Acrylic acid nitric oxide

The chief methods for the preparation of /3-bromopropionic acid are the action of hydrobromic acid on acrylic acid,1 on hydracrylic acid,2 and on ethylene cyanohydrin 3 the oxidation of /3-bromopropionaldehyde 4 and of trimethylene bromohydrin 5 with nitric acid. [Pg.26]

Hydrogen hexafluorophophosphate, Borosilicate glass, 4354 Hydrogen peroxide, Diethyl ether, 4471 Imidazoline-2,4-dithione, 1138 Lithium nitride, Silicon tetrafluoride, 4681 Magnesium, Metal oxides, 4685 Manganese trifluoride, 4329 f Methyl acrylate, 1526 Nitric acid, Glassware, 4430 Oxalic acid, Urea, 0721... [Pg.2360]

Essentially, all primary skin irritants include acids, alkalis, metals, salts, and solvents. Among organic acids one may include acetic acid, acrylic acid, carbolic acid, chloroacetic acid, formic acid, lactic acid, oxalic acid, and salicylic acid. Among inorganic acids one may list arsenious acid, chromic acid, hydrochloric acid, hydrofluoric acid, nitric acid, phosphoric acid, and sulfuric acid. Alkalis include butylamines, ethylamines, ethanolamines, methylamines, propylamines, and triethanolamine. One also may include ammonium carbonate, ammonium hydroxide, calcium carbonate, calcium cyanamide, calcium hydroxide, calcium oxide, potassium carbonate, potassium hydroxide, sodium carbonate (soda ash), sodium hydroxide (caustic soda), and sodium silicate. [Pg.387]

Among the reactions of acrolein which are important in determining its structural formula are those in which it is reduced to allyl alcohol and to propionaldehyde or oxidised to acrylic acid. Reduction is most conveniently carried out by means of aluminium amalgam, while atmospheric oxygen is sufficient to oxidise it. More powerful oxidants cause profound breakdown of the molecule thus nitric acid forms oxalic and glycollic acids and chromic acid mixture formic acid and carbon dioxide. [Pg.143]

CsHjoOj Combustible liquid. Forms explosive mixture with air [explosion limits in air (vol %) 1.6 to uel unknown flash point 149°F/65°C Fire Rating 1]. Unless inhibited (200 ppm hydroquinone recommended), polymerization may occur avoid exposure to high temperatures, ultraviolet light, free-radical initiators. Reacts with water with release of heat may not be violent if not contained. Strong oxidizers may cause fne and explosions. Reacts violently with sodium peroxide, uranium fluoride. Incompatible with strong acids, nitrates. Incompatible with sulfuric acid, nitric acid, caustics, aliphatic amines, isocyanates, boranes. Thermal decomposition releases toxic acrid fumes of acrolein and acrylic acid. On small fires, use dry chemical powder (such as Purple-K-Powder), water spray, alcohol-resistant foam, or CO2 extinguishers. [Pg.899]

ACRYLIC ACID, 2-HYDROXYETHVL ESTER (818-61-6) Combustible liquid (flash point 214°F/101°C). Unless inhibited (/j-methoxyphenol is recommended), polymerization can occur, especially when heated. Violent reaction with strong oxidizers. Incompatible with permanganates, ammonium persulfate, bromine dioxide, strong acids sulfuric acid, nitric acid. Attacks mild steel and tin plate. Swells rubber removes paint. [Pg.41]