Adsorption processes for gas

Esteves A., Mota J. P. B. 2011. Novel hybrid membrane/pres-sure swing adsorption processes for gas separation applications. In Drioli E. and Barbieri G. (eds.) Membrane Engineering for the Treatment of Gases, pp. 245-275. Cambridge, U.K. The Royal Society of Chemistry. ISBN 978-1-84973-239-0. 

Rota, R. and Wankat, P. C. (1991) Proc. Adsorption Processes for Gas Separation. 

The simulation reported here consists of the following sequential operating procedure applied to an initially evacuated adsorber (I) charge up to P = 10 bar, (II) constant-pressure feed, and (III) discharge down to F = 1.25 bar. This example encompasses the major steps of every cyclic batch adsorption process for gas separation, in which regeneration of the bed is accomplished by reducing the pressure at essentially constant temperature, as is the case in pressure swing adsorption. The input parameters and output variables for each phase are listed in Table 1. 

Table 1.2. Desorption enthalpies of cyclic industrial adsorption processes for gas/vapor...

Esteves lAAC, Mota JPB (2002) Simulation of a new hybrid membrane/pressure swing adsorption process for gas separation. Desalination 148 275-280... 

Sircar, S. (1991) Recent trends in pressure swing adsorption, in Adsorption Processes for Gas Separation, edited by F. Meunier and M. D. LeVan, Recents ftogres en Genie des Procedes, 5(17), Groupe Francais de Genie des Procedes, Nancy, pp. 9-14 Sircar, S. and Hanley, B. F. (1995) Adsorption, 1,313 Sowerby, B. and Crittenden, B. D. (1991) Trans. IChemE, 69A, 3-13 Thomas, H. C. (1944)/. Am. Chem. Soc.,66,1664-1666 Tien, C. (1994) Adsorption Calculations and Modelling, Butterworth-Heinemann, Boston... 

Novel Hybrid Membranej Pressure Swing Adsorption Processes for Gas Separation Applications... 

Kryosol An adsorptive process for purifying methane from landfill gas. Operated at high pressure. The overall methane recovery is 90 to 95 percent. 

MEDISORBON An adsorptive process for removing mercury and dioxins from flue-gas. The adsorbent is a dealuminated zeolite Y manufactured by Degussa. For mercury removal, the zeolite is impregnated with sulfur. Developed in 1994 by Lurgi Energie und Umwelt and piloted in Germany and The Netherlands. 

So far we have had an overview of the forces involved in the adsorption process for ions in solution. However, we have not yet said anything about how to determine these forces or how to describe the adsoibed state of the ion. Physical quantities such as pressure, volume, temperature, and amount of substance describe the conditions in which a particular material exists that is, they describe the state of a material. These quantities are interrelated and one cannot be changed without causing a change in one or more of the others. The mathematical relationship among these physical quantities is called the equation of state of the system. Well-known examples of equations of states for gases are the ideal gas (PV = nRT) and the virial [P = RT(n/V) + RTB2T n/vf +. ..] equations of state. 

On the other hand, for the mesoporous carbons, the gas adsorption process changes with increasing relative pressure as follows first monolayer-multilayer adsorption on the pore surfaces, then capillary condensation in the mesopoies, and finally multilayer adsorption on the outer surfaces in sequence (Types IV and V isotherms). Therefore, the adsorption process for the mesoporous carbons is initially similar to that for the macroporous carbons, but at higher relative pressures the amount adsorbed rises very steeply due to the capillary condensation in the mesopoies. 

The Monte-Carlo principle uses random numbers in the region 0 < random < 1. The main randomized values in the Monte-Carlo simulation, see Figure 1, of a gas-phase adsorption process for radioactive species are ... 

Gas chromatography may be divided into gas solid chromatography (mainly adsorptive processes) and gas-liquid chromatography (mainly partition) depending on whether the stationary phase is a solid or a liquid at its operating temperature. If the stationary phase is a hquid it must be coated on a support for packed coliunn chromatography. For capillary column chromatography, the stationary phase may be coated directly on to the walls of the coliunn, or on to a support which is bonded to the... 

Sano, Y., Choi, K.H., Korai, Y., and Mochida, I. Effects of nitrogen and refractory sulfur species removal on the deep HDS of gas oil. Applied Catalysis. B, Environmental, 2004, 53, 169 Sano, Y., Sugahara, K., Choi, K.H., Korai, Y., and Mochida, I. Two-step adsorption process for deep desulfurization of diesel oil. Fuel, 2005, 84, 903. 

Fuderer, A. Selective adsorption process for production of ammonia synthesis gas mixtures. U.S. Patent 4,375,363, 1983. 

Filippov, L.K., Theoretical basis of adsorption processes for separation of multicomponent mixtures. Gas Sep. Purif,2(3), 138-143 (1988),... 

In engineering gas adsorption processes, for example in air separation processes [4.14], it may happen that a sorbent first is exposed to pure component 1 of a sorptive gas and after equilibration component 2 is added thus starting a coadsorption process approaching a certain equilibrium state Z... 

Xiang Z, Cao D, Lan J, Wang W, Broom DP Multiscale simulation and modelhng of adsorptive processes for energy gas storage and carbon dioxide capture in porous coordination frameworks. Energy Environ Sd 3(10) 1469—1487, 2010. 

Multilayer gas adsorption As mentioned elsewhere, the fracking process for gas recovery from shale deposits is a process where adsorbed gas is released by the process. In some systems, adsorption of gas molecules proceeds to higher levels where multilayers are observed. From data analyses, one finds that multilayer adsorption takes place. Figure 1.46. 

The randomized values in the Monte-Carlo simulation of a gas-phase adsorption process for radioactive species are ... 

Ammonia synthesis process two pressure swing adsorption stages for gas separation. J. B. Johnson and A. Pinto (Imperial Chemical Industries Ltd). US 4772420 (1988). 

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