Water-dispersable starch polymer

Dried flavoring wall material development conducted in this study was completed in two separate phases. Firstly, a water-dispersable starch polymer which 1) exhibited good flavor retention potential during spray drying and 2) was able to form a stable flavor-incorporated aqueous emulsion was examined. 

For example, starch is the principal water-dispersible natural polymer used industrially as an adhesive and in its many forms it is widely employed in the paper and paper products industry. Poly(vinyl acetate) and its copolymers are synthetic materials and are usually used as aqueous latices. They have found widespread used in the paper industry, where their often superior properties offset their higher price, and are used in bookbinding, milk cartons, envelopes, etc. and are also very familiar as the household white glue for woodworking. 

Amylose (Section 25.15) The water-dispersible component of starch. It is a polymer of a(l,4)-linked glucose units. 

There are five prime factors that determine the properties of starches 1. starch is a polymer of glucose (dextrose) 2. the starch polymer is of two types linear and branched 3 the linear polymeric molecules can associate with each other giving insolubility in water 4. the polymeric molecules are organized and packed into granules which are insoluble in water and 5 disruption of the granule structure is required to render the starch polymer dispersible in water. The modification of starch takes into account these factors. 

Starch (amylose and amylopectin) hydrolysis along with ester-fication, etherification or oxidation have been previously discussed as available methods for producing starch derivatives with improved water dispersibilities and reduced retrogradation potential (, ). Since oxidative and hydrolytic reactions are simple, easily controlled chemical modifications, starch-derived polymers made by hydrolysis alone or oxidative and hydrolytic processes were developed and tested. 

Preparation of DMS0-Soluble Starch-g-PAN Samples and Water-Soluble Starch-g-Polyacrylamide. Five grams of starch- -PAN (prepared by either ceric- or cobalt-60 initiation) was dispersed in 333 g of DMSO, and the dispersion was heated for 2 hr at 115°C. The cooled dispersion was then treated with ultrasound for 10 min to mechanically rupture gel particles and to render the polymer soluble (Branson Sonifier, Model S 125 ... 

Five grams of starch-g-polyacrylamide was dispersed in 333 ml of water and the mixture was heated for 4.5 hr at 95-100°C. The cooled dispersion was then treated with ultrasound, as described for starch-g-PAN in DMSO. The resulting solution was gravity-filtered through fluted Whatman 54 paper, and the filtrate was freeze-dried to give 4.4 g of polymer. To give a denser, more compact product, which might more closely resemble soluble starch-g-PAN, the freeze-dried polymer was dispersed in 20 ml of water, and the polymer was precipitated from the thick paste by addition of ethanol. The polymer was separated by filtration, washed with ethanol, and vacuum dried at 60°C. 

Most types of Hot melt adhesives used in the mannfacture of laminates and in rapid Packaging industry applications are mineral oil-derived, hydrophobic and essentially non-dispersible, so they cannot be considered as renewable. However, some basic polymers have been prepared over the last decade from vegetable sources, which are renewable, and are adhesive, although these properties have limitations. These include poly(hydro-xybutyrate/hydroxyvalerate) (PHBV), poly(lactide) (which has poor thermal stability), and starch esters. Adhesives based on sulphonated polyesters with polar petroleum waxes have improved adhesion and adequate water dispersibility. In general, however, the perfect adhesive from renewable resources with satisfactory adhesion properties remains to be discovered. 

Fanta GF, FeUser FC, Eskins K, Baker FL. 1999a. Aqueous starch-oil dispersions prepared by steam jet cooking. Starch films at the oil-water interface. Carbohydr Polym 38 25-35. 

Polymers. In combination with various metal salts, sorbitol is used as a stabilizer against heat and light in poly(vinyl chloride) (qv) resins and, with a phenohc antioxidant, as a stabilizer in uncured styrene—butadiene mbber (qv) compositions and in polyolefins (see Heat stabilizers Olefin POLYMERS Rubbercompounding). Heat-sealable films are prepared from a dispersion of sorbitol and starch in water (255). Incorporation of sorbitol in coUagen films gready restricts their permeabiUty to carbon dioxide (256). 

The synthetic approach is very simple and does not require any special set up. In a typical room temperature reaction, 1.0 mL aqueous solution of cadmium chloride was added to 20 mL aqueous solution of soluble starch in a 50 mL one-necked round-bottom flask with constant stirring at room temperature. The pH of the solution was adjusted from 6 to 11 using 0.1 M ammonia solution. This was followed by a slow addition of 1.0 mL colourless selenide ion stock solution. The mixture was further stirred for 2 h and aged for 18 h. The resultant solution was filtered and extracted with acetone to obtain a red precipitate of CdSe nanoaprticles. The precipitate was washed several times and dried at room temperature to give a material which readily dispersed in water. The same procedure was repeated for the synthesis of PVA and PVP - capped CdSe nanoparticles by replacing the starch solution with the PVA and PVP polymers while the synthesis of elongated nanoparticles was achieved by changing the Cd Se precursor ratio from 1 1 to 1 2. The synthesis of polymer capped ZnSe nanoparticles also follows the same procedure except that ZnCb solution was used instead of CdCb solution. 

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