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Aldehydes carbon disulfide

Reactions were carried out by condensing a-aminonitriles [NCCHiRiiNHJ with carbon disulfide in the presence of aldehydes (R CHO) or ketones [Pg.287]

Synthesis from Thiohydantoins. A modification (71) of the Bucherer-Bergs reaction consisting of treatment of an aldehyde or ketone with carbon disulfide, ammonium chloride, and sodium cyanide affords 2,4-dithiohydantoias (19). 4-Thiohydantoias (20) are available from reaction of amino nitriles with carbon disulfide (72). Compounds (19) and (20) can be transformed iato hydantoias. [Pg.254]

Both antimony tribromide and antimony ttiiodide are prepared by reaction of the elements. Their chemistry is similar to that of SbCl in that they readily hydroly2e, form complex haUde ions, and form a wide variety of adducts with ethers, aldehydes, mercaptans, etc. They are soluble in carbon disulfide, acetone, and chloroform. There has been considerable interest in the compounds antimony bromide sulfide [14794-85-5] antimony iodide sulfide [13868-38-1] ISSb, and antimony iodide selenide [15513-79-8] with respect to their soHd-state properties, ferroelectricity, pyroelectricity, photoconduction, and dielectric polarization. [Pg.204]

A by-product of the reaction between an enamine, elemental sulfur, and carbon disulfide is an a-dithiopyrone. This by-product is the result of the condensation of two enamine molecules with one carbon disulfide molecule. In the case of aldehydic enamines, the reaction probably proceeds through... [Pg.237]

Acetylene works Acrylates works Aldehyde works Aluminum works Amines works Ammonia works Anhydride works Arsenic works Asbestos works Benzene works Beryllium works Bisulfate works Bromine works Cadmium works Carbon disulfide works Carbonyl works Caustic soda works Cement works Ceramic works Chemical fertilizer works Chlorine works Chromium works Copper works Di-isocyanate works Electricity works Fiber works Fluorine works Gas liquor works Gas and coke works Hydrochloric acid works Hydrofluoric acid works Hydrogen cyanide works Incineration works Iron works and steel works... [Pg.755]

Chloroacetic acid, reaction with salicyl-aldehyde, 46, 28 Chloroacetone, 46, 3 Chloroacetyl fluoride, 45, 6 o-Chloroacetyl isocyanate, 46,16 -Chloroaniline, reaction with carbon disulfide and aqueous ammonia,... [Pg.123]

The complex also undergoes a variety of addition reactions with reagents such as methyl iodide, hydrochloric acid, benzoyl chloride, and allyl chloride.8 In a reaction similar to that of the decarboxylation of aldehydes, the complex will abstract CS from carbon disulfide to give the irans-thiocarbonyl complex rans-RhClCS[P(C8H6)5]2.9... [Pg.71]

Most of the cyclizations of the five-membered ring relating this type of fused [l,2,4]triazines concern the synthesis of [l,3,4]thiadiazolo[2,3-c][l,2,4]triazines. These synthetic approaches are similar in respect to the starting compound, which is a substituted 4-amino-3-mercapto[l,2,4]triazine-5(477)one 218 in each case. The ring-closure reactions can be classified into four related categories according to the reagent used aldehyde, isothiocyanate, carbon disulfide, or an acid. [Pg.878]

Isonitrile complexes, having a similar electronic structure to carbonyl complexes, can also react with nucleophiles. Amino-substituted carbene complexes can be prepared in this way (Figure 2.6) [109-112]. Complexes of acceptor-substituted isonitriles can undergo 1,3-dipolar cycloaddition reactions with aldehydes, electron-poor olefins [113], isocyanates [114,115], carbon disulfide [115], etc., to yield heterocycloalkylidene complexes (Figure 2.6). [Pg.21]

Water freezes to ice at 0°C expands by about 10% on freezing boils at 100°C vapor pressure at 0°, 20°, 50°, and 100°C are 4.6, 17.5, 92.5, and 760 torr, respectively dielectric constant 80.2 at 20°C and 76.6 at 30°C dipole moment in benzene at 25°C 1.76 critical temperature 373.99°C critical pressure 217.8 atm critical density 0.322 g/cm viscosity 0.01002 poise at 20°C surface tension 73 dynes/cm at 20°C dissolves ionic substances miscible with mineral acids, alkalies low molecular weight alcohols, aldehydes and ketones forms an azeotrope with several solvents immiscible with nonpolar solvents such as carbon tetrachloride, hexane, chloroform, benzene, toluene, and carbon disulfide. [Pg.968]

