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1-Vinylcyclohexene

PROPERTIES RESEARCH grade PURE GRADE TECHNICAL GRADE [Pg.46]


Production of ethylbenzene from butadiene has been iavestigated by many researchers. It consists of two steps cyclodimerization of 1,3-butadiene to 4-vinylcyclohexene and dehydrogenation of the vinylcyclohexene to ethylbenzene. [Pg.481]

When buta-1,3-diene 3 is irradiated in the presence of a photosensitizer (e.g. benzophenone), the isomeric divinylcyclobutanes 6 and 7 are formed via the intermediate diradical species 4 and 5 respectively in addition the [4 + 2] cycloaddition product 4-vinylcyclohexene (see Diels-Alder reaction) is obtained as a side product ... [Pg.77]

The use of zeolites is particularly advantageous for self-Diels-Alder reactions of gaseous dienes because it reduces the polymerization of the reactant. An example is the cyclodimerization of 1,3-butadiene to 4-vinylcyclohexene [20a] carried out at 250 °C with satisfactory conversion when non-acidic zeolites, such as large-pore zeolites Na-ZSM-20, Na- S and Na-Y, are used. [Pg.148]

The Dow corporation has recently developed constrained geometry addition polymerization catalysts (CGCT), typically Me2Si(C5Me4)(NBut)MCl2 (M = Ti, Zr, Hf) (141) activated with MAO. The homo-polymerization of a-olefins by CGCT afford atactic or somewhat syndiotactic (polypropylene rr 69%) polymers. The metal center of the catalyst opens the coordination sphere and enables the co-polymerization of ethylene to take place, not only with common monomers such as propylene, butene, hexene, and octene, but also with sterically hindered a-olefins such as styrene and 4-vinylcyclohexene [202]. [Pg.32]

The thermolysis of ladderanes has been studied in detail (Scheme 1). On heating, bicyclo[2.2.0]hexane and its derivatives exhibit skeletal inversion and cleavage to 1,5-hexadiene derivatives.26 The thermolysis of anti- and yyft-tricyclo[4.2.0.02,5]octanes and their derivatives gives cis,cis- and cis, trans-1,5-cyclooctadienes, cis- and trans-1,2-divinylcy clobutanes, and 4-vinylcyclohexene as ring-opening products.27-29 Furthermore, syn-tricyclo-[4.2.0.02,5]octane isomerizes to aw//-tricyclo[4.2.0.02,5]octane.29c,d The thermodynamic parameters and the reaction mechanisms for these thermal reactions have been discussed. [Pg.136]

Diisobutylaluminium hydride catalyses the ring-closure of various dienes. It is proposed that the process involves addition of the aluminium hydride to a terminal double bond, followed by ring-closure and, finally, elimination of the catalyst (equation 106). Thus 1,5-hexadiene gives methylenecyclopentane (213) (equation 107), 1,6-heptadiene gives methylenecyclohexane (214) (equation 108), 4-vinylcyclohexene gives bicyclo[3.2.1]oct-2-ene (215) (equation 109) and the spiro compound 217 is obtained from 5-methylene-l,8-nonadiene (216) (equation 110)112. [Pg.538]

At the same time, when I is compared with 4-vinylcyclohexene diepoxide (II), it was observed that II is considerably more reactive. The reasons for the difference in the reactivity between I and II were not immediately apparent and, therefore, a study of the reactivity of I was undertaken with the aid of model compounds. [Pg.83]

Tetrahydrobenzyl alcohol (( )3-cyclohexenene-l-methanol) and 30% aqueous hydrogen peroxide were purchased from Fluka, AG. 3-Cyclohexene-1-carboxylic acid and cis-4-cyclohexene-l,2-dicarboxylic acid were used as purchased from Lancaster Chemical Co. Methyl iodide, acetic anhydride, Oxone (potassium peroxymonosulfate), Aliquot 336 (methyl tri-n-octylammonium chloride), sodium tungstate dihydrate and N,N-dimethylaminopyridine (DMAP) were purchased from Aldrich Chemical Co. and used as received. 3,4-Epoxycyclohexylmethyl 3, 4 -epoxycyclohexane carboxylate (ERL 4221) and 4-vinylcyclohexene dioxide were used as purchased from the Union Carbide Corp. (4-n-Octyloxyphenyl)phenyliodonium hexafluoroantimonate used as a photoinitiator was prepared by a procedure described previously (4). [Pg.83]

Tetrahydronaphthalene, 3300 f Tetrahydropyran, 1965 Tridecanal, 3619 f Vinyl acetate, 1532 f 4-Vinylcyclohexene, 3004... [Pg.331]


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3-Vinylcyclohexene oxide

3-Vinylcyclohexene oxide n -Vinylcyclopentadienyl)

3-Vinylcyclohexene oxide polymerization

3-Vinylcyclohexene oxide styrene copolymerization

3-Vinylcyclohexene oxide synthesis

4-Vinylcyclohexene dioxide

4-Vinylcyclohexene, epoxidation

4-vinylcyclohexene diepoxide

4-vinylcyclohexene, addition

Cyclohexenes Bicyclo hexenes, Vinylcyclohexenes

F 4-Vinylcyclohexene

Hydrogenation vinylcyclohexene

L-Vinylcyclohexene

Vinylcyclohexene , synthesis

Vinylcyclohexene Diels-Alder-dimerization

Vinylcyclohexene cyclodimerization, butadiene

Vinylcyclohexene isomerization

Vinylcyclohexene oxidation

Vinylcyclohexene regioselective

Vinylcyclohexene selective

Vinylcyclohexenes

Vinylcyclohexenes, radical cations

Vinylcyclohexenes, radical cations retro-Diels-Alder reaction

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