Water Sampling Rates

Sampling rates at different temperatures have been determined by Huckins et al. (1999) for PAHs at 10,18, and 26 °C, by Rantalainen et al. (2000) for PCDDs, PCDFs, and non-ortho chlorine substituted PCBs at 11 and 19 °C, and by Booij et al. (2003a) for chlorobenzenes, PCBs, and PAHs at 2,13 and 30 °C. The effect of temperature on the sampling rates can be quantified in terms of activation energies (A a) for mass transfer, as modeled by the Arrhenius equation 

The relative sampling rate of a single compound (i) that is exposed under different site conditions (j = 1, 2) equals 

Dividing Eq. 3.30 by Eq. 3.32 gives the sampling rate of compound i in exposure) 

The reference sampling rate (/ s,ref) as well as the exposure-specific effect jSj are divided out. For practical applications, it therefore suffices to know how the compound-specific effect depends on the properties of the analytes. Observing that the experimental sampling rates have a similar dependence on log ATow, but show a varying offset for the different studies, the log-transformed sampling rates observed in 19 calibration experiments in 9 studies were fitted as a third order polynomial in log Kq - 

Theoretical Uptake Model Membrane-Controlled Uptake 

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Table A.5 Water Sampling Rates (/ ss) and Uptake Rate Constants (kys) of 4.5 g, 460 cm SPMDs at a Temperature of 25 °C, and Flow Rates of 0.01 and 50 cm s (Luellen and Shea, 2002)...

Table A.7 Water Sampling Rates (R s) and Uptake Rate Constants (kys) of 4.5 g,...

FIGURE 4.17 Effect of ionic strength on the elution of anionic polymers. Column TSK-GEL GMPW, two 17 fjLirt, 7.5 mm X 60 cm columns in series. Sample 0.5 ml of 0.05-0.1% of the sodium salt of polyacrylic acid, an anionic polymer. Elution Water 0.01, 0.025, 0.05, or 0.1 M NaNOs in water. Flow rate 0.5 ml/min. Detection Rl. 

FIGURE 4.24 Adsorption chromatography of small molecules with a TSK-GEL G2500PWxl column. Column TSK-GEL G2500PWxl, 6 /tm, 7.8 mm X 30 cm. Sample (I) phenylacetic acid. (2) 3-phenylpropionic acid, (3) 4-phenylbutyric acid, (4) benzylamine, (5) 2-phenylethylamine, (6) 3-phenylpropylamine, (7) benzyl alcohol, (8) 2-phenylethanol, and (9) 3-phenyl-1 -propanol. Elution 0.1 M NaCIO, in water. Flow rate 2.0 ml/min. Temperature 65 C. Detection UV at 215 nm. 

Use jar tests to determine the most suitable types of polymers and potential application rates. Tests must be conducted on-site with fresh, representative water samples and fresh reagents. 

Paolini, 1986 Stallard, 1980). Comparison with Fig. 9-7 shows a reasonable match between denudation rates and uplift rates for a particular type of terrain. The most concentrated water samples and highest denudation rates are observed in river basins in tectonically active areas. 

The official analytical method of the Ministry of Environment, Japan, recommends the use of a Cig cartridge to determine naproanilide. This method consists of the following procedure 5 mL of the 1N hydrochloric acid are added to the water sample and the solution is applied to a Cig cartridge, which is preconditioned with 5 mL each of acetonitrile and water, at a flow rate of 10-20 mL min. Naproanilide and its metabolite, 2-(2-naphthoxy)propionic acid, are eluted with 10 mL of acetonitrile. 

A monitoring system has been established to determine 90 pesticides including anilides and 10 related degradation products in river water. Pesticide residues in the water sample are collected on a PS-2 cartridge (265-mg) at a flow rate of 10 mL min, eluted with 3 mL of acetone, 3 mL of n-hexane and 3 mL of ethyl acetate successively, and determined by GC/MS. Overall recoveries ranged from 72 to 118%. Recoveries of mepronil, naproanilide, propanil and flutolanil at fortification levels of 0.1 and 2 mg kg Mn water by this method were 80-112%. The LODs were 0.01 -0.1 pg L ... 

A multi-residue method for 25 selected pesticides including propanil using an SPE disk has also been developed as a rapid screening method for organic contaminants in river, lake and seawater samples. Cig SPE disks are conditioned with 10 mL of acetone for 3 h. Water samples (1L) are allowed to percolate through the disks in order to trap the residues at a fiow rate of 50 mL min under vacuum. Residues trapped in the disks are extracted twice by eluting with 5 mL of dichloromethane-ethyl acetate (1 1, v/v). The more hydrophobic compounds (log/fow>3) seem to show no... 

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