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A -glycosides

Maltose obtained by the hydrolysis of starch and cellobiose by the hydrolysis of cellulose are isomenc disaccharides In both maltose and cellobiose two d glucopyra nose units are joined by a glycosidic bond between C 1 of one unit and C 4 of the other The two are diastereomers differing only m the stereochemistry at the anomeric carbon of the glycoside bond maltose is an a glycoside cellobiose is a (3 glycoside... [Pg.1046]

FIGURE 25 6 Molecu lar models of the disaccha rides maltose and cellobiose Two D glucopyranose units are connected by a glycoside linkage between C 1 and C 4 The glycosidic bond has the a orientation in maltose and IS p in cellobiose Mai tose and cellobiose are diastereomers... [Pg.1047]

Both maltose and cellobiose have a free anomeric hydroxyl group that is not involved in a glycoside bond The configuration at the free anomeric center is variable and may be either a or (3 Indeed two stereoisomeric forms of maltose have been iso lated one has its anomeric hydroxyl group m an equatorial orientation the other has an axial anomeric hydroxyl... [Pg.1047]

This reaction has been used m an imaginative way to determine the ring size of glycosides Once all the free hydroxyl groups of a glycoside have been methylated the glycoside is subjected to acid catalyzed hydrolysis Only the anomeric methoxy group IS hydrolyzed under these conditions—another example of the ease of carbocation for matron at the anomeric position... [Pg.1059]

Several other naturally occurring antioxidants have been identified in oils. Sesamol [533-31-3] (6) occurs as sesamoline [526-07-8], a glycoside, in sesame seed oil. FemUc acid [1135-24-6] (7) is found esterified to cycloartenol [469-38-5] in rice bran oil and to 3-sitosterol in com oil. Although it does not occur in oils, rosemary extract has also been found to contain powerful phenoHc antioxidants (12). [Pg.124]

In 1885, from a detailed study of juglone (52) it was proposed that its stmcture was 5-hydroxy-l,4-naphthoquinone (9). This stmcture was confirmed by oxidizing 1,5-dihydroxynaphthalene with potassium dichromate in sulfuric acid (53). Juglone occurs in walnuts as a glycoside of its reduced form, 1,4,5-trihydroxynaphthalene (54). Later it was deterrnined that the sugar is in the 4-position (10) (55). [Pg.397]

The leaves of the indigo plant do not contain the dye as such, but in the form of its precursor, a glycoside known as indican (109). Indican [487-60-5] is the dextrose derivative (35) of indoxyl [480-93-3] (110). Indoxyl occurs also in the urine of humans as the potassium salt of indoxyl sulfonic acid (111). [Pg.402]

The most familiar of all the carbohydrates is sucrose—common table sugar. Sucrose is a disacchar ide in which D-glucose and D-fructose are joined at then anomeric carbons by a glycosidic bond (Figure 25.7). Its chemical composition is the same ine-spective of its source sucrose from cane and sucrose from sugar beets are chemically identical. Because sucrose does not have a free anomeric hydroxyl group, it does not undergo mutarotation. [Pg.1048]

The small change in stereochemistry between cellulose and amylose creates a large difference in their overall shape and in their properties. Some of this difference can be seen in the strorcture of a short portion of fflnylose in Figure 25.9. The presence of the a-glycosidic linkages imparts a twist to the fflnylose chain. Where the main chain is roughly linear- in cellulose, it is helical in anylose. Attractive forces between chains are weaker in fflnylose, and fflnylose does not form the same kind of strong fibers that cellulose does. [Pg.1049]

Sections Disaccharides are carbohydrates in which two monosaccharides are 25.14-25.15 joined by a glycoside bond. Polysaccharides have many monosaccharide units connected through glycosidic linkages. Complete hydrolysis of disaccharides and polysaccharides cleaves the glycoside bonds, yielding the free monosaccharide components. [Pg.1062]


See other pages where A -glycosides is mentioned: [Pg.138]    [Pg.188]    [Pg.189]    [Pg.337]    [Pg.145]    [Pg.266]    [Pg.270]    [Pg.1044]    [Pg.1047]    [Pg.1048]    [Pg.1049]    [Pg.1062]    [Pg.1062]    [Pg.273]    [Pg.480]    [Pg.427]    [Pg.278]    [Pg.280]    [Pg.117]    [Pg.32]    [Pg.475]    [Pg.476]    [Pg.476]    [Pg.477]    [Pg.478]    [Pg.487]    [Pg.395]    [Pg.395]    [Pg.396]    [Pg.148]    [Pg.102]    [Pg.1043]    [Pg.1044]    [Pg.1047]    [Pg.1062]    [Pg.221]    [Pg.221]   
See also in sourсe #XX -- [ Pg.292 ]

See also in sourсe #XX -- [ Pg.440 , Pg.1316 ]

See also in sourсe #XX -- [ Pg.86 ]

See also in sourсe #XX -- [ Pg.292 ]

See also in sourсe #XX -- [ Pg.21 , Pg.162 ]

See also in sourсe #XX -- [ Pg.162 ]




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2-Deoxy-a-glycosides

A Molecular Basis for the Cluster Glycoside Effect

A- and -Glycosides

A- and B-Glycosides

A-1,4-Glycosidic bonds

A-Allyl glycosides

A-Allyl glycosides from D-glucal triacetate

A-Benzyl glycosides

A-C-Glycosides by reaction of acyl ester

A-C-Glycosides stereoselectivity

A-C-glycoside synthesis by Sml2mediated reduction

A-C-glycosides

A-Glycosidation

A-Glycoside synthesis

A-Glycosides benzyl-type protecting groups

A-Glycosides stereoselective construction

A-Selective thermal glycosidation

A-d- -glycoside bonds

A-glycosidic linkage

A-l,4 glycosidic linkage

A-l,4-Glycosidic link

A-l,6-Glycosidic bonds

Allylic a-C-glycoside

As components of cardiac glycosides

C-Glycosides as Stable Pharmacophores

Carbocations as intermediates in glycoside formation

Carbohydrates as components of cardiac glycosides

Enzymatic Synthesis of Alkyl Glycosides with Ionic Liquid as a Modulator

Flavonoids as glycosides

Formation of a Glycoside

Glycosidation a-selective

Glycosidations on a Solid Phase

Glycosides (s. a. Carbohydrates

Glycosides (s. a. Carbohydrates Ethers, Thioglycosides

Glycosides (s. a. Carbohydrates acylglycosides

Glycosides a glycoside

Glycosides as glycosyl donors

Hydrolysis of a Glycoside

Isopropenyl glycosides as glycosyl donors

Methyl a-glycoside

Pentenyl Glycosides as Glycosyl Donors

Regio- and a-Stereoselective Sialyl Glycoside Syntheses Using Thioglycosides of Sialic Acids in Acetonitrile

Use of vinyl glycosides as glycosyl donors

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