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Acetone peroxide, trimeric

Trimeric acetone peroxide Trimeric propylidene peroxide... [Pg.238]

This trimeric acetone peroxide is powerfully explosive [1], and will perforate a steel plate when heated on it [2],... [Pg.1053]

During work-up of the products of ozonolysis of R- and S-citronellic acids, a substantial quantity of the highly explosive trimeric acetone peroxide (3,3,6,6,9,9-hexamethyl-l,2,4,5,7,8-hexoxonane) was unwittingly isolated by distillation at 105-135°C to give the solid m.p. 95°C. The peroxide appears to have been produced by ozonolysis of the isopropylidene group in citronellic acid, and presumably the same could occur when any isopropylidene group is ozonised. Appropriate care is advised. [Pg.1868]

Trimeric Acetone Peroxide Very explosive can penetrate a plate of iron when heated on it A. Baeyer V. Villiger, Ber 32, 3632 (1899)... [Pg.226]

Trimeric acetone peroxide expld violently on heating, impact or friction. It is highly brisant and very sensitive. It may be detond under water or when it contains up to 25% of moisture(Ref 15)... [Pg.43]

Refs on Trimeric Acetone Peroxide l)Beil 1,645 [714] 2)R. woifenstein,Ber28,2265... [Pg.44]

Addnl Refs on Trimeric Acetone Peroxide a)Sprengstoffwerke Dr Nahsen,GerP 423, 176(1925) Brit C A. Sect B, 1926,613 (Dse of acet peroxide in detonators, caps and fuzes in lieu of MF) b)A.E.Thiemann,ChZtr 194211,2757—8(Acet peroxides are claimed to be effective ignition promoters when added to Diesel fuels) c)R.Acree H.L.Haller,... [Pg.44]

Isopropylidene Compounds. Ozonolysis of any compound containing an isopropylidene group may yield the highly explosive trimeric acetone peroxide.14... [Pg.419]

Criegee et al.le converted the bishydroperoxide (75) into the cyclic peroxide (76), which is isosteric with trimeric acetone peroxide, by reaction with acetone in the presence of copper sulfate as a condensing agent. [Pg.182]

Thus the ozonization of tetramethylethylene leads to dimeric acetone peroxide (125)86 (as well as trimeric acetone peroxide), that of tetraphenylethylene130 and 1,1-diphenylethylene62 leads to... [Pg.198]

Trimeric Acetone Peroxide. See under Acetone Peroxides A42-R Trimeric Methyleneaniline. See Anhydro formaldehydeaniline A404-R Trimethylaniline. See Aminohemimellitene A215-R... [Pg.692]

See other pages where Acetone peroxide, trimeric is mentioned: [Pg.163]    [Pg.170]    [Pg.457]    [Pg.830]    [Pg.995]    [Pg.1628]    [Pg.1635]    [Pg.864]    [Pg.44]    [Pg.513]    [Pg.898]    [Pg.1053]    [Pg.1697]    [Pg.1704]    [Pg.450]    [Pg.830]    [Pg.995]    [Pg.1628]    [Pg.1635]    [Pg.170]    [Pg.172]    [Pg.163]    [Pg.44]    [Pg.44]   
See also in sourсe #XX -- [ Pg.42 , Pg.45 ]



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Acetone Peroxides

Trimeric

Trimerization

Trimers

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