Acetone Peroxides

Dimethyl peroxide Diethyl peroxide Di-t-butyl-di-peroxyphthalate Difuroyl peroxide Dibenzoyl peroxide Dimeric ethylidene peroxide Dimeric acetone peroxide Dimeric cyclohexanone peroxide Diozonide of phorone Dimethyl ketone peroxide Ethyl hydroperoxide Ethylene ozonide Hydroxymethyl methyl peroxide Hydroxymethyl hydroperoxide... [Pg.238]

Trimeric acetone peroxide Trimeric propylidene peroxide... [Pg.238]

Acetone cyanohydrin (stabilized), 6 Acetone tliiosemicarbazide, 6 Acetonitrile, 6 Acetophenetidin, 7 Acetophenone, 7 Acetyl acetone peroxide, 7 Acetyl bromide, 7 Acetyl chloride, 7... [Pg.319]

With reference to the mil literature available for unlimited publication, acetone peroxide has been considered for use as a detonating expl (Ref la), but was found to be too volatile at RT for such an application (see Vol 1, A42 R to A45-R)... [Pg.676]

Study of the Explosive Characteristics of Acetone Peroxide , PATR 1202 (1942)... [Pg.681]

Dimethyl peroxide Diethyl peroxide Di-t-butyl-di-peroxyphthalate Difuroyl peroxide Dibenzoyl peroxide Dimeric ethylidene peroxide Dimeric acetone peroxide Dimeric cyclohexanone peroxide Diozonide of phorone Dimethyl ketone peroxide Ethyl hydroperoxide Ethylene ozonide Hydroxymethyl methyl peroxide Hydroxymethyl hydroperoxide 1-Hydroxyethyl ethyl peroxide 1 -Hydroperoxy-1 -acetoxycyclodecan-6-one Isopropyl percarbonate Isopropyl hydroperoxide Methyl ethyl ketone peroxide Methyl hydroperoxide Methyl ethyl peroxide Monoperoxy succinic acid Nonanoyl peroxide (75% hydrocarbon solution) 1-Naphthoyl peroxide Oxalic acid ester of t-butyl hydroperoxide Ozonide of maleic anhydride Phenylhydrazone hydroperoxide Polymeric butadiene peroxide Polymeric isoprene peroxide Polymeric dimethylbutadiene peroxide Polymeric peroxides of methacrylic acid esters and styrene... [Pg.163]

A literature procedure whereby bromopyrimidine is oxidised by excess peroxy-acetic acid in acetone, with sulfuric acid catalysis, was being scaled up. The crude product from the fourth batch at two molar scale was filtered out and allowed to dry to dry in the sintered glass funnel over the weekend. An explosion occurred when it was scraped out to complete purification on the Monday. This was considered due to acetone peroxides, which had probably concentrated locally by wicking or sublimation. [Pg.481]

Action of hydrogen peroxide or permonosulfuric acid on acetone produces this dimeric acetone peroxide, which explodes violently on impact, friction or rapid heating. [Pg.824]

This trimeric acetone peroxide is powerfully explosive [1], and will perforate a steel plate when heated on it [2],... [Pg.1053]

Accidental addition of a little acetone to the residue from wet-ashing a polymer with mixed nitric-sulfuric acids and hydrogen peroxide caused a violent explosion [1]. The peroxoacid would be produced under these conditions, and is known to react with acetone to produce the explosive acetone peroxide [2], but direct oxidation of acetone may have been responsible. [Pg.1651]

During work-up of the products of ozonolysis of R- and S-citronellic acids, a substantial quantity of the highly explosive trimeric acetone peroxide (3,3,6,6,9,9-hexamethyl-l,2,4,5,7,8-hexoxonane) was unwittingly isolated by distillation at 105-135°C to give the solid m.p. 95°C. The peroxide appears to have been produced by ozonolysis of the isopropylidene group in citronellic acid, and presumably the same could occur when any isopropylidene group is ozonised. Appropriate care is advised. [Pg.1868]

