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Zinc aryls

Thiophenols (or aryl mercaptans) are obtained by more vigorous reduction of sulphonyl chlorides (or of sulphinic acids), for example with zinc and dilute sulphuric acid, and are isolated by steam distillation ... [Pg.821]

The terminal diyne 320 is prepared by coupling of the zinc acetylide 318 with /rfln.s-l-iodo-2-chloroethylenc (319), followed by elimination of HCI with sodium amide[231]. Similarly, terminal di- and triynes are prepared by using cw-l,2-dichloroethylene[232]. The 1-alkenyl or l-aryl-2-(perefluoroalkyl) acetylene 321 is prepared by the reaction of a zinc acetylide with halides[233]. [Pg.173]

Lithiation at C2 can also be the starting point for 2-arylatioii or vinylation. The lithiated indoles can be converted to stannanes or zinc reagents which can undergo Pd-catalysed coupling with aryl, vinyl, benzyl and allyl halides or sulfonates. The mechanism of the coupling reaction involves formation of a disubstituted palladium intermediate by a combination of ligand exchange and oxidative addition. Phosphine catalysts and salts are often important reaction components. [Pg.98]

The most commonly used method for reducing an aryl ketone to an alkylbenzene employs a zinc-mercury amalgam m concentrated hydrochloric acid and is called the Clemmensen reduction Zinc is the reducing agent... [Pg.486]

Dehalogenation of monochlorotoluenes can be readily effected with hydrogen and noble metal catalysts (34). Conversion of -chlorotoluene to Ncyanotoluene is accompHshed by reaction with tetraethyl ammonium cyanide and zero-valent Group (VIII) metal complexes, such as those of nickel or palladium (35). The reaction proceeds by initial oxidative addition of the aryl haHde to the zerovalent metal complex, followed by attack of cyanide ion on the metal and reductive elimination of the aryl cyanide. Methylstyrene is prepared from -chlorotoluene by a vinylation reaction using ethylene as the reagent and a catalyst derived from zinc, a triarylphosphine, and a nickel salt (36). [Pg.53]

Several types of nitrogen substituents occur in known dye stmetures. The most useful are the acid-substituted alkyl N-substituents such as sulfopropyl, which provide desirable solubiUty and adsorption characteristics for practical cyanine and merocyanine sensitizers. Patents in this area are numerous. Other types of substituents include N-aryl groups, heterocycHc substituents, and complexes of dye bases with metal ions (iridium, platinum, zinc, copper, nickel). Heteroatom substituents directly bonded to nitrogen (N—O, N—NR2, N—OR) provide photochemically reactive dyes. [Pg.397]

Materials that promote the decomposition of organic hydroperoxide to form stable products rather than chain-initiating free radicals are known as peroxide decomposers. Amongst the materials that function in this way may be included a number of mercaptans, sulphonic acids, zinc dialkylthiophosphate and zinc dimethyldithiocarbamate. There is also evidence that some of the phenol and aryl amine chain-breaking antioxidants may function in addition by this mechanism. In saturated hydrocarbon polymers diauryl thiodipropionate has achieved a preeminent position as a peroxide decomposer. [Pg.140]

Organometallics, such as dialkyl zinc or cadmium-alkyl or aryl lithium Alkali acetylides Diels-Alder Arndt-Eistert... [Pg.254]

As noted, these zinc reagents find extensive application in the preparation of fluorinated styrenes [113, 114], aryl-substituted fluorinated propenes [114],fluor-inateddienes [115,116], and tnfluorovinyl ketones [117], as illustrated in equations 83-88... [Pg.689]

Modifications of this method, such as the use of the more stable diazonium trifluoroacetates and the decomposition of benzenedia-zonium zincichloride with zinc dust, have been used as sources of aryl radicals, although not in the arylation of heterocyclic compounds. Pyridine, quinoline, and thiophene can be phenylated by treatment with benzenediazonium chloride and aluminum trichloride. ... [Pg.132]

The difficulties encountered in the synthesis of 2-alkyl- and 2-aryl-substituted selenazoles lie principally in the preparation of the corresponding selenoamides. In this respect, a method is worthy of note in which the use of selenoamides is dispensed with. For this, a nitrile, a hydrogen selenide, and an a-halogenoketone are reacted together in the presence of a condensation catalyst. Phosphorus oxychloride, alone or mixed with zinc chloride or phosphorus trichloride, is specially suitable. The yields of the corresponding 2-alkylseIenazoles are up to a maximum of 25%,... [Pg.345]

An analogous reaction is the Houben-Hoesch reaction,(sometimes called the Hoesch reaction) using nitriles 7 to give aryl ketones 8. This reaction also is catalyzed by Lewis acids often zinc chloride or aluminum chloride is used. The Houben-Hoesch reaction is limited to phenols—e.g. resorcinol 6—phenolic ethers and certain electron-rich aromatic heterocycles ... [Pg.134]

In addition to sodium, other metals have found application for the Wurtz coupling reaction, e.g. zinc, iron, copper, lithium, magnesium. The use of ultrasound can have positive effect on reactivity as well as rate and yield of this two-phase reaction aryl halides can then even undergo an aryl-aryl coupling reaction to yield biaryls. ... [Pg.305]

Knochel et al. described Pd-catalyzed Negishi cross-coupling reactions between zinc organometallics and aryl iodides in [BMMlM][Bp4]. Scheme 5.2-20 illustrates the reaction for the formation of a 3-substituted cyclohexenone from 3-iodo-2-cyclo-hexen-l-one [82]. [Pg.243]


See other pages where Zinc aryls is mentioned: [Pg.47]    [Pg.13]    [Pg.247]    [Pg.201]    [Pg.47]    [Pg.13]    [Pg.247]    [Pg.201]    [Pg.314]    [Pg.89]    [Pg.185]    [Pg.212]    [Pg.213]    [Pg.215]    [Pg.32]    [Pg.111]    [Pg.26]    [Pg.110]    [Pg.35]    [Pg.99]    [Pg.81]    [Pg.925]    [Pg.310]    [Pg.8]    [Pg.119]    [Pg.56]    [Pg.123]    [Pg.267]   


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