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Authenticity criterion

The CD spectrum of an authentic 310-helix has been reported for Ac(a-MeVal)8-OtBu in TFE (Figure 3). 73 This shows a ratio of [0]nii /[0]nji of 0.4 and a very weak positive band near 190 nm, both in agreement with theory. 65 Therefore, a criterion based upon the ratio of [O]nji /[0]jiJT appears to be reasonable for distinguishing between 310- and a-helix a ratio near... [Pg.746]

Since isocitric acid is quite expensive, adjusting it to the normal range in an adulterated juice would not be economically practical. The price situation could change, however, if heavy emphasis is placed on this acid as a criterion of authenticity. [Pg.407]

It is often observed that when PCR products from ancient remains are cloned, they contain a large number of random substitutions which are believed to be due to damage present in extracted DNA.10 When this error frequency is compared to that of a control template of modem, presumably undamaged DNA, the increased number of errors itself may indicate that the PCR products stem from a damaged template and thus that it likely represents an old sequence.13 However, it should be remembered that if the presumed ancient sequence in reality stems from a contaminating modem sequence present in only a few copies, the PCR product will have gone through many more cycles of polymerization before the plateau phase of the amplification is reached. For example, if an amplification product contains twice as many errors as a control DNA amplified for 30 cycles, that result could be due to errors in the initial template or to the presence of template in a 10- to 100-fold lower concentration (A. von Haeseler and S. Paabo, unpublished, 1991). Thus, because the concentration of ancient DNA is hard or impossible to determine accurately, error rates in amplification products may be difficult to use as a criterion of authenticity. [Pg.418]

The problem of the computation accuracy of these kinetic parameters is dependent first of all on the validity of the copolymer composition determination. As a criterion here one may use the closeness to each other of the values of this composition obtained via the different experimental methods. It is possible to judge about the degree of such a closeness using Tables 6.1 and 6.2 where the data on both chemical analysis and spectroscopy are presented. One can see that, as for the considered cases, the different experimental methods provide quite close values of the copolymer compositions within the accuracy in the range of 5%. Authentic evidence concerning the feasibility to reach such a degree of accuracy is furnished by the data on copolymer composition obtained via independent methods in the different systems, for instance, under the copolymerization of p-chlorstyrene with methyl acrylate [32], of 4-methylstyrene with methyl methacrylate or acrylonitrile [213], and also of styrene with acrylic or methacrylic acids [214],... [Pg.57]

Much of Janzen s criticism has been justified the spin distribution in benzyl radicals themselves shows little substituent dependence44 dimeth-ylanilinium radicals, by Walter s structural criterion of type S, have proved to be of type 045 the original data on triarylaminium and triarylmethyl radicals, used to exemplify type S, have proved ambiguous45-47 authenticated S type behavior has been found only in a small group of acyclic aminyl... [Pg.222]

H.-L. Schmidt, M. Butzenlechner, A. RoBmann, S. Schwarz, H. Kexel, K. Kempe (1993) Inter-and intramolecular isotope correlations in organic compounds as a criterion for authenticity identification and origin assignment. Z. Lebensm. Unters. Forsch. 196. 105-110... [Pg.652]

In the case of interactive authentication, as with all interactive protocols, an important criterion is the round complexity, i.e., the number of rounds needed. Message complexity, the number of separate messages sent during a protocol execution, essentially equals round complexity in 2-party protocols, but bit complexity, the number of bits sent, is as important as usual. The bit complexity of non-interactive authentication is the length of the signature. [Pg.106]

If this criterion were only made for good prekeys, the scheme would still be secure, but effectiveness of authentication would only be error-free if the risk bearer s entity acted correctly. [Pg.196]

Proof sketch. The implicit and explicit requirements from Definitions 7.1 and 7.31 and the property to be polynomial-time in the interface inputs alone are easy to see. Among the criteria from Theorem 7.34, effectiveness of authentication is easily derived from that in the one-time scheme, and the security for the risk bearer is completely identical to that in the underlying one-time scheme. (Recall that the fact that the signer s entity bases many one-time key pairs on the same prekey makes no formal difference at all in Criterion 2 of Theorem 7.34.)... [Pg.329]

Proof. The implicit and explicit requirements fi-om Definitions 7.1 and 7.31 are obviously fulfilled, and effectiveness of authentication and the security for the risk bearer are shown as in Lemma 9.12. Furthermore, it is clear that every successful forgery /that is not the correct signature in the same position y in the sequence is provable. It remains to be shown that the reuse of halves of the one-time secret keys does not increase the likelihood with which such a forgery is the correct signature. Thus, with all the quantifiers as in Criterion 3 of Theorem 7.34 in the version of Definition 9.1, it has to be shown that for/= (m , s ) with s = (j, x , y ) ... [Pg.340]

As early as the 1980 s, it was possible to purchase O.lg of such enriched compounds for 300 to 600, depending on whether the carbonyl, methoxy or ring was labelled. This rendered invalid the 8 C criterion for authenticating vanillins and lead to the investigation of deuterium NMR as a potential method to discriminate between synthetic and natural products (ref. 6). [Pg.515]

Currently, the assay of carbohydrates is a very important criterion for the quality control of drinks and foodstuffs, especially in dietary products. Assay of carbohydrates is also very important in the fields of monitoring of food-labeling claims, analysis of sweeteners, bulking agents, and fat substitutes as well as for establishing authenticity and in the fermentation monitoring in the production of alcoholic beverages. [Pg.854]


See other pages where Authenticity criterion is mentioned: [Pg.152]    [Pg.49]    [Pg.277]    [Pg.141]    [Pg.123]    [Pg.511]    [Pg.54]    [Pg.267]    [Pg.249]    [Pg.532]    [Pg.296]    [Pg.636]    [Pg.198]    [Pg.293]    [Pg.103]    [Pg.511]    [Pg.267]    [Pg.98]    [Pg.716]    [Pg.130]    [Pg.118]    [Pg.725]    [Pg.68]    [Pg.644]    [Pg.437]   
See also in sourсe #XX -- [ Pg.47 ]

See also in sourсe #XX -- [ Pg.47 ]




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Authenticity

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