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Applications analytical extraction

The polarity index is a measure of the polarity of the solvent, which is often the most important factor in the solvent choice for the particular application. In extraction processes, the tenet that like dissolves like (and conversely, opposites do not attract ) is the primary consideration in choosing the solvent for extraction, partitioning, and/or analytical conditions. For example, hexane often provides a selective extraction for nonpolar analytes, and toluene may provide more selectivity for aromatic analytes. [Pg.755]

A single SFE/ESE instrument may perform (i) pressurised C02 (SFE), (ii) pressurised C02/modifier and (iii) pressurised modifier (i.e. ASE /ESE , organic solvent) extractions. The division between SFE and ASE /ESE blurs when high percentages of modifier are used. Each method has its own unique advantages and applications. ESE is a viable method to conduct matrix/analyte extraction provided a solvent with good solvating power for the analyte is selected. Sample clean-up is necessary for certain matrix/analyte combinations. In some circumstances studied [498], SFE may offer a better choice since recoveries are comparable but the clean-up step is not necessary. [Pg.123]

The most common gas-liquid pair encountered in analytical extractions is the air-water interface. The extraction methods discussed in this chapter are most applicable to organic solutes that are considered nonvolatile and semivolatile. However, it is possible to extend these techniques to more volatile chemicals as long as careful consideration of the tendency of the solute to volatilize is made throughout the extraction process. [Pg.43]

In recent years, supercritical fluid extraction has received widespread attention for the removal of non- or low-volatile organic components from liquid and solid matrices. This process has many potential applications like analytical extractions, applications in the food and drug industry, activated carbon regeneration or soil remediation. [Pg.229]

Extraction can be used as an efficient and selective sample preparation method before analysis by chromatographic, spectroscopic, electroanalytical, or electrophoretic methods (see for example [5-10]). International norms from the International Standards Organization, US Food and Drug Administration, and US Environmental Protection Agency recommend application of extraction methods in analysis of food products and environmental and pharmaceutical samples. Novel ideas and new views concerning extraction have led to many controversies about terminology and to reallocation and softening of the boundaries between extraction and other analytical sample treatment techniques. [Pg.123]

Exhaustive extraction involves the quantitative removal of a solute, and selective extraction, the separation of two or more solutes from each other. One classical application of an exhaustive analytical extraction is the ether extraction of iron(III) chloride from hydrochloric acid solutions. The extraction is not strictly quantitative in that a small fraction remains unextracted. Therefore the method is best suited to the removal of relatively large amounts of iron (several grams) from small amounts of such metals as nickel, cobalt, manganese, chromium, titanium, or aluminum. It is of interest that iron(II) remains unextracted. [Pg.429]

Diketones. Beta-diketones such as acetylacetone, benzoyl-acetone, and isopropyltropolone are well known for their applications in analytical extraction of actinides. These compounds are weak acids due to tautomerization thus they can act as cation exchange extractants. Trivalent actinide [M(III)] extraction by the reagent (HA) at low aqueous acid concentration where the compound behaves both as cation exchanger and coordinator probably follows the reaction... [Pg.83]

Apart from automating the matrix application process, it is critical to evaluate the resulting matrix crystals and coating for analyte extraction, localization, and effect on tissue architecture. Several reports have shown that even for standard analytes mixed with matrices, there is an uneven distribution of the analyte within the MALDI crystals and that sample preparation influences the resulting distribution [18-20], Thus, other active areas of research are focused on optimizing matrix application and sample preparation protocols. [Pg.360]

SPME Appheations Guide, Supelco 1www.sigma-aldrich.comL Over 600 references, categorized according to application, analyte/matrix, and extraction condition. [Pg.553]


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