Allylglycidyl ether

Epichlorohydrin, propylglycidyl ether, allylglycidyl ether, phe-noxy-2-propanone, and phenylglycidyl ether... 

This is broadly in agreement with the findings from copolymerization (Table 22 and Section VI-B). The introduction of comonomer units into PTHF reduces its crystallinity and rubbery materials generally result. In one case allylglycidyl ether was copolymerized so that the pendant olefinic side chains would allow sulfur vulcanization (7). 

In this case, PGE, allylglycidyl ether (AGE), and glycidyl methacrylate (GMA) were used as the epoxide. 

Halogeno silanes can be reacted readily with hydrides, e.g. magnesium hydride, in the presence of an ethereal solvent to give the appropriate hydrogen silane [4]. Applying this method e.g. trimethylsilane was obtained in excellent yields. Trimethylsilane was reacted with a-alkenols, allylglycidyl ether, and various alkenyl polyethers whereby the latter directly leads to a nonionic silane surfactant. The easy availability of trimethyl silane and its derivatives opens up a very interesting route to new Si-surfactants from the view of economy, too. 

The Pt-catalyzed hydrosilylation of trimethyl silane and alkenols or alkenyl-polyethers lead to nonionic silane surfactants, whereas the addition of allylglycidyl ether to trimethylsilane results in a precursor for ionic derivatives. The epoxy group is highly reactive towards nucleophilic agents and can be easily transformed into quaternary ammonium, betaine, or sulfonate complexes. Additionally, cation-anion complexes can be formed by the transformation of two equivalents of epoxy silane with one equivalent of trialkyl ammonium hydrogen sulfite. The reaction of hydroxyalkyltrimethylsilane... 

The extension of fhis novel chain transfer event to higher molecular weight a-olefins has enabled us, and ofhers, to make unique poly(norbornene) block copolymers [44]. Examples of fhe diversity of this chain transfer chemistry are given in Fig. 4.15 where chain transfer to efhylene, allylglycidyl ether, isobutylene, cyclo-... 

Chem. Descrip. Allylglycidyl ether alcohol resin CAS 41630-20-0... 

Another example is a copolymer of allylglycidyl ether with tetrahydrofuran formed with antimony pentachloride catalyst. ... 

Ethanediol, polymer with [(2-propenyloxy) methyl] oxirane. See Allylglycidyl ether alcohol resin... 

Santolink X1100. See Allylglycidyl ether alcohol resin... 

Chromium sulfate (ic) crosslinking agent Acrylic acid/acrylamide copolymer Allylglycidyl ether alcohol resin Allyl isocyanate Aluminum acetylacetonate N-2-Aminoethyl-3-aminopropyl trimethoxysilane Ammonium persulfate t-Amyl peroxyacetate Bis (triethoxysilyl) ethane Chromic acetylacetonate Cobalt acetate (ous). 

Allylglycidyl ether alcohol resin t-Amyl peroxyacetate Di-t-butyl diperoxyazelate Din-butyl peroxydicarbonate initiator, acrylate polymerization t-Amyl peroxybenzoate Di-(4-t-butylcyclohexyl) peroxydicarbonate 2,5-Dimethyl-2,5-di (2-ethylhexanoyl peroxy) hexane... 

Polyethylmethacrylate (C6H10O2 C2H602)x Allylglycidyl ether alcohol resin C6H10O2 Na... 

Examples of reactive diluents for epoxy resins include phenyl glycidyl ether, butylglycidyl ether, allylglycidyl ether, and glycerol-based epoxy resins. Diluents should be used sparingly in amounts of 5-15 phr, enough to reduce the viscosity of the adhesive, yet not degrade the properties of the cured material. 

Silicones modified with polyethers and carbohydrates can be obtained in a very similar way (Scheme 2). Analogously, the synthesis starts with a comb-like SiH silicone which reacts easily in a co-hydrosilylation with an allyl-terminated polyether and allylglycidyl ether. Again, the epoxide rings of the resulting silicone are opened with N-methylglucamine. 

C5 ras VP, Manfredi LB, Ton-That M-T, Vazquez A (2008) Physical and mechanical properties of thermoplastic starch/montmorillonite nanocomposite films. Carbohydr Polym 73 55-63 de Morals Teixeira E, Correa A, Manzoli A, de Lima Leite F, de Oliveira C, Mattoso L (2010) Cellulose nanofibers from white and naturally colored cotton fibers. Cellulose 17 595-606 de Moura MR, Aouada FA, Avena-Bustillos RJ, McHugh TH, Krochta JM, Mattoso LHC (2009) Improved barrier and mechanical properties of novel hydrox5q)ropyl methylcellulose edible films with chitosan/tripolyphosphate nanoparticles. J Food Eng 92 448—453 Dean K, Yu L, Wu DY (2007) Preparation and characterization of melt-extruded thermoplastic starch/clay nanocomposites. Compos Sci Technol 67 413 21 Duanmu J, Gamstedt EK, Rosling A (2007) Hygromechanical properties of composites of crosslinked allylglycidyl-ether modified starch reinforced by wood fibres. Compos Sci Technol 67 3090-3097... 

Other examples of recently developed block copolymers based on PEO are those having poly(styrene oxide) [293], poly(allylglycidyl ether) as a cross-linkable block [294] or poly (methyhdene malonates) [171,295] as hydrophobic micellar core-forming blocks. 

ALLYLGLYCIDYL ETHER C.H 0. AGE 1-Allyloxy-2 5-cpoxy-propaiw Strong oxidizers 13S > J... 

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