Vulcanizate tensile strength

Difference in vulcanizate tensile strength of EPDMs prepared with various catalyst systems, especially the high strength of EPDM prepared with vanadium carboxylates (V g)>is examined against various structural parameters. Effect of L r l ... 

Vj g-EPDM and VOCI3-EPDM vulcanizate tensile strength Is not simply explainable by network quality resulting from difference In the third monomer distribution in the terpolymers. 

In Figure 8 are also reproduced data (curves A and C) of the other two systems previously given Q). It is clear that although addition of ETCA to the V g-EtyV Clo system makes the DCPD distribution in the terpolymer much more heterogeneous (curve A, compared to B) and yields lower vulcanizate tensile strength (see above), the much more even distribution of DCPD in V(acac) -EPDM... 

A second important factor is the density of cross-linking. It is a common observation that, with both amorphous and crystallizing vulcanizates, tensile strength passes through a maximum value with increasing cross-link density (Fig. 8.11). Various theories to explain... 

Fig. 16. Effect on vulcanizate tensile strength of peptization time, and type and dosage of peptizer. E, Dispergum 24 F, Struktol A82 G, Struktol A60/Renacit VII 0 1 phr H, Struktol A60/Renacit VII 0-15 phr , unaged i, aged three days at 100°C.

Types of Latex Compounds. For comparison with dry-mbber compounds, some examples of various latex compounds and the physical properties of their vulcanizates are given in Table 23. Recipes of natural mbber latex compounds, including one without antioxidant, and data on tensile strength and elongation of sheets made from those, both before and after accelerated aging, are also Hsted. The effects of curing ingredients, accelerator, and antioxidant are also Hsted. Table 24 also includes similar data for an SBR latex compound. A phenoHc antioxidant was used in all cases. 

Wire and cable insulation based on vulcanizates of PZ has also been studied. Again, low fire risk was the target property, and this was achieved. The need to vulcanize the coating, somewhat modest tensile properties, tensile strength of 5.2 to 12.2 MPa (760 to 1770 psi), and high dielectric constant (4—5 at 10,000 Hz) limited interest in this appHcation (19). 

Increase in the molecular weight of the polychloroprene, increasing viscosity and tensile strength of vulcanizates. 

A VDF unit also follows FIFP m the structurally much more complex terpo-lymers [30] Dipolymers contain 60 wt % VDF (66% F) and terpolymers contain 33-50 wt % VDF (66-69 5% F) and generally less than 28 wt % TFE Molecular weights range from 1 5 x 10 to 10 Their respective continuous service temperature ranges are -18 to 210 °C and -12 to 230 °C Dipolymer vulcanizates retam over 50% of their tensile strength for more than 1 year at 200 °C or for 2 months at 260 C... 

Neoprene vulcanizates have a high tensile strength, excellent oil resistance (better than natural rubber), and heat resistance. 

Butyl ruhher vulcanizates have tensile strengths up to 2,000 psi, and are characterized hy low permeahility to air and a high resistance to many chemicals and to oxidation. These properties make it a suitable rubber for the production of tire inner tubes and inner liners of tubeless tires. The major use of butyl rubber is for inner tubes. Other uses include wire and cable insulation, steam hoses, mechanical goods, and adhesives. Chlorinated butyl is a low molecular weight polymer used as an adhesive and a sealant. 

Figure 18.1 is the typical stress-strain curves of the filled rubber (SBR filled with fine carbon black, HAF),

As shown in Figure 18.1, in the stress-strain curve of the real unfilled SBR vulcanizate, the stress upturn does not appear and as a result, tensile strength and strain at break are only about 2 MPa and 400%-500%, respectively. Nevertheless, the stress-strain curve of the SBR vulcanizate filled with carbon black shows the clear stress upturn and its tensile stress becomes 30 MPa. This discrepancy between both vulcanizates is actually the essential point to understand the mechanism and mechanics of the carbon black reinforcement of mbber. 

Figure 18.17 shows that the characteristics of the stress-strain curve depend mainly on the value of n the smaller the n value, the more rapid the upturn. Anyway, this non-Gaussian treatment indicates that if the rubber has the idealized molecular network strucmre in the system, the stress-strain relation will show the inverse S shape. However, the real mbber vulcanizate (SBR) that does not crystallize under extension at room temperature and other mbbers (NR, IR, and BR at high temperature) do not show the stress upturn at all, and as a result, their tensile strength and strain at break are all 2-3 MPa and 400%-500%. It means that the stress-strain relation of the real (noncrystallizing) rubber vulcanizate obeys the Gaussian rather than the non-Gaussian theory. 

Clay hllers were surface modihed with TMPTA or triethoxyvinyl silane (TEVS) followed by EB irradiation by Ray and Bhowmick [394]. Both the untreated and treated fillers were incorporated in an ethylene-octene copolymer. Mechanical, dynamic mechanical, and rheological properties of the EB-cured unfilled and filled composites were studied and a significant improvement in tensile strength, elongation at break, modulus, and tear strength was observed in the case of surface-treated clay-filled vulcanizates. Dynamic mechanical studies conducted on these systems support the above findings. 

Nandanan et al. [35] reported the utilization of linseed oil as an MFA in nitrile rubber vulcanizates. Linseed oil not only acted as a plasticizer but also as the fatty acid component of the activator in the NBR vulcanizates. Use of linseed oil gave appreciable increase in properties like tensile strength, tear resistance, etc. while the viscosity of the compound was marginally lower than that of the control compound (which used di-octyl phthalate as the plasticizer). The vulcanizates containing linseed oil also exhibited increased cure rate as well as reduced leachability compared to the control at a dosage of 2-5 phr. This loading was seen to replace 6 phr DOP and 2 phr stearic acid in conventional NBR vulcanizates thereby reducing compound costs. 

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