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Vulcanized elastomeric alloys

In contrast to the rigid TPOs described above, low-modulus/flexible grades of TPO blends are also produced commercially. In flexible TPOs, the rubber content can be as high as 60 %, and in some cases, the dispersed rubber may also be partially cross-linked during the mixing without losing the thermoplastic character of the matrix. However, the latter type of dynamically vulcanized elastomeric alloys or thermoplastic vulcanizate rubbers (TPVs) are considered as a separate class of elastomeric materials and hence will be discussed under elastomer blends. On the other hand, the soft TPO blends discussed here contain a low-modulus olefln copolymer elastomer as the major component with some polypropylene added to impart melt processability. [Pg.1756]

Vulcanized elastomeric alloys (EA) are TPEs composed of mixtures of two or more polymers that have received a proprietary treatment. Elastomeric alloy-thermoplastic vulcanizates (EA-TPVs) are a category of TPEs made of a rubber and plastic polymer mixture in which the rubber phase is highly vulcanized. The plastic phase of an EA-TPV is a polypropylene, and the rubber phase is an ethylene-propylene elastomer. [Pg.290]

Dynamically vulcanized, elastomeric thermoplastic alloys or TPVs display properties as good as or even better than the block copolymers, viz., a high degree of rubber elasticity yet good melt processability. The main advantages of the thermoplastic vulcanizate elastomer blends over the uncured thermoplastic/elasto-mer blends are... [Pg.1792]

Considerable improvements in properties result, compared to RRPP, if cross-linking/curing is introduced into the rubber particles. PR modified, rubber compounds. Such materials may be known as dynamically crosslinked polyolefin elastomer or TPO-XL or, as a d5mamically vulcanized material or, as an elastomeric alloy (EA) or, as an elastomeric alloy thermoplastic vulcanizate (EA-TPV). If enough plastic is present (say 50%), the compound can still be easily processed by thermoplastic techniques. [Pg.115]

Commercially important elastomeric thermoplastic alloys are dynamically vulcanized blends of polypropylene with high volume fractions of EPDM, polybutadiene rubber, nitrile rubber, and butyl rubber (Santoprene , Vyram , Geolast and Trefsin ) all currently sold by Advanced Elastomer Systems, a joint venture of Monsanto and Exxon. Another recent member of the commercial dynamically cured elastomeric thermoplastic alloys is the blend of PVC and a crosslinked ethylene copolymer (Alcryn , DuPont). The current consumption of all the elastomeric thermoplastic alloys in the USA is over 23 kton/y, with the EPDM/PP blend (Santoprene ) assuming about 90% of the market share. [Pg.1060]

Montell s in-reactor Catalloy ( catalytic alloy ) polymerization process alloys propylene with comonomers, such as EPR and EPDM, yielding very soft, very hard, and rigid plastics, impact grades or elastomeric TPOs, depending on the EPR or EPDM % content. The term olefinic for thermoplastic olefinic elastomers is arguable, because of the generic definition of olefinic. TPVs are composed of a continuous thermoplastic polypropylene phase and a discontinuous vulcanized rubber phase, usually EPDM, EPR, nitrile rubber, or butyl rubber. [Pg.197]


See other pages where Vulcanized elastomeric alloys is mentioned: [Pg.1036]    [Pg.1792]    [Pg.1036]    [Pg.1792]    [Pg.128]    [Pg.152]    [Pg.1060]    [Pg.222]    [Pg.548]    [Pg.566]    [Pg.566]    [Pg.311]    [Pg.853]    [Pg.164]    [Pg.717]    [Pg.20]    [Pg.1060]    [Pg.1792]    [Pg.1796]   


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Elastomeric

Elastomeric alloys

Elastomerics

Vulcan

Vulcanization

Vulcanize

Vulcanized

Vulcanizing

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