Wavelength selection optics

All lasers have the following three fundamental components (see Figure 1). The gain medium, the business end of the laser, is the medium in which excited states are created which will produce stimulated emission. The exciter is the source of energy for production of the excited states in the gain medium. Finally, the optical resonator determines the directionality, wavelength selectivity, optical feedback, polarization, and other characteristics of the stimulated emission from the gain medium. 

Similar to cw lasers, active media with a broad spectral gain profile can be used for pulsed lasers. With wavelength-selective optical elements inside the laser resonator, the laser wavelength can be tuned across the whole gain profile. However, the drawback is the widening of the pulse length AT with decreasing spectral width Av due to the principal Fourier limit AT > 27t/Av. 

Infrared instruments using a monochromator for wavelength selection are constructed using double-beam optics similar to that shown in Figure 10.26. Doublebeam optics are preferred over single-beam optics because the sources and detectors for infrared radiation are less stable than that for UV/Vis radiation. In addition, it is easier to correct for the absorption of infrared radiation by atmospheric CO2 and 1420 vapor when using double-beam optics. Resolutions of 1-3 cm are typical for most instruments. 

Laser Photochemistry. Photochemical appHcations of lasers generally employ tunable lasers which can be tuned to a specific absorption resonance of an atom or molecule (see Photochemical technology). Examples include the tunable dye laser in the ultraviolet, visible, and near-infrared portions of the spectmm the titanium-doped sapphire, Tfsapphire, laser in the visible and near infrared optical parametric oscillators in the visible and infrared and Line-tunable carbon dioxide lasers, which can be tuned with a wavelength-selective element to any of a large number of closely spaced lines in the infrared near 10 ]lni. 

Sx, Ti -> Tx). Figures 3.2 and 3.3 illustrate the principle of flash spectroscopy/65 If the second light source is continuous, the change in optical density due to the transient species can be monitored as a function of time at a particular wavelength selected on a monochromator. This type of system is illustrated in Figure 3.4. 

Films of pure CNLCs have a unique transmission behavior as CP light with the same sense of circular polarization as the CNLC is filtered out by reflection, while CP light of the opposite handedness as the CNLC film is transmitted. This selective optical transmission characteristic is referred to as a one-dimensional photonic stop-band or a selective reflection band. The stop-band is centered at a certain wavelength Ac, which is dependent on the pitch length p and the average refractive index n of the CNLC ... 

Figure 12.1 shows the classic L-format of the most commonly used fluorescence spectrometer configuration which is topologically the same for the measurement of both steady-state spectra and lifetimes. The source and detector options of relevance to IR fluorescence measurements are discussed in Sections 12.3 and 12.4, respectively. The other optical components comprised of the lenses for focusing and collection and monochromators for wavelength selection contain few peculiarities in the near-IR as... 

Capillary overheating Detector lamp either is not on or is weak. Also, poor selected optical wavelength Light Intensity through cell is low... 

Note that this condition is extremely wavelength selecting. For a given angle of incidence between the input optical beam and the acoustic wave front, and a given value of the acoustic wavelength, only one value of A is permitted. 

The light beam emitted by the source, which must be at the wavelength required for measurement, passes through the flame (or graphite furnace) in which the element is located in its atomic state. The beam is then focused on the entrance slit of the monochromator, located after the sample. The monochromator s role is to select a very narrow band of wavelengths. The optical path ends at the entrance slit of the photomultiplier tube. 

Angel, S.M., and M.L. Myrick. 1990. Wavelength selection for fiber optic Raman spectroscopy. Applied Optics 29 1350-1352. 

All steady-state measurements are performed on a SLM 48000 modified to accommodate the optical cells (72). A Xe-arc lamp is used for excitation, and both excitation and emission monochromators are used for wavelength selection. 

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