Nef prepared acetol in several ways, the more important of which depended upon the reaction between bromoacetone and potassium or sodium formate or acetate, and the subsequent hydrolysis of the ester by methyl alcohol.1 2 Acetol is also formed, together with pyruvic acid, by the direct oxidation of acetone by Baeyer and Villiger s acetone-peroxide reagent.3... [Pg.2]

Some ketone-derived peroxides have explosive properties, of which the most interesting are obtained from acetone. Four acetone-derived peroxides have been synthesized. Acetone peroxide dimer (48) is obtained in 94 % yield by treating acetone with a slight excess of 86 % hydrogen peroxide in acetonitrile in the presence of concentrated sulfuric acid at subambient temperature. The reaction of acetone with potassium persulfate in dilute sulfuric acid also yields acetone peroxide dimer (48). Acetone peroxide trimer (49), also known as triacetone triperoxide (TATP), has been obtained as a by-product of these reactions or by the addition of... [Pg.339]

Two forms of acetone peroxides are known to exist a dimer called diacetone diperoxide (DADP) and a trimer called triacetone triperoxide (TATP). Figure 3.4 displays the chemical structures of each. [Pg.55]

Figure 3.4 Chemical structures of acetone peroxide molecules.

Dimeric Acetone Peroxide Explodes violently by percussion and rubbing A. Baeyer V. Villiger, Ber 32, 3632 (1899)... [Pg.226]

The explosive properties of peroxides have attracted attention for a long time, mainly because of their initiating properties namely, in a confined space burning readily passes into detonation. In spite of this, virtually none of the peroxides has found practical application. Some are rather unstable, others are very volatile and all are highly sensitive to friction and impact e.g. acetone peroxide, very easily prepared by the action of potassium persulphate on acetone in the presence of sulphuric acid (Baeyer and Villiger [82]) possesses, according to T. Urbanski s [83]... [Pg.225]

Dimeric Acetone Peroxide, See Acetone — peroxide, Dimeric in Vol 1, p A41-R... [Pg.194]

Following props(Ref 6) of dimeric acetone peroxide were deed at PicArsn action with match flame — a slight puff hrisance by sand test — 30.1 g sand crushed when 0.4 g of peroxide was initiated with 0.2 g MF, vs 48.0 g sand crushed by 0.4 g TNT impact sensitivity, BurMinesApp with 2 kg wt —... [Pg.42]

Addnl Refs on Dimeric Acetone Peroxide a)Sprengwerke Dr R.Nahsen, GerP 423,176 (1925) BritCA, SeceB(1926), p 6l3(Use of acetone peroxides in fuzes, detonators and caps in lieu of MF) b)N-V.de Bataafsche Petroleum Maatschappij, BritP 444,544(1936)... [Pg.42]

CA 33,3399(1939)[Acetone peroxides, as well as peroxides of higher mol wt ketones, may be prepd by treating a ketone with hydrogen peroxide (obtained by hydrolysis of HjSaOa or a persulfate in the reaction bath) at low temp in the presence of a strong acid and a stabilizer, such as urea. The resulting peroxide is extracted with gasoline]... [Pg.42]

Trimeric acetone peroxide expld violently on heating, impact or friction. It is highly brisant and very sensitive. It may be detond under water or when it contains up to 25% of moisture(Ref 15)... [Pg.43]

Refs on Trimeric Acetone Peroxide l)Beil 1,645 [714] 2)R. woifenstein,Ber28,2265... [Pg.44]

Addnl Refs on Trimeric Acetone Peroxide a)Sprengstoffwerke Dr Nahsen,GerP 423, 176(1925) Brit C A. Sect B, 1926,613 (Dse of acet peroxide in detonators, caps and fuzes in lieu of MF) b)A.E.Thiemann,ChZtr 194211,2757—8(Acet peroxides are claimed to be effective ignition promoters when added to Diesel fuels) c)R.Acree H.L.Haller,... [Pg.44]

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