Alpha-aluminum

The adsorption of binary mixtures of anionic surfactants of a homologous series (sodium octyl sulfate and sodium dodecyl sulfate) on alpha aluminum oxide was measured. A thermodynamic model was developed to describe ideal mixed admicelle (adsorbed surfactant bilayer) formation, for concentrations between the critical admicelle concentration and the critical micelle concentration. Specific... 

The alpha aluminum oxide was purchased from Alpha Products, Thiokol/Ventron Division. The aluminum oxide h d a particle size of 40 microns, a surface area of 160 m /g, and consisted of 90% AI2O2 and 9% H2O, according to the manufacturer. The aluminum oxide was dried in 50 g batches under a vacuum for two days before use. 

C12SO.) are shown in Figure 2. All of the " adsorption isotherms were continuous in Regions II and III, which suggests that the distribution of energy level patches on o the surface of the alpha aluminum oxide was nearly... 

Figure 2. Adsorption Isotherms of CgSO, C10SO4, C12SO4 on Alpha Aluminum Oxide.

The adsorption isotherms of CgSO. and mixtures thereof, on alpha aluminum oxiae are illustrated in Figure 4. Also shown in Figure 4 is the extrapolation of the C SO. pure component adsorption isotherm down to its CAC and the ideal solution theory predictions. 

Activated alumina activated aluminum oxide alpha aluminum oxide alumina alumina, activated alumina, calcined alumina, tabular aluminum oxide alumite aluminum trioxide. 

Chart for determining she) thickne cyiindfico -jnd sjjhsricoi vewsis under axt mal pressure when constructed of alpha-aluminum bronze. (Froni... 

High-Temperature Synthesis of Materials Glycothermal Synthesis of Alpha Aluminum Oxide... 

There are two important side reactions, particularly above 120°C (/) aluminum alkyls decompose to form diaLkylalurninum hydrides and alpha olefins (the diaLkylalurninum hydrides rapidly react with ethylene to regenerate a trialkylalurninum) ... 

A.luminum Jilkyl Chain Growth. Ethyl, Chevron, and Mitsubishi Chemical manufacture higher, linear alpha olefins from ethylene via chain growth on triethyl aluminum (15). The linear products are then used as oxo feedstock for both plasticizer and detergent range alcohols and because the feedstocks are linear, the linearity of the alcohol product, which has an entirely odd number of carbons, is a function of the oxo process employed. Alcohols are manufactured from this type of olefin by Sterling, Exxon, ICI, BASE, Oxochemie, and Mitsubishi Chemical. 

Uses. Magnesium alkyls are used as polymerization catalysts for alpha-alkenes and dienes, such as the polymerization of ethylene (qv), and in combination with aluminum alkyls and the transition-metal haUdes (16—18). Magnesium alkyls have been used in conjunction with other compounds in the polymerization of alkene oxides, alkene sulfides, acrylonitrile (qv), and polar vinyl monomers (19—22). Magnesium alkyls can be used as a Hquid detergents (23). Also, magnesium alkyls have been used as fuel additives and for the suppression of soot in combustion of residual furnace oil (24). 

The Zn—A1 system permits manipulation of the mechanical properties by suitable heat treatment. The aluminum-rich alpha phase is especially suitable for solution hardening since it can be supersaturated by as much as 30 wt % zinc. Furthermore, both alpha and beta phases can be strengthened by precipitation because of decreasing solute solubiUty with decreasing temperature. 

Alpha—beta aluminum alloys respond to heat treatment with a general improvement of mechanical properties. Heat treatment is accompHshed by heating to 815—870°C, quenching in water, and reannealing at 370—535°C, depending on the size and section of the casting. Different combinations of strength, hardness, and ductility can be obtained. Some nickel in aluminum bronze is in soHd solution with the matrix and helps refine the precipitate, and a smaller amount is in the K-intermetaUic compound. 

The measures of solid state reactivity to be described include experiments on solid-gas, solid-liquid, and solid-solid chemical reaction, solid-solid structural transitions, and hot pressing-sintering in the solid state. These conditions are achieved in catalytic activity measurements of rutile and zinc oxide, in studies of the dissolution of silicon nitride and rutile, the reaction of lead oxide and zirconia to form lead zirconate, the monoclinic to tetragonal transformation in zirconia, the theta-to-alpha transformation in alumina, and the hot pressing of aluminum nitride and aluminum oxide. 

Linear alcohols (C12-C26) are important chemicals for producing various compounds such as plasticizers, detergents, and solvents. The production of linear alcohols by the hydroformylation (Oxo reaction) of alpha olefins followed by hydrogenation is discussed in Chapter 5. They are also produced by the oligomerization of ethylene using aluminum alkyls (Ziegler catalysts). 

Alpha carbon atoms, 348 Alpha decay, 417, 443 Alpha particle, 417 scattering, 245 Aluminum boiling point, 365 compounds, 102 heat of vaporization, 365 hydration energy, 368 hydroxide, 371 ionization energies, 269, 374 metallic solid, 365 occurrence, 373 properties, 101 preparation, 238. 373 reducing agent, 367 Alums, 403 Americium... 

Alpha-quartz has many useful properties which lead to its wide use in industry as a glass, ceramic and molecular sieve. However, undoubtedly its most technically important use occurs by virtue of its piezo-electric properties, which allow it to be used as a frequency regulating device in satellites, computers, and the ubiquitous quartz-watch . Unfortunately, it has been found that quartz crystals are susceptible to damage by radiation, and that this is associated with the presence of defects in the crystal lattice. These defects, particularly aluminum and hydrogen, are grown into the crystal and so far have proved impossible to remove. This problem has been the cause of intensive research, which has led to some information on the possible types of defects involved, but has failed to produce details of their geometries, and the way in which they interact. 

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