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Vinylcyclohexenes, radical cations retro-Diels-Alder reaction

Limonene, one of the most prominent natural monoterpenes (cf Section VII), represents a particular derivative of 4-vinylcyclohexene since it has been studied with respect to the pronounced energy dependence of its fragmentation behaviour (Scheme 7). Counterintuitively, and in contrast to 4-vinylcyclohexene, the radical cations of limonene (27) do not undergo the retro-Diels-Alder reaction if the internal energy of the ions is low. As... [Pg.18]


See other pages where Vinylcyclohexenes, radical cations retro-Diels-Alder reaction is mentioned: [Pg.7]    [Pg.7]    [Pg.7]   
See also in sourсe #XX -- [ Pg.6 , Pg.16 , Pg.17 ]

See also in sourсe #XX -- [ Pg.6 , Pg.16 , Pg.17 ]

See also in sourсe #XX -- [ Pg.6 , Pg.16 , Pg.17 ]




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4-Vinylcyclohexene

Cation Diels-Alder reaction

Cationic reactions

Diels-Alder reactions cation radical

Diels-Alder reactions radical

Radical cation reactions

Retro Diels-Alder reaction

Retro-Diels-Alder

Retro-reaction

Vinylcyclohexenes, radical cations

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