2-methylthio ATP NECA, 5 -W-ethylcarboxamido adenosine PPADS, pyridoxal-phosphate-6-azophenyl-2, 4 -disulfonic acid PLC, phospholipase C RB2, reactive blue 2 TNP-ATP, 2, 3 -0-(2,4,6-trinitrophenyl) ATP. 

Benzoic acid,4-amino-3-[(methylthio)-methyl] -, ethyl ester, 15 Benzoic acid, 2-benzoyl-, methyl ester, 63 Benzoic acid, 4-bromo-, 86 Benzoic acid, 4-chloro-, 86 Benzoic acid, 2,4-dimethoxy-, 31 Benzoic acid, 3,4-dnnethoxy-, 31 Benzoic acid, 3,4-dimethyl-, 31 Benzoic acid, 3,5-dimethyl-, 86 Benzoic acid, 4-hydroxy-, 60 Benzoic acid, 2,4,6-tnmethyl-, 31 methyl ester, 63... 

Indenes, 34 Indole [ 1H Indole], 10 INDOLE, 3-BENZOYL- [METI1ANONE, 1//-INDOL-3-YLPHENYL-], 8 INDOLE, 3-BENZYL- [lff-INDOLE, 3-(PHENYLMETHYL)-], 8 INDOLE, 5-CARBOETHOXY-2-METHYL-] 17/-1NDOLE-5-C ARBOXYLIC ACID, 2-METHYL, ETHYL ESTER], 72 Indole, S-carlioethoxy-2-methyI-3-niethyl-thio-11H Indole-5-carboxyhc acid, 2-methyl-3-(methylthio)-, ethyl ester, 73... 

N-Diphenylmethylen- 374 N-Diphenylmethylen-O-aminocarbonyl- 612 N-[l,3-Diphenyl-propyl-(2) - 374 N-[l,3-Diphenyl-propyliden-(2)]- 374, 377, 380 N-(4-Halogen-phenyI)- 683 N-Heptyl- 375 N-Heptyl-N-acetyl- 376 N-Heptyliden- 375 N-Hcptyliden-O-acetyl- 376 0-(2-Hydroxy-athyl)-N-athoxycarbonyl- 133 N-(4-Hydroxy-phenyl)- 683 0-(2-Hydroxy-l-phenyl-athyI)-N-athoxycarbonyI-aus 0-(ci-AthoxycarbonyI-benzyl)-N-athoxycar-bonyl-hydroxylamin und Lithiumalanat 133 N-Isopropyl- 682 N-Isopropylidcn- 613 N-Methyl- 133, 682 O-Methyl-N-bcnzyliden- 377 O-Methyl-N-benzyliden- 375 0-Methyl-N-(4-chlor-benzyl)- 375 0-Methyl-N-(4-chlor-benzyliden)- 375 N-Methy -N,0-diacetyI- 682 N-(4-Methyl-phenyl)- 683 0-McthyI-N-( 1 -phenyl-athyliden)- 375 N-(4-Methylthio-phenyl)- 684 N-(4-Nitro-benzyl)- 374 N-[4-Nitro-benzyliden - 374, 377 N-(2-Nitro-phenyl)- 562 N-(4-Nitro-phenyl)- 682 N-Nitroso-N-cyclohexyl- 697 N-Octyl- 374 N-Octyl-(2)-N-acetyl- 376 N-Octyliden- 374 N-0ctyliden-(2)-0-acctyl- 376 N-(Pentafluor-phenyl)-0,N-diacetyl- 697 N-Phenyl- 474, 481, 682, 783 N-Phenylacetyl-O-benzoyl- 265 N-(l-Phenyl-athyl)- 374 N-(l-Phenyl-athyl)-N-acetyl- 376 N-(l-Phenyl-athyliden)-374, 613 N-( l-Phenyl-athyliden)-0-acetyl- 376 N-[ 1 -Phenyl-buten-( 1 )-yl-(3)-iden]- 582 N-f4-Phenyl-butyl-(2)-iden]- 581 N-Phcnyl-N,0-diacetyl- 682 N-(4-Phenylthio-phenyl)- 684 N-Propyl-N-cyclohexyl- 376 N-Propyl-N-isopropyl- 376 O-Sulfonyl- 481 N-(4-Sulfonyl-phenyI)- 683 N-(2-Vinyl-phenyl)- 698... 

C6Hs ch3 H CH, c6h5 cooc2h5 5-Benzoyl-4-methyl-thio-l-phenyl-... 5-Benzoyl-2-methyl-4-methylthio-l-phenyl-... 5-Benzoyl-12-di-phenyl-4-methyl-thio-... 75 80 85 120 130 151 5-Benzoyl-4-methyl-thio-... 5-Benzoyl-2-methyl-4-methy/thio-... 5-Benzoyl-4-methyl-thio-2-phenyl-... 5-Benzoyl-2-e thoxy-carbonyl-4-me-thylihio-... 55 60 78 55 (Ol) 170 215 (Ol)... 