The meso-ionic 1,3-oxazol-S-ones show an incredible array of cycloaddition reactions. Reference has already been made to the cycloaddition reactions of the derivative 50, which are interpreted as involving cycloaddition to the valence tautomer 51. In addition, an extremely comprehensive study of the 1,3-dipolar cycloaddition reactions of meso-ionic l,3-oxazol-5-ones (66) has been undertaken by Huisgen and his co-workers. The 1,3-dipolarophiles that have been examined include alkenes, alkynes, aldehydes, a-keto esters, a-diketones, thiobenzophenone, thiono esters, carbon oxysulfide, carbon disulfide, nitriles, nitro-, nitroso-, and azo-compounds, and cyclopropane and cyclobutene derivatives. In these reactions the l,3-oxazol-5-ones (66)... [Pg.18]

In the course of studying the reactions of carbon dioxide, carbon disulfide, and other small molecules with peroxobis(triphenylphos-phine)platinum(II) (197), the reactions of Ir(C0)Cl(PPh3)2(02) and RhCl (PPh3)3(02) with C02, CS2, aldehydes, and ketones were also attempted. In every case the metal-containing reactant was recovered unchanged. Somewhat later (198), it was demonstrated that Ir(C0)X(PPh3)2(02),... [Pg.316]

Bond length/bond enthalpy. Note that 1 A equals 0.1 nm. 6 Bond lengths are given for bonds in which none of the partner atoms is involved in a double or triple bond. In such cases bond lengths are somewhat shorter.c In carbon disulfide.d In aldehydes. e In ketones, f In carbon dioxide. [Pg.20]

Condensation of 2-hydrazinopyrimidine (384) with an aromatic aldehyde formed the Schiff bases (386), which then cyclized with bromine to 6-bromo-l,2,4-triazolo[4,3-a]pyrimidine (383) and with carbon disulfide to 387 (92PS145). A similar cyclization was effected also on 384 to give 388 (68T2839 85FRP2549834), but the cyclization of 384 or 385 with carbon disulfide afforded 3-thiolo-l,2,4-triazolo[4,3-a]pyrimidin-7-ones 389 and 390, respectively. A small amount of the isomeric 3-thiolo-l, 2,4-triazolo[4,3-a]pyrimidin-5-one was isolated in the former case (68T2839). Reaction of 385 with benzaldehyde [67JCS(C)498] or p-chlorobenzaldehyde (90MI3) followed by oxidation with LTA in benzene afforded 391 (Scheme 73). [Pg.177]

Amino groups react very easily with aldehydes or ketones, and with aldehydes in the presence of amines, they can be acylated by the usual acylating agents, and they react with amidacetals, Vilsmeier reagents and nitroso compounds (Scheme 12). As mentioned earlier, alkylation leads mainly to AT(2)-alkylated products. The hydrazino group reacts in the same way as the amino group with aldehydes or ketones, with acyl chlorides or carboxylic anhydrides, with sulfonyl chlorides, ortho esters, carbon disulfide and with nitrous acid. The last three reactions have mainly been used for the synthesis of condensed 1,2,4-triazines. [Pg.418]

Aminohydrazines (640) are useful intermediates for the synthesis of reduced 1,2,4-triazines. With nitriles, carboxylic acids, imidates, thioimidates or orthocarboxylates, they form l,4,5,6-tetrahydro-l,2,4-triazines (641) (78HC(33)189, p. 629), with carbon disulfide they give the 3-thiones (642) <78HC(33)189, p.648), and with aldehydes or ketones hexahydro-1,2,4-triazines (643) are formed <78HC(33)189, p. 657). [Pg.443]

Carbon monoxide. cFor carbon disulfide. Tor carbon dioxide. Tor formaldehyde. Other aldehydes... 9Ketones. [Pg.77]


See other pages where Aldehydes carbon disulfide is mentioned: [Pg.505]    [Pg.505]    [Pg.505]    [Pg.505]    [Pg.360]    [Pg.132]    [Pg.777]    [Pg.422]    [Pg.446]    [Pg.139]    [Pg.272]    [Pg.72]    [Pg.276]    [Pg.403]    [Pg.519]    [Pg.53]    [Pg.339]    [Pg.1067]    [Pg.155]    [Pg.207]    [Pg.31]    [Pg.91]    [Pg.467]    [Pg.88]    [Pg.299]    [Pg.171]    [Pg.444]    [Pg.383]    [Pg.53]    [Pg.339]   
See also in sourсe #XX -- [ Pg.126 ]




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Carbon aldehyde

Carbon disulfid

Carbon disulfide

Carbon disulfides

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