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Water injection systems media

Membrane separation coupled on-line to a flow-injection system was employed for the monitoring of propazine and terbutryn in natural water. A microporous hydro-phobic membrane was utilized in which the analytes were extracted from the aqueous medium into an organic solvent that was carried to the flow cell of a photodiode-array spectrophotometer. The LCDs were 4-5 qg so the technique could potentially be used for screening purposes. Samples with positive detection would require further analysis. [Pg.427]

Cyanides Tap, mineral waters GD UV-Vis 2.5 pg L-1 Sequential injection system analyte reaction with ninhydrin in carbonate medium to yielding the coloured product standard addition method [531]... [Pg.383]

A highly sensitive fluorescence quenching method for the determination of silicate based on the formation of an ion associate between molybdosilicate and Rhodamin B (RB) in nitric acid medium was developed. A flow-injection system coupled with a fluorescence detector was used for the measmement of fluorescence intensity at 560 and 580 ran as excitation and emission wavelengths, respectively. The calibration graph for Si showed a linear range of 0.1-5 ng/cm with correlation coefficient of 0.9999, and the detection limit of 0.06 ng/cm. The proposed method was successfully applied to the determination of silicate in ultrapurified water with satisfactory results. [Pg.323]

Offshore platforms are, in essence, similar to buried pipelines because in both, external and internal surfaces are exposed to corroding environments in buried pipelines the external surface of the pipe is exposed to the soil (which is a corrosive environment), and its internal surface is under the corrosive impact of the fluid that is going through, either water, oil or the like. In case of offshore platforms, the whole immersed stmcture is exposed to seawater (a corrosive medium), and the internal surfaces of the systems such as seawater injection systems or oil storage facilities can be considered locations at which corrosion is occurring internally. [Pg.116]

The presence of water, or water vapour, affects the chemistry of thermal modification and heat transfer within the wood (Burmester, 1981). Under dry treatment conditions, the wood is dried prior to thermal modification, or water is removed by the use of an open system, or a recirculating system equipped with a condenser. In closed systems, water evaporated from the wood remains as high-pressure steam during the process. Steam can also be injected into the reactor to act as a heat-transfer medium, and can additionally act as an inert blanket to limit oxidative processes. Such steam treatment processes are referred to as hygrothermal treatments. Where the wood is heated in water, this is known as a hydrothermal process. Hydrothermal treatments have been extensively studied as a... [Pg.101]

First, consider the diffusion of an organic compound across the boundary between two environmental systems, A and B. Imagine that at time 1 = 0, the surface of system A (e.g., an air bubble, a silt particle, etc.) is suddenly juxtaposed to a (very large) system B (e.g., the water of a lake, Fig. 18.5a). Mixing in system B is sufficient that the concentration of the selected compound at the boundary of the injected medium is kept at the constant value, Cg. This concentration is different from the initial concentration in A, CA. In system A, transport occurs by diffusion only. We want to calculate the concentration in system A as it evolves in space and time, CA(x,t). For the time being, we will assume that the equilibrium distribution coefficient between A and B is 1. Hence, the concentration of A seeks to change to be equal to that of system B. [Pg.792]

Essentially, TFE in gaseous state is polymerized via a free radical addition mechanism in aqueous medium with water-soluble free radical initiators, such as peroxy-disulfates, organic peroxides, or reduction-activation systems.15 The additives have to be selected very carefully since they may interfere with the polymerization. They may either inhibit the process or cause chain transfer that leads to inferior products. When producing aqueous dispersions, highly halogenated emulsifiers, such as fully fluorinated acids,16 are used. If the process requires normal emulsifiers, these have to be injected only after the polymerization has started.17 TFE polymerizes readily at moderate temperatures (40 to 80°C) (104 to 176°F) and moderate pressures (0.7 to 2.8 MPa) (102 to 406 psi). The reaction is extremely exothermic (the heat of polymerization is 41 kcal/mol). [Pg.18]

It has to be clear that, once diluted and injected (or administered in ocular and other routes), the emulsion stability and fate are determined by three measurable parameters. The first is the partition coefficient of each emulsion component (including added drugs and agents) between the emulsion assembly and the medium. To some extent this partition coefficient is related to oil-water and/or octanol-water partition coefficients. For example, it was well demonstrated that per component of which logP is lower than 8, the stability upon intravenous (IV) injection is questionable [42,138], The other two parameters are kQff, a kinetic parameter which describes the desorption rate of an emulsion component from the assembly, and kc, the rate of clearance of the emulsion from the site of administration. This approach is useful to decide if and what application a drug delivery system will have a chance to perform well [89],... [Pg.1346]

In most foam displacement applications, the gas and liquid phases (the latter containing the foaming agent) are injected simultaneously or intermittently with the foam being formed in situ. In particular, as gas passes through the porous medium in the presence of foaming agent, several pore level events contribute to the formation of the foam bubbles. Such processes are similar to those observed with oil-water systems (16). [Pg.297]

Nonionic contrast media in either hypertonic or hypotonic solution, when injected in-tracerebrally or into the subarachnoid space of rats, will cause distinct depression of the central nervous system (CNS) and associated brain functions but no excitation (675). Such depressive action can obscure the excitatory action caused by ionicity or chemotoxicity of myelographic agent. When an isotonic contrast medium is injected and mixed with the normally produced cerebrospinal fluid (CSF) in the subarachnoid space of the rat, the resultant mixture is hypertonic with higher levels of sodium and chloride. This movement of sodium and chloride into CSF without accompaniment of water is unexpected. Mennini et al. (672) noted that contrast enhancement of brain parenchyma is never achieved by direct intracarotid or intravenous injection of nonionic contrast media, unless the BBB is spontaneously or experimentally broken ( 6). [Pg.555]


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