Aus Methylamino-essigsaure-ethylester (Sarkosin-ethylester) bzw. 2-Methylamino-l-oxo-l-phenyl-ethan werden mit Dithiocarbonsaure-cyanimid-dimethylester 4-Amino-5-methoxycar-bonyl-l-methyl-2-methylthio-imidazol bzw. 4-Amino-5-benzoyl-l-methyl-2-methylthio-imidazol hergestellt303. 

Benzoic acid, 4 amino 3 [ (methylthio) methyl] -, ethyl ester 56,15 Benzoic acid, 2-benzoyl-, methyl ester, 56, 63... 

Thiochroman-4-ones fragment on treatment with dimethylsulfox-onium methylide [Eq. (14)].86 When R3 = H, both 40 and 41 are produced at 50° whereas only 40 is obtained at room temperature the process is believed to involve 42. In a mechanistically similar reaction, 3-inethylthiochroman-4-one yields 3,4,5,()-tetrahydro-3,5,5-trimethyl-3-[o-(methylthio)benzoyl]-2//-l-benzotliiocin-6-one (43).87... 

Transformation of Methyl- methyl-5-acetamido-4-0-benzoyl-3,5,9-trideoxy-9-iodo-7-0-[(4-methylphenoxy)thiocarbonyl]-8-0-[(methylthio)carbonyl]-p-D-q ycBro-D-qa aclo-2-nonulopyranosid onate 43 to Methyl- methyl-5-acetamido-4-0 -benzoyl-3,5,7,9-tetradeoxy-8-0 -[(methylthio)carbonyl]- -d-galacto-2-nonulopyranosid ona te 44 with TBTH and AIBN [50]... 

Oxidation of 3,5-bis(methylthio)-l,2,4-triazines (81) with potassium permanganate afforded the 3-monosulfones (241) which could be hydrolyzed to 5-methylthio-l,2,4-triazin-3-ones (242) (69BSF3670). 6-Benzyl-3-thioxo-l,2,4-triazin-5-one (243) with potassium permanganate afforded the 6-benzoyl-3-sulfonic acid (244) (67BSF2551). Similarly, 5-amino-... 

Ar) —COOR + HCI] 5-Chloro-7-(4-fluoro-benzoyl)-2-hydroxy- EI0b2. 431 (Educt) S-Chloro-2-hydroxy-7-(4-methylthio-benzoyl)- EI0b2, 431 (F -> SR) 3-(2,2-Dichloro-l-hydroxy-3,3.3-irifluoro-propyl)-]-(2.4,6-trnncthyl-phenyl)- EI0b2. 374 (Educl)... 

A mixture of l-(2,3,5-tri-0-benzoyl-p-D-ribofuranosyl)-4-methylthio-l,2-dihydro-l,3,5-triazin-2-one (0.5875 g), absolute methanol (5 ml) and a normal methanolic sodium methoxide solution (1.2 ml) is stirred at room temperature with the exclusion of atmospheric moisture (a guard tube filled with potassium hydroxide pellets is fitted to the reaction vessel). The starting compound passes into solution in the course of 5 min. The resulting solution is allowed to stand at room temperature for 45 min and then the cations are removed by passage of the solution through a column packed with 10 ml of a weakly acidic cation exchange resin in the H+ form prewashed with water and methanol. The methanolic effluent (60 ml) is evaporated under reduced pressure at 30°C, the residue is dissolved in methanol (20 ml) and the solution once again is evaporated and the l-p-D-ribofuranosyl-4-methoxy-l,2-dihydro-l,3,5-triazin-2-one was obtained. 

Acid-catalyzed fusion of 7-methylthio-l,2,3-triazolo[4,5-d]pyrimidine (257) with l-0-acetyl-2,3,5-tri-0-benzoyl-D-ribofuranose (254) gave the... 

An interesting steric effect caused by a neighboring group ( Fernwir-kung ) was encoimtered in 1935 by Lieser and Leckzyck, who found that treatment of methyl 6-0-benzoyl-2-0-[(methylthio)thiocarbonyl]-/3-D-glu-copyranoside (III) with silver carbonate in methanol effected conversion... 

Lieser and Leckzyck treated methyl 6-0-benzoyl-2-0-[(methylthio)thio-carbonylj- -D-glucopyranoside in absolute methanol with silver carbonate and obtained, in about 10% yield, a compound which, from its analysis, appeared to be a 2,4-(dimethyl orthocarbonate) derivative V. On the other hand, the 0 anomer III (see p. 96), under the same conditions, gave methyl 6-0-benzoyl-2-0-(methoxycarbonyl)- 8-D-g]ucopyranoside (IV). 

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