Volume-averaged population balances

The population balance simulator has been developed for three-dimensional porous media. It is based on the integrated experimental and theoretical studies of the Shell group (38,39,41,74,75). As described above, experiments have shown that dispersion mobility is dominated by droplet size and that droplet sizes in turn are sensitive to flow through porous media. Hence, the Shell model seeks to incorporate all mechanisms of formation, division, destruction, and transport of lamellae to obtain the steady-state distribution of droplet sizes for the dispersed phase when the various "forward and backward mechanisms become balanced. For incorporation in a reservoir simulator, the resulting equations are coupled to the flow equations found in a conventional simulator by means of the mobility in Darcy s Law. A simplified one-dimensional transient solution to the bubble population balance equations for capillary snap-off was presented and experimentally verified earlier. Patzek s chapter (Chapter 16) generalizes and extends this method to obtain the population balance averaged over the volume of mobile and stationary dispersions. The resulting equations are reduced by a series expansion to a simplified form for direct incorporation into reservoir simulators. 

As shown in Appendix A, Equation (1) can be averaged over the volume of the porous medium to yield the population balances of bubbles in flowing foam... 

The continuum form of the bubble population balance, applicable to flow of foams in porous media, can be obtained by volume averaging. Bubble generation, coalescence, mobilization, trapping, condensation, and evaporation are accounted for in the volume averaged transport equations of the flowing and stationary foam texture. 

The zeroth order moments of the volume averaged bubble population equations, i.e., the balances on the total bubble density in flowing and stationary foam, have the form of the usual transport equations and can be readily incorporated into a suitable reservoir simulator. 

The purpose of this Appendix is to volume-average the population balance of bubble number density... 

Lee et al [66] and Prince and Blanch [92] adopted the basic ideas of Coulaloglou and Tavlarides [16] formulating the population balance source terms directly on the averaging scales performing analysis of bubble breakage and coalescence in turbulent gas-liquid dispersions. The source term closures were completely integrated parts of the discrete numerical scheme adopted. The number densities of the bubbles were thus defined as the number of bubbles per unit mixture volume and not as a probability density in accordance with the kinetic theory of gases. 

Chen et al [12] and Bertola et al [8] simulated mixtures consisting of A1+1 phases by use of algebraic slip mixture models (ASMMs) which have been combined with a population balance equation. Each bubble size group did have individual local velocities which were calculated from appropriate algebraic slip velocity parameterizations. In order to close the system of equations, the mixture velocity was expressed in terms of the individual phase velocities. The average gas phase velocity was then determined from a volume weighted slip velocity superposed on the continuous phase velocity. Chen et al [12] also did run a few simulations with the ASMM model with the same velocity for all the bubble phases. 

In this section the population balance modeling approach established by Randolph [95], Randolph and Larson [96], Himmelblau and Bischoff [35], and Ramkrishna [93, 94] is outlined. The population balance model is considered a concept for describing the evolution of populations of countable entities like bubble, drops and particles. In particular, in multiphase reactive flow the dispersed phase is treated as a population of particles distributed not only in physical space (i.e., in the ambient continuous phase) but also in an abstract property space [37, 95]. In the terminology of Hulburt and Katz [37], one refers to the spatial coordinates as external coordinates and the property coordinates as internal coordinates. The joint space of internal and external coordinates is referred to as the particle phase space. In this case the quantity of basic interest is a density function like the average number of particles per unit volume of the particle state space. The population balance may thus be considered an equation for the number density and regarded as a number balance for particles of a particular state. 

The coalescence terms in the average microscopic population balance can then be expressed in terms of the local effective swept volume rate and the coalescence probability variables ... 

The application of similar advanced distribution functions in the context of population balance analysis of polymerization processes is familiar in reaction engineering [40, 97]. However, the microscopic balance equations used for this purpose are normally averaged over the whole reactor volume so that simplified macroscopic (global) reactor analysis of the chemical process behavior is generally performed [35]. 

The Euler-Euler model is based on the volume average form of the transport equation developed for multiphase systems [46] and is coupled with the population balance equations for the particle agglomeration [139]. The general model equations... 

FIGURE 7.4.1 Temporal evolution of the average particle volume in Brfownian aggregation for a constant number of particles in the volume of mixing from Monte Carlo simulation compared with (i) population balance equation, (ii) product density analysis using closure hypothesis (7.4.13). (From Sampson and Ramakrishna, 1986.)... 

The population balance deals with number of pores rather than the pore volume, in a given size range. However, if the number density function is assume to be equal to the pore volume size distribution divided by the average pore volume in rach pore-size range and both breath and length are independent of time and uncorrelated with the width, then a parameter proportional to the number density hmction can be defined as follows ... 

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