Aluminum characterization

Puhakainen K et al (2010) A new phase in the system lithium-aluminum characterization of orthorhombic Li2Al. J Solid State Chem 183 2528-2533... 

Inorganic flocculants are analyzed by the usual methods for compounds of this type. Residual metal ions in the effluent are measured by spectroscopic techniques such as atomic absorption. Polymeric aluminum species formed in solution have been characterized by Al-nmr (64). 

Soft magnetic materials are characterized by high permeabiUty and low coercivity. There are sis principal groups of commercially important soft magnetic materials iron and low carbon steels, iron—siUcon alloys, iron—aluminum and iron—aluminum—silicon alloys, nickel—iron alloys, iron-cobalt alloys, and ferrites. In addition, iron-boron-based amorphous soft magnetic alloys are commercially available. Some have properties similar to the best grades of the permalloys whereas others exhibit core losses substantially below those of the oriented siUcon steels. Table 1 summarizes the properties of some of these materials. 

The clad plate is x-rayed perpendicular from the steel side and the film contacts the aluminum. Radiography reveals the wavy interface of explosion-welded, aluminum-clad steel as uniformly spaced, light and dark lines with a frequency of one to three lines per centimeter. The waves characterize a strong and ductile transition joint and represent the acceptable condition. The clad is interpreted to be nonbonded when the x-ray shows complete loss of the wavy interface (see X-ray technology). 

Nickel—Copper. In the soHd state, nickel and copper form a continuous soHd solution. The nickel-rich, nickel—copper alloys are characterized by a good compromise of strength and ductihty and are resistant to corrosion and stress corrosion ia many environments, ia particular water and seawater, nonoxidizing acids, neutral and alkaline salts, and alkaUes. These alloys are weldable and are characterized by elevated and high temperature mechanical properties for certain appHcations. The copper content ia these alloys also easure improved thermal coaductivity for heat exchange. MONEL alloy 400 is a typical nickel-rich, nickel—copper alloy ia which the nickel content is ca 66 wt %. MONEL alloy K-500 is essentially alloy 400 with small additions of aluminum and titanium. Aging of alloy K-500 results in very fine y -precipitates and increased strength (see also Copper alloys). 

The earliest reported reference describing the synthesis of phenylene sulfide stmctures is that of Friedel and Crafts in 1888 (6). The electrophilic reactions studied were based on reactions of benzene and various sulfur sources. These electrophilic substitution reactions were characterized by low yields (50—80%) of rather poorly characterized products by the standards of 1990s. Products contained many by-products, such as thianthrene. Results of self-condensation of thiophenol, catalyzed by aluminum chloride and sulfuric acid (7), were analogous to those of Friedel and Crafts. 

The predorninant method for the analysis of alurninum-base alloys is spark source emission spectroscopy. SoHd metal samples are sparked direcdy, simultaneously eroding the metal surface, vaporizing the metal, and exciting the atomic vapor to emit light ia proportion to the amount of material present. Standard spark emission analytical techniques are described in ASTM ElOl, E607, E1251 and E716 (36). A wide variety of weU-characterized soHd reference materials are available from major aluminum producers for instmment caUbration. 

This group of aluminum carboxylates is characterized mainly by its abiUty to gel vegetable oils and hydrocarbons. Again, monocarboxylate, dicarboxylate, and tricarboxylate salts are important. The chemical, physical, and biological properties of the various types of aluminum stearates have been reviewed (29). Other products include aluminum palmitate and aluminum 2-ethylhexanoate (30). 

Several nonequilihrium forms of aluminum oxides have been observed (11,12) in hydrothermal experiments at low water vapor pressures in the temperature region of 300—500°C. The KI—AI2O2 form, also known as tondite [12043-15-1] AI2O2 I/5H2O, is characterized by a distinct x-ray diffraction pattern. 

Over 50 acidic, basic, and neutral aluminum sulfate hydrates have been reported. Only a few of these are well characterized because the exact compositions depend on conditions of precipitation from solution. Variables such as supersaturation, nucleation and crystal growth rates, occlusion, nonequilihrium conditions, and hydrolysis can each play a role ia the final composition. Commercial dry alum is likely not a single crystalline hydrate, but rather it contains significant amounts of amorphous material. 

W.R. Blumenthal and G.T. Gray III, Structure-Property Characterization of a Shock-Loaded Boron Carbide Aluminum Cermet, in 4th Oxford Conf. on Mech. Prop, of Mat. at High Rates of Strain, Int. Phys. Conf. Ser. 102, Oxford, 1989, 363 pp. 

Quantifying the effect of surface roughness or morphology is difficult, however. Surface preparations that provide different degrees of surface roughness also usually produce surfaces that have different oxide thicknesses and mechanical properties, different compositions, or different contaminant levels. The problem of separation of these variables was circumvented in a recent study [52] by using a modified microtome as a micro milling machine to produce repeatable, well-characterized micron-sized patterns on clad 2024-T3 aluminum adherends. Fig. 2 shows the sawtooth profile created by this process. 

Physical properties of aluminum are characterized by the following data ... 

Fig. 3.3. Stress-particle velocity characterizations of many materials have been documented. The explosive cross curves superposed on the materials responses provide approximate loading stress levels to be determined from the intersection of the explosive and material curves. For example, the detonation of TNT produces a pressure of 25 GPa in 2024 aluminum alloy.

Carr and his co-workers [86C01, 87C01] have shown that transmission electron microscopy is a powerful tool in characterizing linear and higher-order defect configurations and their densities on shock-modified rutile, alumina, aluminum nitride, and zirconia [84H02]. The principal impediment to detailed characterization of shock-formed defects is their very high concentrations, which prevent identification of specific deformation features except in... 

The elementary building block of the zeolite crystal is a unit cell. The unit cell size (UCS) is the distance between the repeating cells in the zeolite structure. One unit cell in a typical fresh Y-zeolite lathee contains 192 framework atomic positions 55 atoms of aluminum and 1atoms of silicon. This corresponds to a silica (SiOj) to alumina (AI.O,) molal ratio (SAR) of 5. The UCS is an important parameter in characterizing the zeolite structure. 

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