Fluid bed atmospheric pressure

Today the circulating fluidized bed (CFB) has become the dominating design for combustors operated at atmospheric pressure. Pressurized circulating fluidized bed combustors are under development for combined power cycle applications, but so far no clear advantages have been revealed yet. For this reason the existing commercial pressurized fluid bed systems are bubbling beds. 

Both the atmospheric and pressurized fluid bed combustors bum coal with limestone or dolomite in a fluid bed that, with recent modifications to the system, allows the limestone sorbent to take up about 90% of the sulfur that would normally be emitted as sulfur dioxide. In addition, combustion can achieved at a lower temperatnre than in a conventional combustor thereby reducing the formation of nitrogen oxide(s). 

Fluidized-bed combustors can be either atmospheric or pressurized (Yeager and Preston, 1986). The atmospheric type operates at normal atmospheric pressure while the pressurized type operates at pressures 6-16 times higher than normal atmospheric pressure. The pressurized fluid-bed boiler offers a higher efficiency and less waste products than the atmospheric fluid-bed boiler. There is also a circulating (entrained) bed combustor which allows for finer coal feed, better fuel mixing, higher efficiency, as weU as an increased sulfur dioxide capture. 

Fluid Coking", developed in 1953. The reaction proceeds at atmospheric pressure, at about SOO-SSOT, in a reactor whose feed is mixed in a fluidized bed of hot coke which maintains the desired temperature. 

Freeze drying has also been carried out at atmospheric pressure in fluid beds using circulating refrigerated gas. Vacuum-type vibrating conveyors, rotating multishelf dryers and vacuum pans can be used as can dielectric and microwave heating. 

The previous example was a rather unique application and not a typical case for fluidization. Although some fluidized bed reactions are executed at elevated pressure, like the naphtha reforming, most are used at atmospheric or at low pressures. The proceeding conceptual sketch. Figure 8.2.4, gives the most important features of a fluid-bed, cataljdic reactor. 

The process is centred around two separate circulating fluid bed (CEB) reactors. They both operate at atmospheric pressure ... 

Viscous flow permeametry measured near atmospheric pressure offers the advantages of experimental simplicity and a means of measuring the external or envelope area of a powder sample which is otherwise not readily available by any adsorption method. The usefulness of measuring the external surface area rather than the BET or total surface area becomes evident if the data is to be correlated with fluid flow through a powder bed or with the average particle size. 

Consider a fluidized bed operated at an elevated temperature, e.g. 800°C, and under atmospheric pressure with ah. The scale model is to be operated with air at ambient temperature and pressure. The fluid density and viscosity will be significantly different for these two conditions, e.g. the gas density of the cold bed is 3.5 times the density of the hot bed. In order to maintain a constant ratio of particle-to-fluid density, the density of the solid particles in the cold bed must be 3.5 times that in the hot bed. As long as the solid density is set, the Archimedes number and the Froude number are used to determine the particle diameter and the superficial velocity of the model, respectively. It is important to note at this point that the rale of similarity requires the two beds to be geometrically similar in construction with identical normalized size distributions and sphericity. It is easy to prove that the length scales (Z, D) of the ambient temperature model are much lower than those in the hot bed. Thus, an ambient bed of modest size can simulate a rather large hot bed under atmospheric pressure. 

In view of these considerations, a large amount of effort is reported in the scientific press on the development of a process to produce benzene from n-hexane by combined cyclization and dehydrogenation. w-Hexane has a low Research octane number of only 24.8 and can be separated in fair purities from virgin naphthas by simple distillation. Recently, an announcement was made of a process in the laboratory stage for aromatiza-tion of n-hexane (16). The process utilizes a chromia-alumina catalyst at 900° F., atmospheric pressure, and a liquid space velocity of about one volume of liquid per volume of catalyst per hour. The liquid product contains about 36% benzene with 64% of hexane plus olefin. The catalyst was shown to be regenerable with a mixture of air and nitrogen. The tests were made on a unit of the fixed-bed type, but it was indicated that the fluid technique probably could be used. If commercial application of this or similar processes can be achieved economically, it could be of immense help in relieving the benzene short-age. 

The conditions in countercurrent fixed beds have been investigated for many years in order to improve the understanding of two-phase flow and to develop reliable design methods. However the proposed correlations available for fluid dynamics and mass transfer are practically all based on experimental data obtained at atmospheric pressure. Extrapolation of the results to high pressure is questionable and not recommended. Moreover the results of systematic investigations in the high-pressure range are scarce in the open literature. 

Regeneration via Fluid-Bed Combustion. Table V gives the conditions of runs presented here—essentially atmospheric pressure, superficial residence time of 1 sec, excess air (115% of stoichiometric), silica bed solids. Temperatures of 983° and 1038°C were investigated. No... 

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