Linked fullerene

Imahori H and Sakata Y 1997 Donor-linked fullerenes photoinduced electron transfer and its potential application Adv. Mater. 9 537-46... 

Imahori H, Hagiwara K, Akiyama T, Taniguchi S, Okada T and Sakata Y 1995 Synthesis and photophysical property of porphyrin-linked fullerene Chem. Lett. 265-6... 

Akiyama T, Imahori H, Ajawakom A and Sakata Y 1996 Synthesis and self assembly of porphyrin-linked fullerene on gold surface using S-Au linkage Chem. Lett. 907-8... 

Reaction ofcarboxy- or hydroxy-substituted o-quinodimethanes such as 52, 54 or deprotected 58 lead to Cjq adducts with a functionalizable group. They can be derivatized for example by forming an ester [46,49,50] from the acid or by addition of the hydroxy funchonality to double bonds [49], Addihon products of the para-dihydroxy derivahve 65 can be easily oxidized to the corresponding benzoquinone-linked fullerene with DDQ [48]. The cycloadduct 73 of Cgg with 4-(4-fluoro-3-... 

Evidently, the existence of electronic interactions between the D and A units in the ground state can be unequivocally established on the basis of electrochemical studies. A recent report has reviewed the electrochemical properties of donor-linked fullerenes as a function of the attached chromophores including transition metal structures,... 

Nierengarten J.-F., Eckert J.-F., Felder D., Nicoud J.-F., Armaroli N., Marconi G., Vicinelli V., Boudon C., Gisselbrecht J.-P., Gross M., Hadziioannou G., Krasnikov V., Ouali L., Echegoyen L., Liu S.-G. (2000) Synthrsis and electronic properties of donor-linked fullerenes towards photochemical molecular devices, Carbon, 38, 1587-1598. 

Topics which have formed the subjects of reviews this year include excited state chemistry within zeolites, photoredox reactions in organic synthesis, selectivity control in one-electron reduction, the photochemistry of fullerenes, photochemical P-450 oxygenation of cyclohexene with water sensitized by dihydroxy-coordinated (tetraphenylporphyrinato)antimony(V) hexafluorophosphate, bio-mimetic radical polycyclisations of isoprenoid polyalkenes initiated by photo-induced electron transfer, photoinduced electron transfer involving C o/CjoJ comparisons between the photoinduced electron transfer reactions of 50 and aromatic carbonyl compounds, recent advances in the chemistry of pyrrolidino-fullerenes, ° photoinduced electron transfer in donor-linked fullerenes," supra-molecular model systems,and within dendrimer architecture,photoinduced electron transfer reactions of homoquinones, amines, and azo compounds, photoinduced reactions of five-membered monoheterocyclic compounds of the indigo group, photochemical and polymerisation reactions in solid Qo, photo- and redox-active [2]rotaxanes and [2]catenanes, ° reactions of sulfides and sulfenic acid derivatives with 02( Ag), photoprocesses of sulfoxides and related compounds, semiconductor photocatalysts,chemical fixation and photoreduction of carbon dioxide by metal phthalocyanines, and multiporphyrins as photosynthetic models. 

D. E. Markov, E. Amsterdam, P. W. M. Blom, A. B. Sieval, J. C. Hummelen, Accurate Measurement of the Exciton Diffusion Length in a Conjugated Polymer Using a Heterostructure with a Side-Chain Cross-Linked Fullerene Layer. The Journal of Physical Chemistry A 2005,109, 5266-5274. 

Markov, D.E., Amsterdam, E., Blom, P.W.M., Sieval, A.B., and Hummelen, J.C. (2005) Accurate measurement of the exciton diffusion length in a conjugated polymer using a heterostructure with a side-chain cross-linked fullerene layer. 

Cheng Y-J, Hsieh C-H, He Y, Hsu C-S, Li Y (2010) Combination of indene-C60 bis-adduct and cross-linked fullerene interlayer leading to highly efficient inverted polymer solar cells. JAm Chem Soc 132 17381-17383. doi 10.1021/jal08259n... 

There are several other recent reports on the synthesis (and possibility) of photoinduced electron transfer in supramolecules such as porphyrin linked C60 [146,147], norbomene linked C6o. [148], phthalocya-nine linked fullerene [149], Cu(I) complex linked fullerenes [150], aniline linked fullerenes [151] and oligothiophene linked fullerenes [152]. 

Alkynyl-bridged macrocycUc metal complexes, 704 a-phase, 110 Alternate layers, 731. 751 Alternating Heisenberg model, 786 Amphiphilic molecule, 728 Analogues of TCNQ, 229. 245 Aniline linked fullerenes, 444 Anisotropic conductivity, 758 Anisotropy, 100. 113. 667 Anodic intercalation, 651 of graphite, 653... 

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