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4- amino-5-nitro-l,2,3-triazole

Kinetics of thermal decomposition of explosives 3-amino-5-nitro-l,2,4-triazole (ANTA) and its derivatives [38], l,3-bis(l,2,4-triazol-3-amino)-2,4,6-trinitrobenzene [39] and transition metal salts of NTO [40]. [Pg.185]

ANTA 3-Amino-5-nitro-l,2,4-triazole ( French abbreviation ANT)... [Pg.487]

Treatment of the ammonium salt of 3,5-dinitro-1,2,4-triazole (113) with hydrazine hydrate leads to selective reduction of one of the nitro groups to yield 3-amino-5-nitro-1,2,4-triazole (ANTA) (114), a high performance explosive (calculated VOD 8460 m/s) possessing thermal stability (m.p. 238 °C) and an extremely low sensitivity to impact. ANTA (114) is also synthesized from the nitration of 3-acetyl-l,2,4-triazole with anhydrous nitric acid in acetic anhydride at subambient temperature followed by hydrolysis of the acetyl functionality. The ammonium salt of 3,5-dinitro-l,2,4-triazole (113) is itself a useful explosive which forms a eutectic with ammonium nitrate. ... [Pg.309]

Diazotiation 3-amino-5-acetamido-l,2,4-triazole and following substitution diazo group on nitro group on the method [392] leads to corresponding nitrotriazole [445], which on the acyl protection relieving gives 5-amino-3-nitro-l,2,4-triazole [262, 446] (Scheme 57). [Pg.37]

New energetic materials were prepared from by perfluoroalkyl-l,2,4-triazoles. For instance, Shreeve et al. obtained 3-nitro-5-trifluoromethyl-1,2,4-triazole 90 by the diazotization of 3-amino-5-trifluoromethyl-l,2,4-triazole in the concentrated sulfuric acid [87], In its turn 3-amino-l,2,4-triazole and 3-nitro-5-trifluoromethyl-1,2,4-triazole were used in the preparation of energetic 3-amino-l,2,4-triazolium 3-nitro-5-trifluoromethyl-l,2,4-triazolate 91. Energetic polymeric material 92 was synthesized containing in the monomer unit ions of 3-nitro-5-trifluoromethyl-1,2,4-triazolate. The yield of polymer is unknown [88]. [Pg.479]

Nitro-l,2,4-triazole (45%) [451] and l-methyl-4-cyano-5-nitropyrazole (42%) [452] were isolated during the oxidation of corresponding aminoazole derivatives by a solution of hydrogen peroxide in trifluoroacetic acid. One of the amino groups in l-acyl-3,5-diamino-l,2,4-triazole is oxidized by hydrogen peroxide in the presence of sodium tungstate [453] (Scheme 59). [Pg.38]

More recently, Stepanov et al. (1989) investigated the acid-base properties of the zwitterion 3.22 which is obtained in the diazotization of 5-amino-3-nitro-l,2,4-triazole. Under alkaline conditions the (Z)-diazoate dianion 3.23 is formed. It can be isomerized thermally to give the (E)-diazoate dianion 3.24. If the solution of this compound is acidified, the primary addition of a proton takes place at the anionic ring nitrogen yielding 3.25, and subsequently the hydrogen-bond-stabilized (Z)-iso-mer (3.26). Further acidification gives the nitrosoamine (3.27). [Pg.61]

Amino derivatives of 1,2,3- and 1,2,4-triazoles are useful precursors to the corresponding nitro-substituted triazoles. 3-Amino-1,2,4-triazole (98) undergoes diazotization on reaction with nitrous acid the resulting diazonium salt (110) can react with a range of nucleophiles, including an aqueous solution of sodium nitrite which yields 3-nitro-1,2,4-triazole (111). Diazotization of 3,5-diamino-l,2,4-triazole (112), followed by heating with an aqueous solution of sodium nitrite, yields 3,5-dinitro-1,2,4-triazole (113). ... [Pg.309]

Gilardi and co-workers reported a synthesis of 4-(trimethylsilyl)-5-nitro-1,2,3-triazole (136) via a cycloaddition between l-nitro-2-(trimethylsilyl)acetylene (134) and trimethylsilyl azide (135). This may provide a route to 4,5-dinitro-l,2,3-triazole via nitrodesilylation or lead to the synthesis of 4-amino-5-nitro-l,2,3-triazole, an isomer of ANTA. [Pg.312]

In aryl- or amino-substituted 1,2,4-triazols the nitro group enters the side chain [269-271], An attempt to realize the nitration of 3,5-bisphenylamino-l,2,4-triazole led to opening of the triazole ring. Picrylurea was isolated as the only reaction product [272], The nitration products of 2-methyl-l,2,3-triazole 1-oxide under mild conditions (20°C) are a mixture of 5-nitro (75%) and 4-nitro (23%) derivatives. Under more... [Pg.20]

