Waste repositories

The throwaway fuel cycle does not recover the energy values present ia the irradiated fuel. Instead, all of the long-Hved actinides are routed to the final waste repository along with the fission products. Whether or not this is a desirable alternative is determined largely by the scope of the evaluation study. For instance, when only the value of the recovered yellow cake and SWU equivalents are considered, the world market values for these commodities do not fully cover the cost of reprocessing (2). However, when costs attributable to the disposal of large quantities of actinides are considered, the classical fuel cycle has been the choice of virtually all countries except the United States. 

The primary issue is to prevent groundwater from becoming radioactively contaminated. Thus, the property of concern of the long-lived radioactive species is their solubility in water. The long-lived actinides such as plutonium are metallic and insoluble even if water were to penetrate into the repository. Certain fission-product isotopes such as iodine-129 and technicium-99 are soluble, however, and therefore represent the principal although very low level hazard. Studies of Yucca Mountain, Nevada, tentatively chosen as the site for the spent fuel and high level waste repository, are underway (44). 

Miscellaneous. Iridium dioxide, like RUO2, is useful as an electrode material for dimensionally stable anodes (DSA) (189). SoHd-state pH sensors employing Ir02 electrode material are considered promising for measuring pH of geochemical fluids in nuclear waste repository sites (190). Thin films (qv) ofIr02 ate stable electrochromic materials (191). 

It has been traditional to subject workers to higher risks than the public, (a) Write a short discussion of the equities of this practice with consideration for the fact the worker may leave employment that imposed a long term risk, (b) The Nevada Test Site has been selected as a possible location for a high level waste repository. For purposes of the risk assessment, the workers in the repository will be treated as workers with subsequent higher allowable risk. There are many other workers at NTS. Discuss whether these should be treated as workers or public, (c) If they are treated... 

Other options for eliminating weapons-grade plutonium arc to seal it permanently in solid radioactive waste and dispose of it in waste repositories, and to use the plutonium to fuel fast neutron reactors (without reprocessing the plutonium into a MOX fuel). 

Despite the problems of direct experimental evaluation of plutonium stability constants, they are needed in modeling of the behavior of plutonium in reprocessing systems in waste repositories and in geological and environmental media. Actinide analogs such as Am+3, Th+, NpOj and UOj2 can be used with caution for plutonium in the corresponding oxidation states and values for stability constants of these analogues are to be found also in reference 20. 

Except for large scale accidental releases (e.g. nuclear explosions or catastrophic accidents at nuclear plants), water will be the main transport medium of plutonium to man. Therefore the size and location of plutonium sources, its pathways to man and its behaviour in natural waters are essential knowledge required for the evaluation of its ecological impact. That information, combined with radiological health standards, allows an assessment of the overall risk to the public from plutonium e.g. from a waste repository for spent unreprocessed reactor fuel elements in deep granite bedrock (8, 9). ... 

A general conclusion from the review of the distribution of plutonium between different compartments of the ecosystem was that the enrichment of plutonium from water to food was fairly well compensated for by man s metabolic discrimination against plutonium. Therefore, under the conditions described above, it may be concluded that plutonium from a nuclear waste repository in deep granite bedrock is not likely to reach man in concentrations exceeding permissible levels. However, considering the uncertainties in the input equilibrium constants, the site-specific Kd-values and the very approximate transport equation, the effects of the decay products, etc. — as well as the crude assumptions in the above example — extensive research efforts are needed before the safety of a nuclear waste repository can be scientifically proven. 

Rydberg, J. "Groundwater Chemistry of a Nuclear Waste Repository in Granite Bedrock" UCRL-53155 Lawrence Livermore Lab. Livermore, 1981. 

At Los Alamos, we are making a concerted effort to reduce this waste volume to a minimum. In effect, we are trying to look beyond the need for permanent waste repositories by evaluating new processing and recycle concepts. 

Selection criterion for radioactive nuclear waste repository site and... 

Waste, repository site-selection criterion, ground-water leaching. 335-36... 

Francis AJ, Gillow JB, Dodge CJ, et al. 1998. Role of bacteria as biocolloids in the transport of actinides from a deep underground radioactive waste repository. Radiochim Acta 82 347-354. 

