Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Aldehydes and anhydrids

In treating of the monoatomic compounds, it was stated that substances existed corresponding to the fatty acids, known as aldehydes and anhydrids, the former differing from the acids in that they contained the group COH instead of COOH the latter being the oxids of the acid radicals. Similar compounds exist corresponding to the acids of these two series. [Pg.332]

Glycolic acid. Glycolic aldehyde. Osalic acid. Glyoxalic acid. GlyoxoL [Pg.332]

While the anhydrids of the fatty series may be considered as derived from the acids by the subtraction of HaO from two molecules of the acid those of both the series of acids under consideration are derived from a single molecule of the acid by the subtraction of HaO  [Pg.332]

The diamins are derived from a double molecule of NHs, or of ammonium hydroxid, by the substitution of the diatomic radicals of the glycols (hydrocarbons of the series C Han) for an equivalent uumber of H atoms. [Pg.332]

When it is considered that in the formation of these substances any number of groups CnHan of different constitution may be introduced between two NHa groups, thus  [Pg.332]


Perkin reaction A condensation between aromatic aldehydes and the sodium salts of fatty acids or their aromatic derivatives. The reaction between benzaldehyde and sodium ethanoate in the presence of ethanoic anhydride leads to sodium cinnamate... [Pg.300]

When cinnamaldehyde, succinic acid and acetic anhydride are heated in the presence of litharge (PbO), the aldehyde and the succinic acid condense to give the dicarboxylic acid (I), which undergoes decarboxylation to give the pale yellow crystalline 1,8-diphenyloctatetrene (II), Kuhn has shown that as the... [Pg.238]

The mechanism of the reaction, which is of the aldol type, involves the car-bonyl group of tlie aldehyde and an active methylene group of the anhydride the function of the basic catalyst B (acetate ion 0H3000 or triethylamine N(0,Hb)j) is to form the anion of the active hydrogen component, i.e., by the extraction of a proton from the anhydride ... [Pg.707]

The lower members of other homologous series of oxygen compounds— the acids, aldehydes, ketones, anhydrides, ethers and esters—have approximately the same limits of solubility as the alcohols and substitution and branching of the carbon chain has a similar influence. For the amines (primary, secondary and tertiary), the limit of solubility is about C whilst for the amides and nitriles it is about C4. [Pg.1046]

It is convenient to consider the indiflferent or neutral oxygen derivatives of the hydrocarbons—(a) aldehydes and kelones, (b) esters and anhydrides, (c) alcohols and ethers—together. All of these, with the exception of the water-soluble members of low molecular weight, are soluble only in concentrated sulphuric acid, i.e., fall into Solubility Group V. The above classes of compounds must be tested for in the order in which they are listed, otherwise erroneous conclusions may be drawn from the reactions for functional groups about to be described. [Pg.1060]

When the compound for identification fails to respond to test 4 (aldehyde or ketone), the next class reactions to apply are the hydroxatnic acid teat and saponification, i.e., hydrolysis in alkaline solution. These are the class reactions for esters and anhydrides the rarely-encountered lactones react similarly. [Pg.1062]

The production of both an alcohol and the sodium salt of an acid might easily be confused with the hydrolysis products of an ester (in the above instance benzyl benzoate). Such an error would soon be discovered (e.g., by reference to the b.p. and other physical properties), but it would lead to an unnecessary expenditure of time and energy. The above example, however, emphasises the importance of conducting the class reactions of neutral oxygen-containing compounds in the proper order, viz., (1) aldehydes and ketones, (2) esters and anhydrides, (3) alcohols, and (4) ethers. [Pg.1063]

If the unknown neutral, oxygen-containing compound does not give the class reactions for aldehydes, ketones, esters and anhydrides, it is probably... [Pg.1065]

The chemistry of the carbonyl group is probably the single most important aspect of organic chemical reactivity Classes of compounds that contain the carbonyl group include many derived from carboxylic acids (acyl chlorides acid anhydrides esters and amides) as well as the two related classes discussed m this chapter aldehydes and ketones... [Pg.741]

Just as most other aldehydes do, furfural condenses with compounds possessing active methylene groups such as aUphatic carboxyUc esters and anhydrides, ketones, aldehydes, nitriles, and nitroparaffins. [Pg.77]

Sulfur tetrafluoride [7783-60-0] SF, replaces halogen in haloalkanes, haloalkenes, and aryl chlorides, but is only effective (even at elevated temperatures) in the presence of a Lewis acid catalyst. The reagent is most often used in the replacement of carbonyl oxygen with fluorine (15,16). Aldehydes and ketones react readily, particularly if no alpha-hydrogen atoms are present (eg, benzal fluoride [455-31-2] from benzaldehyde), but acids, esters, acid chlorides, and anhydrides are very sluggish. However, these reactions can be catalyzed by Lewis acids (HP, BF, etc). [Pg.268]

Chemical Properties. A combination of excellent chemical and mechanical properties at elevated temperatures result in high performance service in the chemical processing industry. Teflon PEA resins have been exposed to a variety of organic and inorganic compounds commonly encountered in chemical service (26). They are not attacked by inorganic acids, bases, halogens, metal salt solutions, organic acids, and anhydrides. Aromatic and ahphatic hydrocarbons, alcohols, aldehydes, ketones, ethers, amines, esters, chlorinated compounds, and other polymer solvents have Httle effect. However, like other perfluorinated polymers,they react with alkah metals and elemental fluorine. [Pg.375]

