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Base , 81 measuring strength

Based on breaking length, which measures strength per unit area. [Pg.360]

Different product sorts (20-22,24-26) are marked in the score plot of spectral NIR measurements (Fig. 4). Sorts 23 and 31 are in separate classes outside the range of this plot. A gradient is seen in the plot, indicating the chemical differences among the sorts the %DE are increasing in the 20->25/26 direction while the opposite holds for the Ca-based gel strength measm-ements. [Pg.545]

The thermodynamic tendency of a substance to act as a Lewis base. The strength of a Lewis base depends on the nature of the acid with which the Lewis base forms a Lewis adduct. Hence, comparative measures of Lewis basicities are given by equilibrium constants for the formation of the adducts by a common reference acid. See Lewis Base Nucleophilicity Hard Bases Soft Bases Donor Number... [Pg.420]

As a strong base, the strength of caustic soda solution can be determined by titration with a standard solution of strong acid using a color indicator or by potentiometric titration using a pH meter. Also, concentration of sodium in an aqueous solution can be measured by AA or ICP spectrophotometry. [Pg.870]

Kjj is the base dissociation constant, or base ionization constant, that measures a base s strength. Some values are given for bases in Table 3. [Pg.114]

Spectroscopic methods have been used in isolation for the determination of base characteristics. A number of studies, for example Reference [24], have correlated the O Is binding energy measured by X-ray photoelectron spectroscopy (XPS) to the determination of base site strength. It has been proposed that decreasing binding energy relates to an increased abihty for electron pair donation and hence... [Pg.824]

Equation (4-11) illustrates the role of solvent basicity in determining the strength of a solute acid. Equation (4-11) is, however, of little direct use in analytical acid-base measurements because we have no methods of evaluating the absolute constants acidity basicity suppose we wish to Compare the ionization constants of two acids HA and HA" in a solvent SH. From (4-11)... [Pg.63]

In a very new report, Fujino et al. challenge the two-isomerization-mechanism concept on the basis of their time-resolved and time-integrated femtosecond fluorescence measurements of B-azobenzene following excitation of the (7t,7t ) State. They use the extremely weak fluorescence (cf. Figure 1.8) as an indicator for the population of the emitting state. From the ratios of their measured fluorescence lifetimes (S2 0.11 ps Sp 0.5 ps) and the radiative lifetimes deduced from the (absorption-spectra-based) oscillator strengths, they determine the fluorescence quantum yields 2.5310 for the emission and 7.5410" for the Si—>So emission. By comparison... [Pg.36]

Dispersive and specific interactions are considered to contribute independently to the adsorption of probe molecules at the adsorbent surface. It was presented that the adhesion of the fibre-matrix interface depends clearly on the measured strength of acid/base interactions of both fibre and polymer-matrix. Fowkes [2,3] indicated also that the surface of fillers can be chemically modified to enhance acid-base interaction and increase adsorption. [Pg.466]

The outputs from finite element analysis will tell the chemist many of the important predictive characteristics of the part. The effects of load (stress, strain, and deflection) are measured. Material selection based on strength and part dimensions and tolerances are determined and easily adjusted. The effects of heat (heat transfer and thermal stresses) are determined as well as material selection based on conduction and insulation. Special applications such as bending and vibration characteristics, crashworthiness, fatigue, and noise can be determined. The design requirements, such as expected loads, load cycle cost, mass targets, and budget targets, can be predicted and met with proper application of the FEA tool. [Pg.52]

If an acid is strong, its conjugate base has no measurable strength. Thus the Cl ion, which is the conjugate base of the strong acid HCl, is an extremely weak base. [Pg.604]

Acidity is a measure of the tendency of a compound to give up a proton. Basicity is a measure of a compound s affinity for a proton. The stronger the acid, the weaker is its conjugate base. The strength of an acid is given by the acid dissociation constant (KJ. Approximate values are as... [Pg.56]

Different modes of strength testing have evolved based on different levels of technologic sophistication. The practical impHcation of contextual dependencies on the provided mechanical environment of the strength measures must be considered during selection of the appropriate mode of measurement. In this regard, equipment that can measure strength in different modes is more efficient in terms of both initial... [Pg.1370]


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