Amino-1,2,4-triazolium 4,5-dinitr oimidazolate 742-1301 4-Amino-l,2,4-triazolium 3-nitro-l,2,4-triazolate ... [Pg.216]

A three-component condensation of 3-amino-l, 2,4-triazole (or its 5-Me and 5-methylthio derivatives), 1 and DMF-dimethylacetal afforded 8,9-dihydro[l,2,4]triazolo[l,5-fl]quinazolin-6(7H)-ones (06RCB1224). Condensation of 3,4,5-triamino-l,2,4-triazole with aromatic aldehydes and dimedone afforded partially hydrogenated 9-aryl-[l,2,4]triazolo[5,l-frJquinazolin-8-ones. The structure of 2-amino-6,6-dimethyl-3-(4-nitro-benzylidene)amino-9-(4-nitrophenyl)-5,6,7,9-tetrahydro[l,2,4]triazolo[5,l-fr]-quinazolin-8-one was confirmed by X-ray analysis (05RCB2903). [Pg.105]

Amino-l-nitro-l,2,4-triazole (581), obtained by nitration of 5-amino-triazole with acetyl nitrate, rearranges, on heating, to the nitramino-triazole (582). ° The combined action of sodium hydroxide, potassium iodide, tri-ethylamine, and sodium dihydrogen phosphite on the chloro-nitro-triazole (583) results in a mixture of the rearranged triazole (584), 3-chloro-l,2,4-triazole, and the coupled product (585). The stable betaine (586) has been prepared by treatment of 4-phenyl-1,2,4-triazole with phenacyl bromide, followed by tri-ethylamine. The meso-ionic triazolium thiolate (537 X = S) reacts with chlorine to form the dichloride (587 X = SCU), which has been converted into the betaine (588) by the action of diethyl bromomalonate in the presence of triethylamine. ... [Pg.196]

Fig. 1. HeterocycHc amines usedia azo dyes, (a) 2-Amino-6-nitrohenzothiazo1e [6285-57-0], (b) 3-amiao-5-nitro-2,l-benzisothiazole [14346-19-1], (c) 3-amiQo-4JT-l,2,4-triazole [65312-61 -0], (d) 5-amiQo-l,2,4-thiadiazole [7552-07-0, (e) 4,4 -diamiQo-2,2 -biphenylsulfone [6259-19-4], (f)... Fig. 1. HeterocycHc amines usedia azo dyes, (a) 2-Amino-6-nitrohenzothiazo1e [6285-57-0], (b) 3-amiao-5-nitro-2,l-benzisothiazole [14346-19-1], (c) 3-amiQo-4JT-l,2,4-triazole [65312-61 -0], (d) 5-amiQo-l,2,4-thiadiazole [7552-07-0, (e) 4,4 -diamiQo-2,2 -biphenylsulfone [6259-19-4], (f)...
Substitution of the 4-nitro group in 3,4-dinitrofuroxan 1176 by ammonia occurs readily, even at low temperature. Subsequent treatment of the obtained amine, product 1177, with r-butylamine results in formation of 4-amino-2-(/-butyl)-5-nitro-l,2,3-triazole 1-oxide 1178. However, there must be some additional side products in the reaction mixture, as the isolated yield of compound 1178 is only 17%. Upon treatment with trifluoroperacetic acid, the r-butyl group is removed. The obtained triazole system can exist in two tautomeric forms, 1179 and 1180 however, the 1-oxide form 1179 is strongly favored (Scheme 195) <2003CHE608>. [Pg.131]


See other pages where 4- amino-5-nitro-l,2,3-triazole is mentioned: [Pg.118]    [Pg.174]    [Pg.370]    [Pg.342]    [Pg.118]    [Pg.174]    [Pg.370]    [Pg.342]    [Pg.28]    [Pg.602]    [Pg.309]    [Pg.194]    [Pg.160]    [Pg.349]    [Pg.402]    [Pg.403]    [Pg.142]    [Pg.175]    [Pg.227]    [Pg.371]    [Pg.754]    [Pg.754]    [Pg.60]    [Pg.210]    [Pg.43]    [Pg.286]    [Pg.286]    [Pg.135]    [Pg.354]    [Pg.370]    [Pg.114]   
See also in sourсe #XX -- [ Pg.309 ]




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1- -l,2,4-triazoles

1- Amino-4-nitro

1.2.4- Triazole 5-amino-3-nitro

2- -l,2,3-triazole

2- Amino-l-nitro

4-amino-l,2,4-triazole

Nitro triazoles

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