Aldehyde Synthesis. Formylation would be expected to take place when formyl chloride or formic anhydride reacts with an aromatic compound ia the presence of aluminum chloride or other Friedel-Crafts catalysts. However, the acid chloride and anhydride of formic acid are both too unstable to be of preparative iaterest. [Pg.559]

Acids are usually the end products of ketone oxidations (41,42,44) but vicinal diketones and hydroperoxyketones are apparent intermediates (45). Acids are readily produced from vicinal diketones, perhaps through anhydrides (via, eg, a Bayer-ViUiger reaction) (46,47). The hydroperoxyketones reportedly decompose to diketones as well as to aldehydes and acids (45). Similar products are expected from radical— radical reactions of the corresponding peroxy radical precursors. [Pg.336]

Although the reaction is a general one for aldehydes and ketones, in certain instances, esters, anhydrides, and nitrites are attacked by these reagents (8,92). [Pg.381]

Condensation with Aldehydes and Ketones. Succinic anhydride and succinic esters in the presence of different catalysts react in the gas phase with formaldehyde to give citraconic acid or anhydride and itaconic acid (94—96). Dialkyl acyl succinates are obtained by reaction of dialkyl succinates with C 4 aldehydes over peroxide catalysts (97). [Pg.535]

PMVEMA, supphed as a white, fluffy powder, is soluble in ketones, esters, pyridine, lactams, and aldehydes, and insoluble in aUphatic, aromatic, or halogenated hydrocarbons, as well as in ethyl ether and nitroparaffins. When the copolymer dissolves in water or alcohols, the anhydride group is cleaved, forming the polymers in free acid form or the half-esters of the corresponding alcohol, respectively. Table 7 illustrates the commercially available alternating copolymers and derivatives. [Pg.518]

Acids and esters (see Esters, organic) are less easily brominated than aldehydes or ketones. Acid chlorides and anhydrides are more easily brominated (23). [Pg.282]

Hydrazinopyridazines are easily formylated with formic acid or ethyl formate and acety-lated with acetic anhydride. A-Pyridazinylthiosemicarbazides are obtained from thiocyanates or alkyl- and aryl-isothiocyanates. Hydrazinopyridazines condense with aliphatic and aromatic aldehydes and ketones to give hydrazones. [Pg.35]

Paint and varnish manufacturing Resin manufacturing closed reaction vessel Varnish cooldng-open or closed vessels Solvent thinning Acrolein, other aldehydes and fatty acids (odors), phthalic anhydride (sublimed) Ketones, fatty acids, formic acids, acetic acid, glycerine, acrolein, other aldehydes, phenols and terpenes from tall oils, hydrogen sulfide, alkyl sulfide, butyl mercaptan, and thiofen (odors) Olefins, branched-chain aromatics and ketones (odors), solvents Exhaust systems with scrubbers and fume burners Exhaust system with scrubbers and fume burners close-fitting hoods required for open kettles Exhaust system with fume burners... [Pg.2177]

Perkin condensation is the reaction between aromatic aldehydes and aliphatic acid anhydrides (in the presence of the sodium salt) to form p-arylacrylic acid... [Pg.256]

Under Barbier conditions, trifluoromethyl bromide reacts with electrophiles, such as aldehydes, Orkelo esters, activated esters, and anhydrides in the presence of pyridine to give trifluoromethylated compounds [35, 45 46] (equations 34 37)... [Pg.677]

In similar work, CF3CCI2CO2CH3 yields methyl a-trifluoromethyl-a,(i-un-saturated carboxylates when reacted with a zinc-copper couple, aldehydes, and acetic anhydride [67] (equation 55). This methodology gives (Z)-a-fluoro-a- -un-saturated carboxylates from the reaction of carbonyl compounds with CFCI2CO2CH3 and zinc and acetic anhydride [6 ]. [Pg.683]

AkoJwIs may be obtained from aldehydes, ketones, esters, acid chlorides, and anhydrides,... [Pg.307]

Several improved methods for the preparation of known unsaturated azlactones as well as some interesting new compounds of this type have been reported. Crawford and Little observed that the direct use of 2-phenyl-5-oxazolone (1) in the Erlenmeyer reaction gave much improved yields (35-74%) of unsaturated azlactones with aliphatic aldehydes and with ketones such as acetone and cyclohexanone [Eq, (1)], The usual procedure of mixing a carbonyl compound, hippuric acid, acetic anhydride, and sodium (or lead) acetate affords poor yields in the aliphatic series. [Pg.76]

Anhydrides are reduced with relative ease. McAlees and McCrindle 20) established the following increasing order of difficulty for various carbonyls acid chlorides > aldehydes, ketones > anhydrides > esters > carboxylic acids > amides. Reduction may proceed by 1,2-addilion of hydrogen or by cleavage of an oxygen-carbonyl bond. If 1,2-addition to the carbonyl occurs, as in the presence of strong protic acids over palladium, 1,1-diesters are formed by acylation 26). [Pg.79]


See other pages where Aldehydes and anhydrids is mentioned: [Pg.78]    [Pg.65]    [Pg.10]    [Pg.92]    [Pg.174]    [Pg.477]    [Pg.78]    [Pg.65]    [Pg.10]    [Pg.92]    [Pg.174]    [Pg.477]    [Pg.19]    [Pg.227]    [Pg.247]    [Pg.306]    [Pg.320]    [Pg.320]    [Pg.48]    [Pg.427]    [Pg.63]    [Pg.95]    [Pg.304]    [Pg.52]   


SEARCH



Aldehydes, ketones, esters, and anhydrides

Anhydrides aldehydes

© 2024 chempedia.info