Without confronting the complexity of studying and evaluating the TSPAs, one can gain some perspective on the scale of the hazards by considering the protective standards that have been proposed for nuclear waste repositories, in particular for the proposed US. site at Yucca Mountain (Bodansky, 1996). There have been three major proposals in recent years ... 

It should be noted that there is intense controversy as to the health effects of radiation doses below about 100 mSv per year. This estimate of 15,000 annual cancer deaths from indoor radon, as well as estimates of tens of thousands of eventual cancer deaths from Chernobyl exposures, is obtained by applying the linearity hypothesis. This hypothesis has been adopted by most regulatory agencies but is strongly contested by some scientists who believe it overestimates the effects of radiation at low dose levels. Of course, if calculations based on this hypothesis overestimate the deaths from indoor radon, they also overestimate the effects of potential radiation from a waste repository. 

There is some dispute among analysts as to whether world production of conventional oil will peak before the year 2020 or whether the peak will be delayed by another decade or two (Kerr, 1998), but in either case the current era of relatively cheap oil will end within several decades. A similar scenario is likely to follow for natural gas, although at a slower pace, and at a still slower pace, for coal. If our responsibilities to future generations include the relatively small problems that nuclear waste repositories may create in 10,000 years, they also include preparing for fossil fuel scarcity that will occur very much sooner. 

Progress in the establishment of a permanent waste repository, presumably at Yucca Mountain, within a framework of reasonable waste disposal standards. 

In the last twenty odd years, almost all nuclear endeavors in the U.S. have run into bureaucratic and litigious delays, making their schedules and costs unpredictable. In addition to reactor construction, there are the bureaucratic delays in the waste repository programs. Another example is the attempt to build a new uranium enrichment plant in the state of Louisiana, a plant which uses advanced technology demonstrated in several countries in Europe. Licensing started over seven years ago and is still held up by issues without relevance to technology or safety. It is approaching the point where the delays, and costs may lead to the abandonment of a potential asset... 

Sorption can significantly diminish the mobility of certain dissolved components in solution, especially those present in minor amounts. Sorption, for example, may retard the spread of radionuclides near a radioactive waste repository or the migration of contaminants away from a polluting landfill (see Chapters 21 and 32). In acid mine drainages, ferric oxide sorbs heavy metals from surface water, helping limit their downstream movement (see Chapter 31). A geochemical model useful in investigating such cases must provide an accurate assessment of the effects of surface reactions. 

Severe reactor-accident release, waste-repository release, land disturbance, and others, if hydrogen is produced via uranium feedstock ... 

RADIATION EFFECTS RELEVANT TO RADIOACTIVE HIGH-LEVEL WASTE REPOSITORY... 

Once Through, Reprocessing, and High-Level Waste Repository... 

Pearcy, E. C., Prokryl, J. D., Murphy, W. M. Leslie, B. W. 1994. Alteration of uraninite from the Nopal I deposit, Pena Blanca District, Chihuahua, Mexico, compared to degradation of SNF in the proposed U.S. high level nuclear waste repository at Yucca Mountain, Nevada. Applied Geochemistry, 9, 713—732. 

Such studies are sometimes criticized because they appear to be based on the concept of a global analogy between the specific example studied and a waste repository site (e.g., Miller et al. 1994). Clearly no geological site fully resembles a radioactive waste repository site. Confusion also seems to arise from the fact that analogy has sometimes been considered as a particular... 

There are inherent scale limitations in the time and space dimensions covered by laboratory studies. The applicability of the near field geochemical models derived from laboratory observations have to be applied to long-term, large-scale situations like the ones involved in the safety assessment of nuclear waste repositories. Hence, there is a need to test the models developed from laboratory investigations in field situations that are related to the ones to be encountered in repository systems. 

Colloid influence on the radionuclide migration from a nuclear waste repository... 

The reliable long-term safety assessment of a nuclear waste repository requires the quantification of all processes that may affect the isolation of the nuclear waste from the biosphere. The colloid-mediated radionuclide migration is discussed as a possible pathway for radionuclide release. As soon as groundwater has access to the nuclear waste, a complicated interactive network of physical and chemical reactions is initiated, and may lead to (1) radionuclide mobilization (2) radionuclide retardation by surface sorption and co-precipitation reactions and (3) radionuclide immobilization by mineralization reactions, that is, the inclusion of radionuclides into thermodynamically or kinetically stabilized solid host matrices. 

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