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The environmental chemistry of chlorinated paraffins was first reviewed in the Handbook of Environmental Chemistry by Zitko [4]. There have been many other reviews, especially for environmental and human exposure assessment, beginning with a report prepared for the US Environmental Protection Agency by Howard et al. [5] and more recently by Mukherjee [6], Environment Canada [2], UK Dept of the Environment [7], the World Health Organization [8], and by Tomy et al. [9], In addition to environmental chemistry aspects, the above reviews have covered the toxicity and bio accumulation of PCAs. This chapter will focus on the recent advances in knowledge of the physical properties, degradation, analysis, and environmental levels of PCAs with special emphasis on the Cio-Cu group. 

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Acknowledgments The author receives funding from the UK Dept of Health (NHS Chair of Pharmacogenetics program), MRC, and Wellcome Trust. 

Dept of Chemistry, The University of Liverpool, Crown Street, Liverpool L69 7ZD, UK Dept of Chemistry, University College, London, WCIH OAJ, UK... 

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We wish to thank Dr. Nabeel Affara (Dept, of Pathology, University of Cambridge) and Dr. David Latto (BioRobotics UK Ltd.) for their extensive contribution to the microarray methodologies described in this review. 

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Henryk Pawl Herbich obtained his eivil engineering diploma from the Technical University of Warsaw in 1923. He attended also courses at the University of Edinburg UK, receiving the DSe degree in 1943. He worked from 1924 for the Dept, of Public Works, and later for the Polish Dept, of Transportation as hydraulic engineer. He was from 1935 head of the Polish Water Power Bureau, and vice-president of the Inland Waterways Department until 1939. Then he directed the hydro-electric research division, the Polish Hydrological Institute, and he was part-time Lecturer at the Technical University of Warsaw. 

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Acknowledgements We thank Dr. N. Smirnoff (Dept of Biological Sciences, University of Exeter, Exeter EX4 4PS, UK) for critical discussion and correcting the English text. 

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