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Alkene hydrogenation catalysis

In addition, hydrotrope solutions have been involved in reactions concerning solid particles. As examples may be mentioned the template-free synthesis of microtubules [34], important materials in nano-technology, and the more sophisticated role of hydrotropes to concurrently optimize the interfacial tension and the colloidal stabilization of rhodium particles in biphasic liquid-liquid alkene hydrogenation catalysis [35], Finally reaction kinetics has been used as a means to follow the association of hydrotrope molecules in aqueous solutions [36],... [Pg.22]

A large number of (mostly zero-valent) nickel-alkene complexes has been reported. Although these complexes have not been recently reviewed, their general properties and structures were expertly described in 1982 [21]. A complete overview of the reported nickel-alkene and nickel-alkyl complexes is beyond the scope of this section, in which a selection of nickel-alkene and nickel-alkyl complexes is described, mostly related to possible intermediates in hydrogenation catalysis. [Pg.99]

The use of ionic liquids has been successfully studied in many transition metal-catalyzed hydrogenation reactions, ranging from simple alkene hydrogenation to asymmetric examples. To date, almost all applications have included procedures of multiphase catalysis with the transition-metal complex being immobilized in the ionic liquid by its ionic nature or by means of an ionic (or highly polar) ligand. [Pg.1416]

The old and lasting problem of heterogeneous catalysis, the mechanism of alkene hydrogenation, has also been approached from the viewpoint of structure effects on rate. In 1925, Lebedev and co-workers (80) had already noted that the velocity of the hydrogenation of the C=C bond decreases with the number of substituents on both carbon atoms. The same conclusion can be drawn from the narrower series of alkenes studied by Schuster (8J) (series 52 in Table IV). Recently authors have tried to analyze this influence of substituents in a more detailed way, in order to find out whether the change in rate is caused by polar or steric effects and whether the substituents affect mostly the adsorptivity of the unsaturated compounds or the reaetivity of the adsorbed species. Linear relationships have been used for quantitative treatment. [Pg.172]

Aqueous biphasic catalysis is also used in homogeneous hydrogenations.117-119 In new examples Ru clusters with the widely used TPPTN [tris(3-sulfonatophenyl) phosphine] ligand120 and Rh complexes with novel carboxylated phosphines121 were applied in alkene hydrogenation, whereas Ru catalysts were used in the hydro-genation of aromatics. Aerobic oxidation of terminal alkenes to methyl ketones was carried out in a biphasic liquid-liquid system by stable, recyclable, water-soluble Pd(II) complexes with sulfonated bidentate diamine ligands.124... [Pg.812]

Applications of HT-type catalysts, prepared by the above methods, have been reported in recent years for basic catalysis (polymerization of alkene oxides, aldol condensation), steam reforming of methane or naphtha, CO hydrogenation as in methanol and higher-alcohol synthesis, conversion of syngas to alkanes and alkenes, hydrogenation of nitrobenzene, oxidation reactions, and as a support for Ziegler-Natta catalysts (Table 2). [Pg.79]

Methyltrioxorhenium(VII) (MTO) absorbance spectroscopy, 130, 132 alkene epoxidation, catalysis with hydrogen peroxide... [Pg.319]

Ammonia N-donor Ligands Asymmetric Synthesis by Homogeneous Catalysis Decarbonylation Catalysis Hydride Complexes of the Transition Metals Hydroboration Catalysis Hydrogenation Isomerization of Alkenes Hydrosilation Catalysis P-donor Ligands Rhodium Organometallic Chemistry. [Pg.4081]


See other pages where Alkene hydrogenation catalysis is mentioned: [Pg.87]    [Pg.110]    [Pg.226]    [Pg.441]    [Pg.238]    [Pg.98]    [Pg.25]    [Pg.97]    [Pg.4]    [Pg.89]    [Pg.668]    [Pg.673]    [Pg.371]    [Pg.479]    [Pg.112]    [Pg.118]    [Pg.406]    [Pg.707]    [Pg.1158]    [Pg.154]    [Pg.147]    [Pg.283]    [Pg.660]    [Pg.688]    [Pg.1531]    [Pg.1615]    [Pg.1867]    [Pg.4103]   
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