Amine and azo

Generally, the addition of chlonne or bromine to tnfluoroacetonitrile leads to a mixture of partially halogenated imines, amines and azo alkanes [270, 271] In special cases, such as the HgF2-mediated addition of bromine, N,N dihaloper-fluoro-2-alkylamines can be obtained in good yields [272]... 

Farrell, P.G. and Newton, J. Ionization potentials ofprimary aromatic amines and azo-hydrocarbons. Tetrahedron Lett., p. 5517, 1966. 

Bowman MC, Rushing CR. 1981. Trace-level determination of benzidine, 3,3 -dichlorobenzidine in animal chow wastewater and human urine. In Egan H, ed. Environmental carcinogens - selected methods of analysis. Volmne 4. Some aromatic amines and azo dyes in the general and industrial environment. Lyon, France International Agency for Research on Cancer, 159-174. 

L. Fishbein u. H. Egan, Environmental Carcinogens, Selected Methods of Analysis, Vol. 4 Some Aromatic Amines and Azo Dyes in the General and Industrial Environment, International Agency for Research on Cancer. 1RAC, Lyon 1981. 

Vol. 4. Some Aromatic Amines and Azo Dyes in the General cmd Industrial Environment (lARC Seientific Publications No. 40). Edited by L. Fishbein, M. Castegnaro, I.K. O Neill H. Bartsch(1981)... 

The other reaction mixtures were analyzed by GLC (OV 101 FID). In these cases it was possible to identify the following compounds substrate, dehalogenated nitro compound, desired aniline dehalogenated aniline. Two reaction intermediates (hydroxy I amine and azo- or hydrazo-compound) were determined as a sum. The selectivities given were determined at the end of the hydrogenation and are defined as... 

Since both molar volume and refractive index are influenced by the actual molecular species present in a solution, molar refraction has some potential value for studying association equilibria. Giles and co-workers (65-68) correlated the method with dielectric constant measurements, and have been the most active users of refractive index for studying compound formation. Reference 68 reviews earlier work (which is sketchy) and lists about forty systems (mostly oxygen containing compounds) that were studied. References 65-67 deal with amide, amine, and azo compounds, plus esters and additional work on alcohols, aldehydes, ketones, and carbohydrates. The method is simple the refractive index of a series of mixtures of varying composition but constant concentration in a solvent is measured. Compound formation is shown by a change in the slope of the n vs. mole fraction plot, such as in Fig. 2-15. 

Meth-Cohn and co-workers derived strong chemical support for the singlet nitrene carbazole pathway from a study of the thermolysis and photolysis of the azide 246.306 Here, the nitrene 247 has two intramolecular pathways open to it, namely, formation of carbazole (249) or phenanthridine (250) apart from intermolecular reactions leading to amine and azo compound (Scheme 48). 

Cancer. Volume IIB fAromatic Amines and Azo Dves). Academic Press, New York, 1974. 

Topics which have formed the subjects of reviews this year include excited state chemistry within zeolites, photoredox reactions in organic synthesis, selectivity control in one-electron reduction, the photochemistry of fullerenes, photochemical P-450 oxygenation of cyclohexene with water sensitized by dihydroxy-coordinated (tetraphenylporphyrinato)antimony(V) hexafluorophosphate, bio-mimetic radical polycyclisations of isoprenoid polyalkenes initiated by photo-induced electron transfer, photoinduced electron transfer involving C o/CjoJ comparisons between the photoinduced electron transfer reactions of 50 and aromatic carbonyl compounds, recent advances in the chemistry of pyrrolidino-fullerenes, ° photoinduced electron transfer in donor-linked fullerenes," supra-molecular model systems,and within dendrimer architecture,photoinduced electron transfer reactions of homoquinones, amines, and azo compounds, photoinduced reactions of five-membered monoheterocyclic compounds of the indigo group, photochemical and polymerisation reactions in solid Qo, photo- and redox-active [2]rotaxanes and [2]catenanes, ° reactions of sulfides and sulfenic acid derivatives with 02( Ag), photoprocesses of sulfoxides and related compounds, semiconductor photocatalysts,chemical fixation and photoreduction of carbon dioxide by metal phthalocyanines, and multiporphyrins as photosynthetic models. 

Polycyclic Aromatic Hydrocarbons [5] Aromatic Amines and Azo-Dyes [6] Mycotoxins [7]... 

N NMR spectra were only described for 1-aryl-3,3-dialkyltriazenes. The signal due to the central nitrogen in RN NpNyR 2 appears at the lowest field. The average shifts of the other nitrogens with respect to Np are 97 to 115 ppm for N and 258 to 293 ppm for N [21 to 23]. A comparison with the shifts of free amines and azo compounds shows for... 

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