Manganese trifluoride

Silicon Alkali carbonates, calcium, chlorine, cobalt(II) fluoride, manganese trifluoride, oxidants, silver fluoride, sodium-potassium alloy... 

Up to 20 products with different numbers of fluorine atoms and double bonds have been isolated from the fluonnation of benzene with silver difluoride [d], manganese trifluoride [7], potassium tetrafluoroargentate [d], and potassium hexafluoronickelate [24] The composition of the products depends on the fluorinating agents and on the temperature (Table 1)... 

Table 1. Comparison of Fluorination of Benzene with Manganese Trifluoride [7], Potassium Hexafluoronickelate [24], Silver Difluoride [6], and Potassium Tetrafluorocobaltate [6]...

The Vapour Phase Fluorination of Trichloroethylene with Cobalt Trifluoride and with Manganese Trifluoride, G. Fuller, M. Stacey, J. C. Tatlow, and C. R. Thomas, Tetrahedron, 18 (1962) 123-133. 

Hydrogen hexafluorophophosphate, Borosilicate glass, 4360 Hydrogen peroxide, Diethyl ether, 4477 Imidazoline-2,4-dithione, 1141 Lithium nitride, Silicon tetrafluoride, 4688 Magnesium, Metal oxides, 4690 Manganese trifluoride, 4335 f Methylacrylate, 1531 Nitric acid, Glassware, 4436 Oxalic acid, Urea, 0725... 

Manganese trichloride oxide, 4141 Manganese trifluoride, 4335 Mercury(II) bromide, 0269 Mercury(I) fluoride, 4312 Mercury(II) iodide, 4602 Molybdenum hexafluoride, 4365 Molybdenum pentachloride, 4180 Neptunium hexafluoride, 4366 Osmium hexafluoride, 4370 Palladium tetrafluoride, 4347 Palladium trifluoride, 4341... 

Although manganese trifluoride (48) has a monoclinic unit cell, the... 

EXPLOSION and FIRE CONCERNS combustible solid in powder form flammable when exposed to flame or by chemical reaction with oxidizers NFPA rating (not available) reacts violently with alkali carbonates, oxidants, calcium, cesium carbide, cobalt difluoride, iodine pentafluoride, manganese trifluoride, nitrosyl fluoride, silver fluoride, and sodium-potassium alloys bums in fluorine and chlorine will react with water or steam to produce hydrogen when heated in case of fire, all extinguishing agents are allowed for firefighting purposes. 

Dicarboxylic Acids.— Perfluoro- -thiaglutaric add has been obtained by permanganate oxidation of fluorinated thiolens (10 X == Y = H X = H, Y = F X = Y = F X = Y = Cl) procured in studies of the fluorination of tetrachlorothiophen, thiophen, and tetrahydrothiophen with cobalt trifluoride, manganese trifluoride, and potassium tetrafluorocobaltate(m). The best route to this acid still appears to be fluorination of tetrachlorothiophen with silver difluoride followed by permanganate oxidation of the 3,4-dichlorotetrafluoro-3-thiolen (10 X = Y = Cl) thus obtained in not less than 45% yield. ... 

A Farlow-type reaction involving manganese trifluoride and graphite has been used to generate the gaseous species (CFj)n (n = 1, 2, 3 etc.), CFj, and CjFa under equilibrium conditions. By mass spectrometric methods it has been found that values of for CFa(g), CFj(g), and CjFgfg) are... 

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