Ambient Air Ozone Monitoring

Note For safety reasons ozone should always be used with an ambient air ozone monitor (measuring ranges 0-1 ppm) with a safety shut down procedure. 

Ambient air ozone monitor. Is it necessary to check the ambient air ozone concentration in the lab Yes, it is highly recommended to control the lab environment and connect the monitor to the ozone generator so that the ozone production will be shut off in case of leakage in the system B 2.5... 

Methods of measuring the components of photochemical smog are reviewed in Chapter 6. There have been significant advances in the calibration of instruments for monitoring ozone in ambient air. A method based on the absorption of ultraviolet radiation at 254 nm has been adopted by California for the calibration of air monitoring instruments. The method is based on the use of a commercially available instrument that measures ultraviolet absorption as a transfer standard in the calibration process. 

In addition to the specificity of the monitoring method, an important requirement for the measurement of atmospheric pollutants is the accuracy of the calibration technique. The calibration procedure for the measurement of oxidants or ozone utilizes a stable and reproducible sample of dilute ozone in air. The ozone concentration of this sample is established with a reference method that is not necessarily suitable for monitoring ambient air. This reference method must agree with the scientifically accurate measurement of ozone in the calibration sample. 

Most currently used oxidant and ozone monitors need to be calibrated with a predetermined concentration of ozone in air. Regardless of the principle used to measure ambient ozone or oxidant concentrations, the primary reference standard for calibrating each monitoring device or system should be identical everywhere. This requirement remains to be achieved in practice. Up to June 1975, at least seven calibration procedures were practiced in the United States. These are listed in Table 6-5... 

The analytic principles that have been applied to accumulate air quality data are colorimetry, amperometry, chemiluminescence, and ultraviolet absorption. Calorimetric and amperometric continuous analyzers that use wet chemical techniques (reagent solutions) have been in use as ambient-air monitors for many years. Chemiluminescent analyzers, which measure the amount of chemiluminescence produced when ozone reacts with a gas or solid, were developed to provide a specific and sensitive analysis for ozone and have also been field-tested. Ultraviolet-absorption analyzers are based on a physical detection principle, the absorption of ultraviolet radiation by a substance. They do not use chemical reagents, gases, or solids in their operation and have only recently been field-tested. Ultraviolet-absorption analyzers are ideal as transfer standards, but, as discussed earlier, they have limitations as air monitors, because aerosols, mercury vapor, and some hydrocarbons could, interfere with the accuracy of ozone measurements made in polluted air. 

Differences in measurement methods include analyzer systems based both on the same and on different measurement principles. The average standard deviation in the performance of different chemiluminescent ozone instruments that are sampling the same ambient air both with and without an added ozone concentration of 0.(X)2-0.5 ppm is 6-10%. Field studies comparing an ultraviolet monitor with several chemiluminescent monitors showed correlation coefficients for hourly averages of 0.80-0.95 between various pairs of instruments. Hourly averages for about 500 pairs of values at ambient ozone concentrations of 0.005-0.100 ppm showed deviations of 3-23% between the average values for paired instruments. 

It is important to separate conceptually, and in practice, the calibration process from the monitoring process. Photochemical oxidants consisting primarily of ozone were firrt continuously measured in southern California by measuring the color change of potassium iodide solutions brought into contact with the ambient air. This measurement continues to yield valid photochemical-oxidant data in California. However, it has yielded questionable data at ambient air monitoring sites elsewhere in... 

Since reaction mechanisms and experimental observations are not independent of the system in which they are made, the experimental set-up and how the experiment is run affect the outcome. That means that it must be clear how equipment and procedures affect the outcome when they are chosen. It also means that experimental set-ups and procedures from drinking water treatment cannot be applied on waste water without appropriate evaluation and vice versa. In general, an experimental set-up consists of an ozone generator, reactor, flow meters and on-line analysis of at least the influent and effluent ozone gas concentrations and ambient air monitor (Figure 2-1). Each set-up will be tailored to the experimental goals and the resources available. 

Multi-component hydrocarbon standards to provide accurate calibration of instruments (generally gas chromatographs) used to monitor the concentrations of a wide range of volatile organic hydrocarbon compounds (VOCs) in ambient air. These standards currently contain 30 different hydrocarbon species that are important to photochemical ozone formation, with concentrations ranging down to a few parts per billion by molar value. They are disseminated widely in the United Kingdom and the rest of Europe as calibration standards, and as test mixtures for assessment of the quality of international ambient hydrocarbon measurements (often under the auspices of the European Commission - EC). 

Kummer et al. 8) have reported that at pressures of about 0.5 torr, the relative emission intensities of the higher olefins and of the organic sulfides were substantially greater than that of ethylene Table II summarizes the reported relative emission intensities. Since a recently developed commercial ozone monitor is based on the chemiluminescent reaction between ozone and ethylene, this suggests the possibility of using the sulfide-ozone chemiluminescent reaction to monitor the low concentration of sulfur compounds in ambient air. This possibility is being further investigated now. 

Ambient air quality in the United States has improved dramatically since the Clean Air Act was enacted in 1970. The Environmental Protection Agency (EPA) monitors air quality and compares the data with the National Ambient Air Quality Standards (NAAQS), which have been established for ozone (O3), carbon monoxide (CO), nitrogen dioxide (NO2), sulfur dioxide (SO2), lead (Pb), and particulate matter (PM, airborne particles of any composition). Improvements in air quality help to mitigate atmospheric corrosion, as will be discussed in this chapter. 

Ozone in ambient air is presently measured at many sites over the world. In North America approximately 4300 air monitoring stations are currently in operation, which typically measure ozone and some primary air pollutants such as nitrogen oxides (NOx), sulfur dioxide (SO2), and carbon monoxide (CO). They are mainly in and near... 

Another negative effect of VOCs is their contribution to photochemical ozone creation. In the presence of sunlight, VOCs in ambient air undergo photochemical reactions leading to formation of secondary pollutants of which the most prominent is tropospheric ozone [3]. This ozone is currently monitored by several agencies and many photochemical models are instrumented with efficient and accurate sensitivity algorithms [4]. 

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